• Journal of Korea Soil Environment Society
• /
• v.2 no.2
• /
• pp.81-94
• /
• 1997

In many solute transport studies, either flux or resident concentration has been used. Choice of the concentration mode was dependent on the monitoring device in solute displacement experiments. It has been accepted that no priority exists in the selection of concentration mode in the study of solute transport. It would be questionable, however, to accept the equivalency in the solute transport parameters between flux and resident concentrations in structured soils exhibiting preferential movement of solute. In this study, we investigate how they differ in the monitored breakthrough curves (BTCs) and transport parameters for a given boundary and flow condition by performing solute displacement experiments on a number of undisturbed soil columns. Both flux and resident concentrations have been simultaneously obtained by monitoring the effluent and resistance of the horizontally-positioned TDR probes. Two different solute transport models namely, convection-dispersion equation (CDE) and convective lognormal transfer function (CLT) models, were fitted to the observed breakthrough data in order to quantify the difference between two concentration modes. The study reveals that soil columns having relatively high flux densities exhibited great differences in the degree of peak concentration and travel time of peak between flux and resident concentrations. The peak concentration in flux mode was several times higher than that in resident one. Accordingly, the estimated parameters of flux mode differed greatly from those of resident mode and the difference was more pronounced in CDE than CLT model. Especially in CDE model, the parameters of flux mode were much higher than those of resident mode. This was mainly due to the bypassing of solute through soil macropores and failure of the equilibrium CDE model to adequate description of solute transport in studied soils. In the domain of the relationship between the ratio of hydrodynamic dispersion to molecular diffusion and the peclet number, both concentrations fall on a zone of predominant mechanical dispersion. However, it appears that more molecular diffusion contributes to the solute spreading in the matrix region than the macropore region due to the nonliearity present in the pore water velocity and dispersion coefficient relationship.

• Korean Journal of Soil Science and Fertilizer
• /
• v.37 no.4
• /
• pp.212-219
• /
• 2004

To minimize the danger of soil erosion and settle habitats earlier, afforestation, which vegetates bare slopes, is selected as an environmental recovering technology. Large portions of these areas often are suffered by a bad germination and growth inhibition of sprayed seeds. Afforested materials collected in the normal and damaged sites were not any big difference in chemical characteristics and biological response to ryegrass. But background soil of the damaged site has very low pH (3.6) and high contents of iron and aluminum compared with them of the normal sites. Both germination and root growth of ryegrass were inhibited severely in the water extracts of damaged soils, but not in the water extracts of normal sites. Groundwater collected nearby the damaged sites was very strong acidic (pH 33) and exhibited a high value of electrical conductivity and high contents of iron and aluminum. In the ground water, germinated ryegrass was scarcely grown. In Al standard solution, the root growth of ryegrass was inhibited over 50% in 0.5 mM in pH 3.5-4.5 and in 1.4 mM in pH 5.5, which seems to be related to $Al^{3+}$ activity in solution. In the ferric Fe ($Fe^{3+}$) standard solution, ryegrass growth was inhibited over 50% in the concentration of 14-19 mM in root and 23-25 mM in shoot. This strong tolerance of ryegrass to $Fe^{3+}$ might be concerned with the very low activity of $Fe^{3+}$ at pH 3.5-5.5. In contrast, ryegrass responded very sensitively to ferrous Fe ion ($Fe^{2+}$), especially in root growth: $Fe^{2+}$ concentrations corresponding to 50% growth reduction were 0.3-0.4 mM at pH 3.5-5.5 in roots. This high growth inhibition should be related to the high ion activity of $Fe^{2+}$ irrespective of different pH conditions. In conclusion, low pH and high contents of $Fe^{2+}$ and aluminum seem to be caused by pyrite and be closely related to the growth inhibition of ryegrass seeded in afforested area.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.18 no.2
• /
• pp.64-73
• /
• 2015

The distributions of Pb and Cd concentrations in the surface seawater of the East Sea were investigated during the R/V Lavrentyev cruise (July 2009) in which four transects from Russia shore to South were conducted to collect 26 surface water samples. The total dissolved concentrations of Pb and Cd were measured using ICP-MS (Perkin Elmer, DRC-e). In the coastal area, their concentrations of Russia shore (Pb, 0.08; Cd, 0.10 nM) were comparable for Cd but on the other hand, 6 times lower for Pb than Korea shore (Pb, 0.49; Cd, 0.11 nM). In the subregion, their concentrations of Warm region (Pb, 0.22; Cd, 0.01 nM) were about 1.7 times higher for Pb but 0.4 lower for Cd than Cold region (Pb, 0.13; Cd, 0.14 nM). The distributions of Pb and Cd concentrations were divided by lowest level at $10^{\circ}C$ of water temperature. Below $10^{\circ}C$, Pb and Cd concentrations increased when surface water temperatures decreased. Above $10^{\circ}C$, their concentrations increased with temperature, which showed highest concentrations in the Ulleung basin, directly influenced by flux from East Korean Warm Current and neighboring countrys (Korea and Japan). Specially, in the case of Pb, the concentrations decrease remarkablely with temperatures decrease from D10 directly influenced by flux from East Korean Warm Current, which shows highest Pb level. By comparing with other sea areas (Western Mediterranean, East Pacific), Pb concentrations in the East Sea were a little higher. The influence of East Korean Warm Current and neighboring countrys (Korea and Japan) may be relatively important. Therefore, the distribution of Cd may primarily be influenced by mixing of different water masses while the distribution of Pb may mainly be influenced by flux from East Korean Warm Current and atmospheric inputs. River inputs and interaction with particulate materials may also some roles for the distribution of these elements.

• Economic and Environmental Geology
• /
• v.41 no.1
• /
• pp.63-79
• /
• 2008

Physicochemical characteristics of stream water, leachate, mine water and groundwater were investigated to estimate the influences of the tailing and waste rock from the abandoned Uljin mine area. Total extraction analysis and mineralogical studies were carried out to understand sulfide weathering and to determine the distributions of trace elements in the soil affected by mine waste (tailing, waste rock and leachate). The pH and EC value of the leachate from the tailing disposal ranged 2.9-6.0, $99{\sim}3,990{\mu}S/cm$, respectively, and the concentrations of dissolved major (up to 492 mg/l Ca; 83.8 mg/l Mg; 45.2 mg/l Na; 44.7 mg/l K, 50.8 mg/l Si) and trace elements (up to $826,060{\mu}g/l$ Fe; $131,230{\mu}g/l$ Mn; $333,600{\mu}g/l$ Al; $61,340{\mu}g/l$ Zn; $2,530{\mu}g/l$ Cu; $573{\mu}g/l$ Cd; $476{\mu}g/l$ Pb) were relatively high. The stream water showed the variation of dissolved metal concentrations in seasonally and spatially. The dissolved metal contents of the stream water increased by influx the leachate from the tailing disposal, but these of the down stream have been considerably decreased by mixing of dilute tributaries. The dissolved metal concentrations of the stream water at dry season (as February) were lower than these at rainy season (as May and July). These represent that the amounts of the leachate varied with season. However, stream water could not be effectively diluted by confluence with uncontaminated tributaries, because the flux of tributaries and streams reduced at dry season. Thus attenuations by dilution had been dominantly happened in rainy seasons. The order of accumulations of trace element in soils compared with background values revealed Mn>Fe>Pb>Cu>Zn. Sulfide minerals were mainly pyrrhotite, sphalerite and galena and chalcopyrite. Pyrrhotite was rapidly weathered along the edge and fractures, and results in the formation of Fe-(oxy)hydroxides, which absorbed a little amount of Zn.

• Korean Journal of Environmental Agriculture
• /
• v.35 no.4
• /
• pp.286-293
• /
• 2016

BACKGROUND: 18% of difenoconazole+iminoctadin triacetate microemulsion (3%+15%) formulation were mixed and sprayed as closely as possible to normal practice on the ten of farms located in the Youngju of South Korea. Patches, cotton gloves, socks, masks and XAD-2 resin were used to measure the potential exposure for applicators wearing standardized whole-body outer and inner dosimeter (WBD). This study has been carried out to determine the dermal and inhalation exposure to difenoconazole during preparation of spray suspension and application with a power sprayer on a grape orchard. METHODS AND RESULTS: A personal air monitor equipped with an air pump IOM sampler and cassette and glass fiber filter were used for inhalation exposure. The field studies were carried out in a grape orchard. The temperature and relative humidity were monitored with a thermometer and a hygrometer. Wind speed was measured using a pocket weather meter. All mean field fortification recoveries were between 97.3% and 119.6% in the level of 100 LOQ (limit of quantification) while the LOQ for difenoconazole was $0.025{\mu}g/mL$ using HPLC-UVD. The arms exposure to difenoconazole for the mixer/loader (0.0794 mg) was higher than other body parts (head, hands, upper body, legs). The exposure to difenoconazole in the legs for applicator (3.78 mg) was highest in the parts of body. The dermal exposure for mixer/loader and applicator were 0.02 and 2.28 mg on a grape orchard, respectively. The inhalation exposure during application was estimated as 0.02 mg. The ratio of inhalation exposure to dermal exposure was equivalent to 0.9% of the dermal exposure. CONCLUSION: The inhalation exposure for applicator indicated $18.8{\times}10^{-3}mg$, which was level of 0.9% of the dermal exposure (2.28 mg). Operator exposure (0.004 mg/kg bw/day) to difenoconazole during treatment for grape is calculated as 2.5% of the established AOEL (0.16 mg/kg bw/day).

• Korean Journal of Environmental Biology
• /
• v.32 no.2
• /
• pp.138-152
• /
• 2014

The objective of the study survey was to determine the effect of marine sand extraction on community composition and rate of recolonization of the meiobenthos following cessation of mining activities. Because of meiobenthic distribution in nature, high abundance, intimate association with sediments, fast reproduction, benthic larva period, sensitivity to pollution and rapid life histories, meiobenthos are widely regarded as ideal organisms to study the potential ecological indicator of natural and anthropogenic stresses. The community structure of meiobenthos was studied at seven stations within sandy tidal and sub tidal zones in Jangbongdo in the Yellow Sea, Korea from Aug. 2006 to Dec. 2007. Meiobenthic samples were collected by three core samples, with a 3.6 cm in diameter, from each sediment sample taken with a Smith-McIntyre Grab. It was found that sand mining often causes complete removal of the sediment and the damage to the habitats of meiobenthos. This study in the effect showed that sand mining resulted in a reduction in total abundance and biomass of meiobenthos in mining area. The finding of this study further showed that initial restoration of abundance and biomass within one year of the cessation of sand mining.

• Journal of the Korean Society of Groundwater Environment
• /
• v.5 no.2
• /
• pp.88-100
• /
• 1998

Since fractures may serve as major conduits of groundwater flow in crystalline rocks, characterization of conductive fractures is especially important for interpretation of flow system. In this study, characterization of fractures to investigate hydraulically conductive fractures in gneisses at an abandoned mine area was performed. The orientation, width, length, movement sense, infilling materials, spacing, aperture, roughness of both joints and faults and intersection and connectivity to other joints were measured on outcrops. In addition, characteristics of subsurface fractures were examined by core logging in five boreholes, of which the orientations were acquired by acoustic televiewer logging from three boreholes. The dominant fracture sets were grouped from outcrops; GSet 1: N50-82$^{\circ}$E/55-90$^{\circ}$SE, GSet 2: N2-8$^{\circ}$E/56-86$^{\circ}$SE, GSet 3: N46-72$^{\circ}$W/60-85$^{\circ}$NE, GSet 4:Nl2-38$^{\circ}$W/15-40$^{\circ}$SW and from subsurface; HSet 1: N50-90$^{\circ}$E/55-90$^{\circ}$SE, HSet 2: N10-30$^{\circ}$E/50-70$^{\circ}$SE, HSet 3: N20-60$^{\circ}$W/50-80$^{\circ}$NE, HSet 4: N10-50$^{\circ}$E/$\leq$40$^{\circ}$NW. Among them, GSet 1, GSet 3 and HSet 1, HSet 3 are the most intensely developed fracture sets in the study area. The mean fracture spacings of HSet 1 are 30-47cm and code 1 fractures, such as faults and open fractures, comprise 21.0-42.9 percent of the whole fractures in each borehole. HSet 3 shows the mean fracture spacings of 55-57cm and the ratio of code 1 fractures is 15.4-26.9 percent. In spite of the mean fracture spacing of 239cm, code 1 fractures of HSet 4 have the highest ratio of 54.5 percent. From the fact that faults or open fractures have high hydraulic conductivity, it can be inferred that the three fracture sets of N55-85$^{\circ}$E/50-80$^{\circ}$SE, N20-60$^{\circ}$W/50-75$^{\circ}$NE and N10-30$^{\circ}$E/$\leq$30$^{\circ}$NW from a fracture system of relatively high conductivity. It is indirectly verified with geophysical loggings and constant injection tests performed in the boreholes.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.5 no.1
• /
• pp.27-36
• /
• 2000

We investigated the phytoplankton community from June to September 1997 in the waters off Kohung, Korea where red tides dominated by harmful dinoflagellates had occurred from August to September or October since 1995. We took water samples five times from 5 depths at 6 or less stations in this study period. The most dominant harmful dinoflagellate during the red tide which had outbroken on August 24, 1997 was Gyrodinium impudicum, not Cochlodinium polykrikoides. On August 21 just before the harmful red tide occurred the abundance of G. impudicum at the inner bay station, 90cells $ml^{-1}$, was higher than that at the outer bay station. However, on August 27 just after the red tide had outbroken, the abundance of G. impudicum at the inner bay station did not increase, whereas that at the outer bay increased rapidly and reached to the maximum of 30,000 cells $ml^{-1}$. Instead, diatoms such as Skeleltonema costatum, Chaetoceros pseudocurvisetus, Pseudonitzschia pungens rapidly increased at the inner bay station where fresh water from lands has reached. The high abundance of diatoms might have inhibited the growth of red tide dinoflagellates at this station. The transport of already formed red tide patches from offshore areas, aggregation of scattered cells driven by physical forces, and/or competition between diatom and dinoflagellates might be responsible for this appearance of dense red tide patches at the outer bay station.

• Economic and Environmental Geology
• /
• v.48 no.5
• /
• pp.409-420
• /
• 2015

The Sangdae-ri riverside around Musimcheon stream, flowing through Gadeok-myon of Cheongju City, is one of the representative strawberry fields employing water curtain cultivation (WCC) in Korea. In this area, annual groundwater use for WCC has been calculated by a few methods. On the assumption that all the water flowing through the final ditch may be mostly composed of groundwater, the discharge rate in it can be used as a good proxy for assessing the groundwater use. However, in the study area, the final ditch was set up in an unpaved state near and parallel to Musimcheon stream. Under such circumstances, the drainwater is likely to be influenced by infiltration and/or inflow of nearby stream. Hence, we examined whether or not stream water has influenced water flowing out through the final ditch in respect of ion concentrations or field parameters such as T, pH and electrical conductivity (EC) values. The period of measuring field parameters and sample collection was from February 2012 through February 2015. The drainwater in the final ditch did not show the average quality of groundwater, but similar quality of stream water in respect of pH, EC, ion contents and water type. From this, it is suggested that measuring the flow rate of the final ditch should not be directly used for assessing groundwater use in the study area. In addition, because of its sensitivity to ambient temperature, water temperature proved not to be appropriate for estimating the interaction between ditch and stream. For accuracy, additional methods will be needed to calculate mixing ratios between stream and ground water within drainage system.

• Economic and Environmental Geology
• /
• v.42 no.4
• /
• pp.315-333
• /
• 2009

In this study, the hydrochemical and the isotopic characteristics of major streams in the Daejeon area were investigated during rainy and dry seasons. The stream water shows the electrical conductivity of the range of $37{\sim}527{\mu}s$/cm, and pH $6.21{\sim}9.83$. The chemical composition of stream waters can be grouped as three types: the upper streams of Ca(Mg)-$HCO_3$ type, Ca(Mg)-$SO_4(Cl)$ type of middle streams flowing through urban area, and Na(Ca)-$HCO_3$(Cl, $SO_4$) type of the down streams. Based on in-situ investigation, the high pH of stream waters flowing through urban area is likely to be caused by the inflow of a synthetic detergent discharging from the apartment complex. The electrical conductivity of stream waters at a dry season is higher than those of at a rainy season. We suggest that the hydro-chemical composition of stream waters in the Daejeon area was affected by the discharging water from the sewage treatment facilities and anthropogenic contaminants as well as the interaction with soil and rocks. ${\delta}D$ and ${\delta}^{18}O$ values of the stream waters show the relationship of ${\delta}D=6.45{\delta}^{18}O-7.4$, which is plotted at a lower area than global meteoric water line(GMWL) of Craig(1961). It is likely that this isotopic range results from the evaporation effect of stram waters and the change of an air mass. The isotope value shows an increasing trend from upper stream to lower stream, that reflects the isotopic altitude effect. The relationship between ${\delta}^{13}C$ and $EpCO_2$ indicates that the carbon as bicarbonate in stream water is mainly originated from $CO_2$ in the air and organic materials. The increasing trend of ${\delta}^{13}C$ value from upper stream waters to lower stream waters can be attributed to the following reasons: (1) an increasing dissolution of $CO_2$ gas from a contaminated air in downtown area of the Daejeon, and (2) the increment of an inorganic carbon of groundwater inflowed into stream by base flow. Based on the relationship between ${\delta}^{34}S$ and $SO_4$ of stream waters, the stream waters can be divided into four groups. $SO_4$ content increases as a following order: upper and middle Gab stream${\delta}^{34}S$ value decreases as above order. ${\delta}^{34}S$ value indicates that sulfur of stream waters is mainly originated from atmosphere, and is additionally supplied by pyrite source according to the increase of sulfate content. The sulfur isotope analysis of a synthetic detergent and sewage water as a potential source of the sulfur in stream waters is furtherly needed.