• Title/Summary/Keyword: 활성-셀

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Extraction of Cd and Pb from Soil by Anionic Surfactant and Ligand NaI (NaI 리간드화 계면활성제에 의한 토양내 Cd과 Pb 추출 연구)

  • Heo, Jung-Hyun;Jeong, Seung-Woo
    • Journal of Soil and Groundwater Environment
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    • v.13 no.5
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    • pp.74-80
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    • 2008
  • Heavy metals, Cd and Pb, in soil were extracted by using anionic surfactants such as AOS (alpha olefin sulfonate), SDS (sodium dodecyl sulfate), and LAS (linear alkyl benzene sulfonic acid). Metal extractability from soil was affected by the carbon number and solution pH of surfactants. LAS showed higher metal extractability due to the acidic solution condition. Although SDS has a fewer carbon number than AOS, it would produce smaller micelles and resulted in more efficient extraction of metals by increased soil contact. Cd extractability of surfactant was twice enhanced by adding NaI as a ligand. However, Pb extractability of surfactant was sometimes reduced by adding NaI. Those ligand effects were dependent on solubility of metal-ligand. The column experiment also showed that SDS having smaller micelles resulted in higher metal extractability than AOS.

The Protective Effect of Selenium on Radiation in Rat (흰쥐에 있어 방사선에 대한 셀레늄의 보호효과)

  • Son, Eun-Joo;Ryu, Eun-soon
    • Journal of the Korean Society of Radiology
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    • v.13 no.3
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    • pp.439-444
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    • 2019
  • In this study, the radiation protection effects of selenium, known as a powerful antioxidant, were studied. After 14 days of oral injection of selenium into the rat, a full body irradiation of 10 Gy was carried out. And after 1 day, 3.5 day, 7 day and 21 day, we observed blood cell components and superoxide dismutase(SOD) and small intestine changes. Compared to irradiation groups, there was a significant protection effect of reducing the hematopoietic immune system damage in the irradiated group after selenium administration(p<0.05). Then, selenium is a valid ingredient that increases the activity of the superoxide Dismutase(SOD), and it is confirmed that it has an effect of inhibiting apoptosis expression of small intestinal cells by irradiation. Based on these results, selenium is considered to be an essential ingredient for protecting living things from radiation.

Fabrification of Segmented Flat-Tubular SOFC cell (Segmented 평관형 SOFC 셀 제조)

  • Park, Sung-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Choi, Heon-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.137.1-137.1
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    • 2010
  • SOFC cell 하나의 전위차는 약1.1V이기 때문에 발전용으로 사용하기 위해서는 수많은 단전지를 직렬로 연결하는 구조가 필요하다. 이러한 stack의 디자인에서 발생하는 문제를 획기적으로 개선한 형태가 하나의 지지체에 셀을 직렬로 연결함으로 전극의 선폭 및 단위 셀 간의 간격이 기존 평판형, 원통형에 비해 대폭 축소되어 전극 및 연결재의 저항손실을 최소화할 수 있는 Segmented형 SOFC이다. Segmented SOFC에 적용하기 위한 세라믹 다공성 지지체는 연료와 공기에서의 화학적 안정성, 셀의 구성소재와 반응이 없으며 열팽창계수가 유사해야하는 특성을 가져야하는데 그 중에서도 지지체로써 적절한 기계적 강도와 높은 가스투과도가 요구되어진다. 본 연구에서는 고온에서 안정한 Spinel의 MgAl2O4를 주성분으로 하는 다공성 지지체를 압출 성형하여 평관형으로 제조하였으며 활성탄을 기공형성제로 사용하여 연료의 공급이 원활하도록 약 30%의 기공율을 가지는 다공성 세라믹 지지체를 제조하였다. 제조된 세라믹 지지체에 연료극(NiO/YSZ), 전해질(TZ8Y), 공기극(LSM)을 코팅하여 실제 SOFC에 적용이 가능함을 확인하였다.

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A Statistical-Mechanical Model on the Temperature Dependence of Critical Micelle Concentration (임계 마이셀 농도의 온도 의존성에 대한 통계 역학적 모델)

  • Lim, Kyung-Hee;Kang, Kye-Hong;Lee, Mi-Jin
    • Applied Chemistry for Engineering
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    • v.17 no.6
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    • pp.625-632
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    • 2006
  • Dependence of the critical micelle concentration (CMC) on temperature is examined from a statistical-mechanical point of view. A simple and primitive model examined in this article yields ln CMC= A+BT+C/T+D ln T with T being temperature and A, B, C, D being constants depending on the properties of the surfactant molecules which comprise the micelles. The resulting equation combines Muller's and Lim's equations, which have already been proven to fit well measured CMC data with temperature. The statistical-mechanical model on micellization discussed in this article provides a theoretical basis on these equations.

The Effects of Endurance Exercise and Selenium Treatment on Mitochondrial Transcription Factors Expression in Old GK Rats (지구성 운동과 셀레늄 투여가 노화 GK 흰쥐의 미토콘드리아 전사인자 발현에 미치는 영향)

  • Kim, Bum-Soo
    • Development and Reproduction
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    • v.14 no.2
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    • pp.75-82
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    • 2010
  • The objective of this study is to identify the effects of endurance exercise and selenium on mitochondrial transcription factor in old Goto-Kakizaki (GK) rats. In this experiments, endurance exercise were treadmill-run at 24 m/min, 30 min/day, 5 days/week, 6 weeks and 5 umol/kg of sodium selenite was injected intraperitoneally. In exercise group, selenium group, and combination group, the mitohondrial biogenesis-related genes, including PGC-$1{\alpha}$, NRF-1, and Tfam expression level were significantly increased compared to control group. Consistent with the increased biogenesis-related genes, the cytochrome C in the treated groups, which was the indicator of mitochondrial content, was significantly increased compared to control group. Especially, combination of exercise and selenium may be effective in the increase of mitochondrial biogenesis, activity and insulin sensitivity. Therefore, exercise and selenium treatment is likely to promote diabeticmitochondrial malfunction and then improve diabetes.

Gel Type Formulation Utilizing Polymer-Surfactant Interaction (폴리머와 계면활성제의 상호작용을 이용한 젤타입 제형의 제조)

  • Kim, Dong-Joo;Kang, Tae-Jun;Lee, Cheon-Koo;Lee, Jung-No
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.33 no.1 s.60
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    • pp.7-10
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    • 2007
  • The interaction between polymers and surfactants was investigated by means of rheological and surface tension measurements. The polymers used in this study were acrylates/$C_{10-30}$ alkyl acrylate crosspolymer (AC) and ammonium acryloyldimethyltaurate/VP copolymer (AV). And the surfactants were PEG-40 hydrogenated castor oil (HC) and polysorbate 60 (P60). HC and P60 made the micelles intervening between AC polymers, resulting in the increase of viscosity. However, HC showed a similar behavior over the wider range of surfactant concentration than P60. Regarding of surface tensions in the same range of surfactant concentration, AC/HC solution showed the area of increasing surface tension with surfactant concentration in contrast to the AC/P60 solution showing no increasing area. It is assumed that the micelles between AC/HC were formed so cooperatively and strongly that the surfactants located at the surface originally moved to the micelles.

Effect of Molecular Structures on the Solubility Enhancement of Organic Contaminants by Amphiphiles (양수성 물질에 의한 유기오염물질의 수중 용해도 증가에 분자구조가 미치는 영향)

  • Cho, Hyun-Hee;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.755-764
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    • 2000
  • Fate and transport of hydrophobic organic contaminants can be influenced by naturally-existing humic substances and surfactants applied to wash polluted soils in the subsurface environment. The objective of this paper is to study the solubility enhancement of four PAHs (polycyclic aromatic hydrocarbon) and p,p'-DDT in humic acid and surfactant solutions. As the number of aromatic ring is increased, the extent of solubility enhancement of PAHs by humic acid increased. Although the hydrophobicity of p,p'-DDT was the largest among five organic compounds used, the extent of solubility enhancement of p,p'-DDT by humic acid was lower than that of pyrene. In case of anionic surfactants, the extent of the increased solubility of five organic compounds by SDS and SDDBS was increased linearly, but the extent of the increased solubility of p,p'-DDT by MADS-12 was lower than that of perylene.

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An Analog Memory Fabricated with Single-poly Nwell Process Technology (일반 싱글폴리 Nwell 공정에서 제작된 아날로그 메모리)

  • Chai, Yong-Yoong
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.5
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    • pp.1061-1066
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    • 2012
  • A digital memory has been widely used as a device for storing information due to its reliable, fast and relatively simple control circuit. However, the storage of the digital memory will be limited by the inablility to make smaller linewidths. One way to dramatically increase the storeage capability of the memory is to change the type of stored data from digital to analog. The analog memory fabricated in a standard single poly 0.6um CMOS process has been developed. Single cell and adjacent circuit block for programming have been designed and characterized. Applications include low-density non-volatile memory, control of redundancy in SRAM and DRAM memories, ID or security code registers, and image and sound memory.

Effect of Dietary Selenium on the Colon Carcinogenesis in Male ICR Mice

  • Cho, Min-Haeng;Kim, Jun-Hyeong;Hue, Jin-Joo;Kang, Bong-Su;Park, Hyun-Ji;Nam, Sang-Yoon;Yun, Young-Won;Kim, Jong-Soo;Jeong, Jae-Hwang;Lee, Beom-Jun
    • Journal of Food Hygiene and Safety
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    • v.25 no.3
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    • pp.269-277
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    • 2010
  • Selenium is an essential micronutrient for normal body function and functions as an essential constituent of selenoproteins. This study was carried out to investigate effect of selenium on the formation of colonic aberrant crypt foci (ACF) and tumor formation in a mouse model. Five-week old ICR mice were acclimated for one week and fed different selenium diet (0.02, 0.1, and 0.5 ppm) for 12 weeks. Animals received three intraperitoneal injections of azoxymethane (10 mg/kg B.W. in saline for 3 weeks), followed by 2% dextran sodium sulfate in the drinking water for a week. There were four experimental groups, including a normal control group and three different selenium levels groups. After sacrifice, the total numbers of aberrant crypt (AC) and ACF were measured in the colonic mucosa after methylene blue staining. The number of tumors was noted for tumor incidence. Liver selenium concentration was measured using ICP-AES method. Gutathione peroxidase (GPx) activity was determined using a GPx assay kit in the liver and colon. TUNEL assay and proliferating cell nuclear antigen (PCNA) staining were performed to examine the cell apoptosis and cell proliferation, respectively. Immunohistochemistry of $\beta$-catenin was also performed on the mucous membrane tissue of colon. The activity of GPx in the liver and colon was decreased in the selenium-deficient diet group while it was increased in the selenium-overloaded diet group. Apoptotic positive cells were increased in the selenium-overloaded diet group but decreased in the selenium-deficient diet group. PCNA staining area was decreased in the selenium-overloaded diet group. In addition, the $\beta$-catenin protein level in the selenium-deficient diet group was increased but decreased in the selenium-overloaded diet group. These results indicate that dietary selenium might exert a modulating effect on colon cancer by inhibiting the development of ACF and colon tumor formation in this mouse model.

The Effect of Additives on Sound Absorption Coefficient of Polyurethane Foam (폴리우레탄폼의 흡음율에 대한 첨가제의 영향)

  • Park, Nam-Cook;Kim, Young-Chul;Park, Chong-Rai
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.197-203
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    • 1997
  • The effect of additives on the mechanical properties of polyurethane foam were investigated. The resin used in this study was prepared by adding catalyst, surfactant and cross-linker to both KONIX FA-703 polyether polyol(80%) and KONIX FA-733 polyether polyol(20%). The polyurethane was foamed by adding equivalent amount of isocyanate(TDI-80, prepolymer M-200, pure MDI) to the resin and was used in property measurements after 72 hours hardening. The physical properties of polyurethane foam were investigated in terms of density, tensile strength, tear strength, elongation, sound absorption coefficient and gel profile measurements. The effects of surfactant on the cell size was investigated by scanning electron microscopy(SEM). The sound absorption coefficient was directly related to the cell size. The physical properties were improved with increasing amount of surfactant(L-5309) until 1.0 part per hundred polyol(1.0pphp).

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