• Title/Summary/Keyword: 활동거동

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Distribution Behavior of Natural Radionuclide Pb in Molten Fe to Metal/Slag/Gas Phase (용융 Fe 중 천연방사성핵종 Pb의 금속/슬래그/가스상으로의 분배거동)

  • So-Yeong Lee;Hyeon-Soo Kim;Jong-Hyeon Lee;Ho-Sang Sohn
    • Resources Recycling
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    • v.33 no.2
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    • pp.54-61
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    • 2024
  • When steel contaminated with Pb, produced by the decay of natural radionuclides, is remelted, Pb distributes among the metal, slag, and gas phases. In this study, 5 wt%Pb was added to Fe and melted with CaO-SiO2-Al2O3-MgO slag to investigate Pb's distribution in the metal/slag/gas. As slag basicity ((wt%CaO)/(wt%SiO2)) increased, Pb solubility in Fe slightly increased, while Pb in the slag tended to decrease. Consequently, the slag/metal distribution ratio of Pb decreased with increasing basicity. Thermodynamic calculations revealed that the slag/Fe phase distribution ratio of Pb remained very low irrespective of the activity coefficient of PbO in the slag, consistent with the experimental results. The calculated evaporation rate of Pb in Fe-Pb was approximately 22 times that of Fe; hence, most of the Pb evaporated into the gas phase.

A Study on the Change of Tensile Force of Friction Type Anchor under Shear Deformation of Ground (지반의 전단변형에 따른 마찰형 앵커의 긴장력 변화에 대한 연구)

  • You, Min-Ku;Kwon, O-Il;Lee, Sang-Duk
    • Journal of the Korean Geotechnical Society
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    • v.34 no.4
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    • pp.13-25
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    • 2018
  • When deformation occurs on slope reinforced with anchor, shear stress and bending stress are applied on the shear surface along the slip surface and increase of the shear deformation causes the tension force variation of the anchor. In this study, shear test was performed by measuring the tension force of the anchor by inducing shear deformation in vertical direction of the anchor using a large-scale direct shear test equipment in order to confirm the tension force variation of the anchor induced by shear deformation. The shear test was performed for 8 conditions which were classified according to the anchor reinforcement, separation distance (1D, 2D, 4D) from the shear surface to bonded part and the lateral-pressure condition (0.1 MPa, 0.2 MPa) of adjacent ground. As a result of the shear test, it was found that the separation distance and the lateral-pressure condition affect the shear force of the ground reinforced by anchor and the tension force of the anchor, and experimentally verified that the shear force variation is related to axial force variation of the anchor head and tip. Therefore, it was confirmed that the behavior of the bonded part induced by the shear deformation can be indirectly predicted by analyzing the tendency of the tension force variation of the anchor head.

Effect of Joint Cohesive Strength on the Earth Pressure against the Support System in a Jointed Rock Mass (절리형성 암반지층 굴착벽체 작용토압에 대한 절리 점착강도의 영향)

  • Son, Moorak;Solomon, Adedokun
    • Journal of the Korean Geotechnical Society
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    • v.30 no.7
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    • pp.41-53
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    • 2014
  • This study examined the magnitude and distribution of the earth pressure on the support system in a jointed rock mass by considering different joint shear strength, rock type, and joint inclination angle. The study particularly focused on the effect of joint cohesive strength for a certain condition. Based on a physical model test (Son and Park, 2014), extended parametric studies were conducted considering rock-structure interactions based on the discrete element method, which can consider the rock and joint characteristics of rock mass. The results showed the earth pressure was strongly affected by the joint cohesive strength as well as the rock type and joint inclination angle. The study indicated that the effect of joint cohesive strength was particularly significant when a rock mass was under the condition of joint sliding. This paper investigates the magnitude of joint cohesive strength to prevent a joint sliding for each different condition. The test results were also compared with Peck's earth pressure, which has been frequently used for soil ground. The comparison indicated that the earth pressure in a jointed rock mass can be significantly different from that in soil ground. This study is expected to provide a better understanding of the earth pressure on the support system in a jointed rock mass.

Diversity of the Cretaceous basaltic volcanics in Gyeongsang Basin, Korea (경상분지내 백악기 현무암질 화산암류의 다양성)

  • 김상욱;황상구;이윤종;고인석
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.1-12
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    • 2000
  • The Cretaceous basaltic rocks in Gyeongsang Basin are temporally and spatially dispersed widely in thick sedimentary piles: Chilgog basaltic rock (CGB) and Cheongyongsa basaltic rock (CSB) in the Shindong Group, and Hakbong basaltic rocks (HBB), Osibbong basalt (OSB), Secheondong basaltic rocks (SCB), Haman basaltic rocks (HAB), Hama basaltic rocks (HMB), and Chaeyaksan basaltic rocks (CYB) in the Hayang Group, upwardly in their stratigraphy. Chilgog basaltic rock is merely identified as pebbles in the Shilla Conglomerate and its provenance has not been found, and it is characteristics that the volcanics except Osibbong basalt and Chaeyaksan basaltic rocks are very small in both of their thickness and extension. Petrochemical diversity of the basaltic rocks are revealed; OSB and SCB distributed in the Yeongyang Minor Basin preserve the calc-alkaline natures in major and immobile minor element geochemistry, but CGB, HBB, HAB, and CYB reflect that they might be originated from calc-alkaline basaltic magma of volcanic arc in continental margin area by trace elements and altered to alkaline suites in the viewpoint of their major element geochemistry. Major and trace element geochemistry of CSB and HMB suggests that they may be derived from within -plate alkaline magma contaminated by the upper continental crust, especially in the case of the former.

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Pervaporation Characteristics of Water/Ethanol and Water/Isopropyl Alcohol Mixtures through Zeolite 4A Membranes: Activity Coefficient Model and Maxwell Stefan Model (제올라이트 4A 분리막을 이용한 물/에탄올, 물/이소프로필알코올 혼합물의 투과증발 특성 연구 : 활동도계수모형 및 Generalized Maxwell Stefan 모형)

  • Oh, Woong Jin;Jung, Jae-Chil;Lee, Jung Hyun;Yeo, Jeong-gu;Lee, Da Hun;Park, Young Cheol;Kim, Hyunuk;Lee, Dong-Ho;Cho, Churl-Hee;Moon, Jong-Ho
    • Clean Technology
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    • v.24 no.3
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    • pp.239-248
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    • 2018
  • In this study, pervaporation experiments of water, ethanol and IPA (Isopropyl alcohol) single components and water/ethanol, water/IPA mixtures were carried out using zeolite 4A membranes developed by Fine Tech Co. Ltd. Those membranes were fabricated by hydrothermal synthesis (growth in hydrothermal condition) after uniformly dispersing the zeolite seeds on the tubular alumina supports. They have a pore size of about $4{\AA}$ by ion exchange of $Na^+$ to the LTA structure with Si/Al ratio of 1.0, and shows strong hydrophilic property. Physical characteristics of prepared membranes were evaluated by using SEM (surface morphology), porosimetry (macro- or meso- pore analysis), BET (micropore analysis), and load tester (compressive strength). Pervaporation experiments with various temperature and concentration conditions confirmed that the zeolite 4A membrane can selectively separate water from ethanol and IPA. Water/ethanol separation factor was over 3,000 and water/IPA separation factor was over 1,500 (50 : 50 wt%, initial feed concentration). Pervaporation behaviors of single components and binary mixtures were predicted using ACM (activity coefficient model), GMS (generalized Maxwell Stefan) model and DGM (Dusty Gas Model). The adsorption and diffusion coefficients of the zeolite top layer were obtained by parameter estimation using GA (Genetic Algorithm, stochastic optimization method). All the calculations were carried out using MATLAB 2018a version.

Slope Stability Analysis of Unsaturated Soil in Debris-Flow Occurrence Slopes (토석류 발생 사면의 불포화토 사면안정해석)

  • Kwak, Cheol-Soo;Park, Byung-Soo;Yoo, Nam-Jae
    • Journal of the Korean Geotechnical Society
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    • v.28 no.9
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    • pp.23-30
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    • 2012
  • This paper is research results of slope stability analysis associated with seepage infiltration for unsaturated soil in debris-flow occurrence slopes. Site investigations were carried out in two slopes, located at Inje in Kangwon province where debris flow occurred in 2006 and at Yangpyung in Kyeunggi province where it occurred in 2010. For unsaturated soil sampled at the zone of debris-flow initiation, soil water characteristic curves with tempe pressure cells and shear strength parameters with newly designed shear strength apparatus were obtained respectively. The commertially available software SEEP/W was used to analyze seepage infiltration in unsaturated soil, based on their properties obtained from test results and the actual rainfall data at the moment of debris flow occurrence, and slope stability analysis with the program of SLOPE/W, associated with results of seepage analysis, was performed to simulate slope failure. As results of this research, seepage infiltration to unsaturated soil due to intensive rainfall was found to cause increase of ground water table as well as degree of saturation. Through this research slope stability analysis for unsaturated soil, considering the actual rainfall characteristic, might be a reasonable method of investigating characteristics of debris flow behavior, in particular, the moment of debris flow occurrence.

Shallow subsurface structure of the Vulcano-Lipari volcanic complex, Italy, constrained by helicopter-borne aeromagnetic surveys (고해상도 항공자력탐사를 이용한 Italia Vulcano-Lipari 화산 복합체의 천부 지하 구조)

  • Okuma, Shigeo;Nakatsuka, Tadashi;Komazawa, Masao;Sugihara, Mitsuhiko;Nakano, Shun;Furukawa, Ryuta;Supper, Robert
    • Geophysics and Geophysical Exploration
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    • v.9 no.1
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    • pp.129-138
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    • 2006
  • Helicopter-borne aeromagnetic surveys at two different times separated by three years were conducted to better understand the shallow subsurface structure of the Vulcano and Lipari volcanic complex, Aeolian Islands, southern Italy, and also to monitor the volcanic activity of the area. As there was no meaningful difference between the two magnetic datasets to imply an apparent change of the volcanic activity, the datasets were merged to produce an aeromagnetic map with wider coverage than was given by a single dataset. Apparent magnetisation intensity mapping was applied to terrain-corrected magnetic anomalies, and showed local magnetisation highs in and around Fossa Cone, suggesting heterogeneity of the cone. Magnetic modelling was conducted for three of those magnetisation highs. Each model implied the presence of concealed volcanic products overlain by pyroclastic rocks from the Fossa crater. The model for the Fossa crater area suggests a buried trachytic lava flow on the southern edge of the present crater. The magnetic model at Forgia Vecchia suggests that phreatic cones can be interpreted as resulting from a concealed eruptive centre, with thick latitic lavas that fill up Fossa Caldera. However, the distribution of lavas seems to be limited to a smaller area than was expected from drilling results. This can be explained partly by alteration of the lavas by intense hydrothermal activity, as seen at geothermal areas close to Porto Levante. The magnetic model at the north-eastern Fossa Cone implies that thick lavas accumulated as another eruption centre in the early stage of the activity of Fossa. Recent geoelectric surveys showed high-resistivity zones in the areas of the last two magnetic models.

Investigations of Application of Anchor Type Nail Using Experiments and Numerical Analysis (모형실험 및 수치해석을 이용한 앵커형 네일의 적용성 검토)

  • Kim, Donggun;Jeong, Gilsu;Jo, Kwangjun;Yoo, Namjae;Um, Jaekyung
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.11
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    • pp.19-26
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    • 2012
  • In the present study, anchor type nail with PC-strand which can add up the pre-stress at the nailing to increase the resistance and shear stress in the whole ground has been investigated. Load-displacement and wall displacement have been analyzed by experimental model and numerical analysis of anchor type nail, nailing, and non-nailing to examine the behavior of anchor type nail. From the experimental results, it was found that horizontal displacement is considerably decreased according to increasing the load in case of anchor type nail added pre-tension. Especially, it was observed that resistance of displacement at the upper wall is increased. The results of numerical analysis show the same results of experimental results.

Stability Evaluation of Green Wall System due to Facing Rigidity (전면벽체 강성에 따른 그린월 시스템의 안정성 평가)

  • Park, Si-Sam;Kim, Hong-Taek;Kim, Seung-Wook;Kim, Yong-Eon
    • Journal of the Korean Geosynthetics Society
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    • v.5 no.3
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    • pp.9-15
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    • 2006
  • The Green Wall system is one of segmental concrete crib type earth retaining wall. Green wall is constructed as procedures that lay the front stretchers, rear stretchers and headers then making a rigid body through harden filled soil of interior cell. Recently, Green Wall method is applied in variable cutting ground construction because of advantage which minimize to cut base ground. In case of Green Wall method is constructed with soil nail method, expect that total system stability will increase more than flexible facing because of facing stiffness is big. However, in this case of design, facing stiffness is not considered so that is poor economy. Hence, in this study, stability increasing effect of total system analyze about that soil nail method is constructed with rigidity facing like a Green Wall method. In present study, laboratory model tests was performed for analysis on stability increasing effect of total system about changing stiffness of facing. LEM analysis conducted for evaluation on safety factor of total system sliding that facing condition changed.

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Behavior of Refractory Organic Matter in Leachate from Landfill Contaminated by Foot-and-mouth Disease (구제역 매몰지역 침출수에서 발생하는 난분해성 유기물질 거동)

  • Kang, Meea;An, Yaesol
    • The Journal of Engineering Geology
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    • v.23 no.4
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    • pp.427-434
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    • 2013
  • The leachate from landfill (Andong city) contaminated by foot-and-mouth disease (FMD) contains 44%-50% hydrophilic organic matter, compared with 22%-27% in natural water bodies such as ground water, lake water, and river water. In such natural water, the organic matter content is reduced by the metabolism of microbes in the water. However, in the case of leachate-1 and -2, the concentrations of RTOC (refractory total organic carbon) and RDOC (refractory dissolved organic carbon) were higher than the initial TOC and DOC after burial. According to time elapsed after burial, the concentrations of RTOC and RDOC were decreased below the initial TOC and DOC. In the case of leachate-6 (386 days after burial), RDOC made up 91% of RTOC. This result shows that organic matter in the leachate was composed dominantly of RDOM, most of which was not removed by the metabolism of microbes. Hence, the presence and characteristics of RDOM provide a valuable indication of the effect of leachate on the quality of surface water and ground water. Such information is useful in understanding leachate environments.