• Title/Summary/Keyword: 활동도 계수

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Activity coefficients of Solvents and Ions in Electrolyte Solutions (전해질 용액에서 용매 및 이온의 활동도 계수)

  • Shim, Min-Young;Kim, Ki-Chang
    • Journal of Industrial Technology
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    • v.20 no.A
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    • pp.185-194
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    • 2000
  • In this work we measured the total pressure of the aqueous solutions and the methanol-water solutions dissolved with inorganic salts, at $25^{\circ}C$. In organic electrolytes used in this work were $K_2SO_4$ and $(NH_4)_2SO_4$. Using the measured vapour pressures the activity coefficient of solvents and the mean ionic activity coefficient were obtained through thermodynamic relations. The activity coefficients of solvent and the mean ionic activity coefficirnt obtained in this work were fitted with Macedo's model and Acard's model. Both two models were good agreeable to the vapor pressure and the mean ionic activity coefficient for the electroyte aqueous solutions. For electrolyte /methanol/water solutions, Macedo's model had much deviation from experimental data, while Acard's model showed a good agreement with experimental data.

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On the Relation Between the Sun and Climate Change with the Solar North-South Asymmetry (태양의 북-남 비대칭성을 고려한 태양활동과 기후변화와의 관계)

  • Cho, I.H.;Kwak, Y.S.;Cho, K.S.;Choi, H.S.;Chang, H.Y.
    • Journal of Astronomy and Space Sciences
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    • v.26 no.1
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    • pp.25-30
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    • 2009
  • We report the relation between the solar activity and terrestrial climate change with the solar north-south asymmetry. For this purpose, we calculate sliding correlation coefficients between sunspot numbers and earth's mean annual temperature anomalies. Then, we compare the epoch that the sign of correlation changes with the epoch that the sign of the solar north-south asymmetry changes. We obtain that corresponding times are 1907 and 1985, respectively. Further more, these two epoches are well consistent with those of signs of the solar north-south asymmetry changes. We also obtain that the plot between sunspot numbers and temperature anomalies could be classified by 1907 and 1985. We conclude that temperature anomalies are shown to be negatively correlated with sunspot numbers when the southern solar hemisphere is more active: and vice versa.

Evaluation of Partial Safety Factors on Sliding of Monolithic Vertical Caisson of Composite Breakwaters (혼성제 직립 케이슨의 활동에 대한 부분안전계수 산정)

  • Lee, Cheol-Eung;Park, Dong-Heon;Kwon, Hyuk-Jae;Lee, Sun-Yong
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.21 no.4
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    • pp.267-277
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    • 2009
  • Partial safety factors of the load, resistance, and reliability function are evaluated according to the target probability of failure on sliding mode of monolithical vertical caisson of composite breakwaters. After reliability function is formulated for sliding failure mode of caisson of composite breakwaters regarding bias of wave force, uncertainties of random variables related to loads, strengths are analyzed. Reliability analysis for the various conditions of water depth, geometric, and wave conditions is performed using Level II AFDA model for the sliding failure. Furthermore, the reliability model is also applied to the real caisson of composite breakwaters of Daesan, Dong- hae, and Pohang harbor. By comparing the required width of caisson of composite breakwater according to target probability of failure with the other results, the partial safety factors evaluated in this study are calibrated straightforwardly. Even though showing a little difference on the 1% of target probability, it may be found that the present results agree well with the other results in every other target probability of failure.

Analysis on the Correction Factor of Emission Factors and Verification for Fuel Consumption Differences by Road Types and Time Using Real Driving Data (실 주행 자료를 이용한 도로유형·시간대별 연료소모량 차이 검증 및 배출계수 보정 지표 분석)

  • LEE, Kyu Jin;CHOI, Keechoo
    • Journal of Korean Society of Transportation
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    • v.33 no.5
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    • pp.449-460
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    • 2015
  • The reliability of air quality evaluation results for green transportation could be improved by applying correct emission factors. Unlike previous studies, which estimated emission factors that focused on vehicles in laboratory experiments, this study investigates emission factors according to road types and time using real driving data. The real driving data was collected using a Portable Activity Monitoring System (PAMS) according to road types and time, which it compared and analyzed fuel consumption from collected data. The result of the study shows that fuel consumption on national highway is 17.33% higher than the fuel consumption on expressway. In addition, the average fuel consumption of peak time is 4.7% higher than that of non-peak time for 22.5km/h. The difference in fuel consumption for road types and time is verified using ANOCOVA and MANOVA. As a result, the hypothesis of this study - that fuel consumption differs according to road types and time, even if the travel speed is the same - has proved valid. It also suggests correction factor of emission factors by using the difference in fuel consumption. It is highly expected that this study can improve the reliability of emissions from mobile pollution sources.

Investigation of vapor-liquid equilibrium of HFC125/134a system (HFC125/134a계의 기-액상평형에 관한 연구)

  • 김창년;박영무
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.2
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    • pp.238-250
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    • 1998
  • Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC125/134a are measured in the range between 268.15 and 283.15K at five compositions. Twenty-five equilibrium data are obtained. To verify consistency of these data, they are tested for thermodynamic consistency. Based upon the present data, the binary interaction parameter for CSD and RKS equation of state is calculated at five isotherms and comparison with the data in the open literatures is made. Results of Nagel and Bier are in very good agreements with those from this study within 0.32∼1.11% for bubble point pressure and -0.66∼0.18% for vapor mole fraction.

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원자력산업의 산업연관 분석

  • 문기환;김승수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.981-987
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    • 1998
  • 원자력 발전 산업의 산업연관분석 결과에 의하면, 원자력 발전의 운영을 통하여 1993년에 국내총산출액 및 국내총생산의 0.5%를 생산하고 있는 것으로 나타났다 원자력 발전 산업의 생산물인 전력은 다른 산업의 생산활동을 위한 중간재로서 활발히 이용되고 있는 바, 이에 대한 지표인 중간수요비 즉 전방연관효과가 전체 산업평균 보다 높은 것으로 나타났다. 반면에 원자력 발전 산업 자체의 생산활동에서 필요로 하는 중간재에 대한 수요 즉, 후방연관효과는 전체 산업평균 보다 상당히 낮은 것으로 나타났다. 한편 원자력 발전 산업의 부가가치율은 다른 발전 산업 중에서 가장 높아서 경쟁관계에 있는 화력 발전산업에 비해 2배 이상의 부가가치를 창출하는 것으로 분석되었다. 원자력 건설 산업의 경제활동이 국민경제에 미치는 파급효과를 살펴보면 생산유발계수가 정부투자와 민간투자에 비해 높아 생산파급효과가 상대적으로 더 큰 것을 알 수 있다 그러나 수입유발계수는 정부투자와 민간투자에 비해 다소 높은 것으로 나타났다.

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The Activity Coefficients of Tri-n-butylphosphate and Europium Complex in the Extraction of Europium by Tri-n-butylphosphate in Nitric Acid Solution (질산유로퓸을 TBP 로 추출할때 TBP와 유로퓸착물의 활동도계수간의 관계)

  • Gang, Ik Gyun
    • Journal of the Korean Chemical Society
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    • v.18 no.4
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    • pp.272-277
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    • 1974
  • A relationship between the activity coefficients of tri-n-butylphosphate(TBP) and europium complex was studied in the extraction of europium by TBP in nitric acid solution. Diluents chosen are cyclohexane, toluene, benzene and chlorobenzene. Concentrations of TBP were varied from 5 to 50 by volume percent and the composition of inorganic layer was kept constant. A method of estimating the solubility parameter of TBP is suggested.

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Study on the Fatigue Crack Behavior by the Stress Intensity Factor and AE Parameters (응력확대계수와 음향방출 변수를 이용한 피로균열 거동 연구)

  • Yoon, Dong-Jin;Jeong, Jung-Chae;Park, Phi-Lip;Kim, Ki-Bok;Lee, Seung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.5
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    • pp.412-423
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    • 2000
  • By using the relation between stress intensity factor and AE parameter, new approach method for assessing the crack length and detectability of crack was proposed. Laboratory experiment was carried out to identify AE characteristics of fatigue cracks for compact tension specimen. The relationship between a stress intensity factor and AE signals activity as well as conventional AE parameter analysis was discussed. As a result, the features of specific parameter such as the length of crack growth the AE energy, the AE peak amplitude, and the cumulative AE hits, showed the almost same trend in their increase as the number of fatigue cycle increased. From the comparisons of peak amplitude and AE energy with stress intensity factor, it was verified that the higher stress intensity factors generated AE signals with higher peak amplitude and a larger number of AE counts. If we can get more reliable database for the relation between AE parameters and stress intensity factor, this approach will provide a good information for evaluating both the existence of crack and the minimum detectable size of crack.

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The Value Relevance of Advertising Activity based on R&D Intensity and Export Ratio (매출액영업이익률, 매출액성장률, 부채비율 및 기업규모를 고려하여 살펴본 광고선전활동이 기업가치에 미치는 영향 : 한국 제조업 기업을 대상으로 한 연구개발집약도 및 수출비중의 조절효과 분석)

  • Kim, Jinsu;Kwon, Gee Jung
    • International Area Studies Review
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    • v.14 no.3
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    • pp.312-338
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    • 2010
  • This paper investigates the value relevance of advertising activity over the period from 2001 to 2009 in the listed Korean stock markets(KOSPI and KOSDAQ). In addition, this paper divide all sample firm into several subsample, based on R&D intensity and export ratio in total sales. The empirical result of this paper shows following two evidence; First, advertising intensity, which proxies for advertising activity, is significantly related to firm value at the 1% level of significance. Second, advertising activity of high R&D intensity and high export ratio sample firms has more significant value relevance than for firms with low R&D intensity and low export ratio. The empirical results suggest that moderation effect of R&D intensity and export ratio are very important factor in determining the value relevance of advertising activity.

The Validity of Activity Participation Assessment for School-Age Children (학령기 아동을 위한 활동 참여 평가도구(Activity Participation Assessment)의 타당도 연구)

  • Kim, Se-Yun
    • The Journal of Korean Academy of Sensory Integration
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    • v.17 no.1
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    • pp.19-29
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    • 2019
  • Objective : The aim of this study was to verify validity of the Activity Participation Assessment for school-age children. Methods : A questionnaire consisting of 30 items from the APA, 75 items from the PACS, and 55 items from the CAPE was administered to elementary school students. A total of 207 questionnaires were analyzed. Confirmatory factor analysis was performed to confirm the construct validity of the APA. Convergence validity and discriminant validity were verified with the average variance extracted (AVE) and the square of the correlation coefficient. The discriminant validity was the Pearson correlation coefficient of the APA, PACS, and CAPE. Results : The results of the analysis were as follows: 1) For construct validity, the goodness of fit of the modified hierarchical second-order factor model was found to be appropriate (p < .001), 2) For convergent validity, the AVE was higher than .50 for all latent variables, 3) For discriminant validity, the AVE of the latent variable was greater than the square of the correlation coefficient (0.239), 4) For concurrent validity, the correlation between the total sum of the APA and PACS scores showed a positive correlation in all domains, and the correlation coefficient ranged from .303 to .647 at a statistically significant level (p < .01), 5) The correlation coefficient between the total sum of the APA and CAPE scores was .490 for recreational activities, .329 for physical activities, .571 for social activities, .401 for skill-based activities, and .390 for self-improvement activities. All domains showed a positive correlation, and were statistically significant (p < .01). Conclusion : APA can be used as a valid assessment tool to measure the participation of school aged children.