• Journal of the Korean earth science society
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• v.44 no.6
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• pp.629-642
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• 2023

Currently, low and intermediate level radioactive waste is being disposed of at the Gyeongju disposal site for permanent isolation. Since 2006, the Korea Radioactive Waste Agency has been conducting site characteristics surveys continuously verifying changes in the site based on the site monitoring and investigation plan. The hydrogeochemical environment of the disposal site is considered for the evaluation of natural barriers. However, the seawater must be considered because of the regional characteristics of Gyeongju, which is near the East Sea. Therefore, this study, collected 30 samples for deriving the groundwater quality data from seven wells and compared with two seawater samples collected from October 2017 to June 2022. Additionally, the study explores the groundwater monitoring method using statistical tools such as clustering and background concentration analysis. The groundwater samples in the study area were classified into two to four clusters depending on their chemical constituents-especially, EC, HCO₃, Na, and Cl-using statistical analysis, molar ratio, and K-means clustering.

• The Journal of Engineering Geology
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• v.10 no.2
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• pp.215-233
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• 2000

The national geochemical baseline mapping project has been conducted since 1996 to establish a quantitative assessment system for geochemical hazards in natural environments. The geochemical image maps have been edited for thirty-six elements(i.e., 10 major oxides and 26 trace elements) in light sediments, finer fraction than 150 $\mu$m, collected from first- to second-order streams(totally 11,000) over five provinces in the western half(ca. 45,000 km$^2$) of Korea. Natural background values of the elements were given for different geological environments. Based on the statistics, geochemical baselines were newly obtained for a quantitative hazard assessment on toxicity of heavy metals and deficiency of essential nutrients. Some chosen examples of geochemical hazards are presented based on new geochemical image maps and related baseline data.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.5C
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• pp.217-228
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• 2009

In case of application of electrophoresis method for leakage restoration of waste impoundment, main points of consideration were to evaluate the mobility of clay particles by electrophoretic force and capacity of leakage repair in leachate electrolyte system contained with various chemical species. However, the flocculation phenomena of clay particles induced by electrochemical interaction between various chemical species and clay particles would cause the big problems in electrophoresis method. Therefore, a series of laboratory tests such as one-dimensional electrophoresis and gravitational experiments were carried out in order to identify the specific chemical species affected flocculation of clay particles and the range of chemical concentration in leachate. In addition, the characteristics of clay particle behavior with chemical species and concentration range in leachate were analized using the concept of the settling velocity, zeta potential, and electrophoretic velocity.

• Environmental engineer
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• s.323
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• pp.2-8
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• 2013

"대학 4년동안 환경공학을 공부한 젊은이들이 졸업 후 일자리를 찾지 못한다면, 우리의 미래는 암담합니다. 최근 유해화학물질 유출사고도 이와 무관하지 않습니다. 한국물환경학회는 환경인의 전문성을 인정받고 일자리를 확충하는 일에 앞장 설 것입니다." 지난 5월 (사)한국물환경학회 제15대 회장에 취임한 장덕진 회장(명지대 환경에너지공학과 교수)은 물산업 발전과 고용창출을 강조했다. 장 회장은 또한 학회의 발전을 위해 최우선적으로 회원확보에 주력할 뜻을 밝혔으며, 좋은 논문을 발굴하여 학술지의 질적 향상에도 기여하겠다고 밝혔다. 다음은 장덕진 회장과의 인터뷰 내용이다.

• Economic and Environmental Geology
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• v.56 no.6
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• pp.729-744
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• 2023

The value of lithium has significantly increased due to the rising demand for electric cars and batteries. Lithium is primarily found in pegmatites, hydrothermally altered tuffaceous clays, and continental brines. Globally, groundwater-fed salt lakes and oil field brines are attracting attention as major sources of lithium in continental brines, accounting for about 70% of global lithium production. Recently, deep groundwater, especially geothermal water, is also studied for a potential source of lithium. Lithium concentrations in deep groundwater can increase through substantial water-rock reaction and mixing with brines. For the exploration of lithim in deep groundwater, it is important to understand its origin and behavior. Therefore, based on a nationwide preliminary study on the hydrogeochemical characteristics and evolution of thermal groundwater in South Korea, this study aims to investigate the distribution of lithium in the deep groundwater environment and understand the geochemical factors that affect its concentration. A total of 555 thermal groundwater samples were classified into five hydrochemical types showing distinct hydrogeochemical evolution. To investigate the enrichment mechanism, samples (n = 56) with lithium concentrations exceeding the 90th percentile (0.94 mg/L) were studied in detail. Lithium concentrations varied depending upon the type, with Na(Ca)-Cl type being the highest, followed by Ca(Na)-SO₄ type and low-pH Ca(Na)-HCO₃ type. In the Ca(Na)-Cl type, lithium enrichment is due to reverse cation exchange due to seawater intrusion. The enrichment of dissolved lithium in the Ca(Na)-SO₄ type groundwater occurring in Cretaceous volcanic sedimentary basins is related to the occurrence of hydrothermally altered clay minerals and volcanic activities, while enriched lithium in the low-pH Ca(Na)-HCO₃ type groundwater is due to enhanced weathering of basement rocks by ascending deep CO₂. This reconnaissance geochemical study provides valuable insights into hydrogeochemical evolution and economic lithium exploration in deep geologic environments.

• Economic and Environmental Geology
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• v.34 no.3
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• pp.255-269
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• 2001

The geochemical studies on groundwater in the borehole, which is straddled by multi-packer (MP) system, were carried out from a volcanic terrain in the Yeosu area. The pH of groundwater collected from selected sections in the MP-installed borehole is much higher (up to 9.6) than that of the borehole groundwater (7.0-7.9) collected using conventional pumping technique. Hydrochemistry shows that the groundwater has a typical chemical change with increasing sampling depth, suggesting that the groundwater is evolved through water-rock interaction along the fracture-controlled flow paths. The groundwater from the deeper part (138-175 m below the surface) in borehole KI is characterized by the Ca-C11 type with high Ca (up to 160 mg/L) and Cl (up to 293 mg/L) contents, probably reflecting seawater intrusion. The groundwater also has high sodium and sulfate contents compared to the waters from other boreholes. These observed groundwater chemistry is explained by the cation exchange, sulfide oxidation, and mixing process with seawater along the flow path.

• Economic and Environmental Geology
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• v.46 no.4
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• pp.359-373
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• 2013

Shale is considered as a source rock for conventional oil and gas exploration and development because shale is fine-grained detrital sedimentary rock which can preserve the organic matter better. Shale has a good sealing capacity for the petroleum trap due to its low permeability. Commercial recoveries of gas from shale in the North America based on the development of technologies of horizontal drilling and hydraulic fracturing reveal that shale also function as a effective reservoir rock. Geochemical techniques to evaluate generation potential of the hydrocarbons from organic matter in the source rocks can be applied for the exploration of the shale gas resources. To evaluate shale gas resources, it is important to understand various geochemical processes and shale characteristics controlling generation, storage and estimation of shale gas reserves. In this paper, the generation mechanism of the oil and gas from organic matter is reviewed, and geochemical techniques which can be applied for the evaluation and characterization of shale gas are introduced.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.337-338
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• 2002

VOCs는 독성이 있고 돌연변이성, 발암성, 기형성을 유발하는 물질로 알려져 있으며 특히 대기질에서는 오존과 광화학스모그의 전구체로서 대기환경오염의 주요지표로 이용하는 국가가 증가하는 추세이다. 우리나라에서는 1999년부터 대기환경보전법 제8조 2항 규정에 의하여 대기환경규제지역내 (석유화학 정제업, 자동차 제조업, 주유소, 자동차 정비업소, 세탁시설, 기타제조업 등) VOCs를 규제토록 되어 있다(환경부, 1999). (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2008.10a
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• pp.307-308
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• 2008

• Proceedings of the KSEEG Conference
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• 2007.04a
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• pp.180-182
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• 2007