• Title/Summary/Keyword: 확산 연소율

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Crown Fuel Characteristics of Japanese Red Pine (Pinus densiflora) in Mt. Palgong, Daegu (대구 팔공산 지역의 소나무 수관층 연료 특성)

  • Koo, Kyo-Sang;Lee, Byung-Doo;Won, Myoung-Soo;Lee, Myung-Bo
    • Journal of Korean Society of Forest Science
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    • v.99 no.1
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    • pp.52-56
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    • 2010
  • Crown fuel characteristics such as crown bulk density, crown base height, and fuel moisture content of Japanese red pine were analyzed. Ten trees in Mt. Palgong at Daegu, were destructively sampled and their crown fuels were weighed separately for each fuel category. Fuel content of live and dead crown component were 53%, and 15.3%, respectively. Foliar moisture content was 56%. Needles and twigs with diameter less than 1cm diameter accounted for 16.2%, 55% of total and crown fuel load. Average crown bulk density of Japanese red pine was 0.24 kg/$m^3$, effective crown fuel bulk density was 0.1325 kg/$m^3$.

Development of Program for Ignition Temperature and Its Applications (발화온도 산출 프로그램 개발 및 적용)

  • Park, Won-Hee;Cho, Youngmim;Kwon, Tae-Soom
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.4
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    • pp.243-250
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    • 2017
  • A fire phenomenon of a solid such as wood involves a phenomenon in which solid is heated from the outside and the gas generated through the thermal pyrolysis process of the material is burnt. The thermal pyrolysis phenomenon of the solid is a phenomenon in which the amount of energy incident from the outside, the amount of heat dissipation of the solid material, the heat transfer between the solid material and the surroundings including the amount of heat transfer to the air adjacent to the solid surface, and the fraction of oxygen in the air. In this paper, we calculate the required ignition temperature to simulate the fire phenomenon as simple as possible. By using cone calorimeter, the ignition time was measured by variously controlling the heat flux flowing into the wood specimen by using various wood specimens. The user friendly program is developed for calculation of the ignition temperature. Five different woods such as low density MDF, high density MDF, plywood, douglas fir and PB with various thickness are considered. The ignition temperatures suggested in this paper can be used for fire propagation analysis for woods.

Oxygen Reduction of PAFC Gas Diffusion Electrode with Various Pt Impregnation Methods (인산형 연료전지용 기체확산전극의 백금촉매 담지방법에 따른 산소환원 특성)

  • Yoo, Duck-Young;Eun, Yeong-Chan;Shim, Joong-Pyo;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.7 no.5
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    • pp.999-1005
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    • 1996
  • Pt catalyst on carbon black was prepared by colloidal method, ion exchanging method and methanol reducing method. The colloidal method has been used generally. At ion exchanging method, $H^+$ of functional group on carbon surface made by oxidation treatment was exchanged with Pt ion. At methanol reducing method, Pt was impregnated on carbon to reduce by methanol contained with surfactants. With TEM and XRD, Pt particle size impregnated on carbon by various methods was $30{\sim}50{\AA}$. Loading yield was about 100%, loading yield of ion exchanging method was 99.92% by DCP analysis and 99.87% by combustion method. Within 60 hour, current density of oxygen reduction was $460mA/cm^2$ at 0.7V(vs. RHE) at colloidal method. It was the better performance than catalyst prepared by ion exchanging, methanol reducing method. But, it was shown some decrease of performance for long operation time(after 100hour), catalyst prepared by methanol reducing method was shown stable performance.

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Research for Performance Improvement of De-NOx of Cu-SCR Catalysts (Cu-SCR 촉매의 De-NOx 성능 향상을 위한 연구)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.112-118
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    • 2018
  • In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.

A Study on the Fine Dust Removal Equipment of Pressurized Water type for the Removal of Exhaust Gas Fine Dust and Volatile Organic Compounds from the Non-industrial combustion plant (비산업 연소 사업장 배출 가스상 미세먼지와 휘발성 유기 화합물 제거를 위한 가압수식 미세먼지 제거 장치 연구)

  • Youn, Jae-Seo;Kim, Sang-Min;Lee, Ye-Ji;Noh, Seong-Yeo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.506-512
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    • 2018
  • The fine dust generated in the home and restaurant business occupies a low ratio of about 4% of the total fine dust emissions. However, at the foodservice business, the rate of change of the pollutant concentration is very high, so that the temporary fine dust concentration can be measured up to 60 times. The pollutants generated from non-industrial combustion plants consist of particulate fine dust and gaseous organic compounds. To remove these pollutants, cleaning dust collection system, which is an effective system for simultaneous removal of gaseous and particulate matter, is applied. This is a method of increasing the probability of diffusion capture of the Brownian motion by pressurized liquid injection method using the atomizing nozzle. The dust removal efficiency of the fine dust collecting system was analyzed by nozzle spraying air pressure condition and angle using the manufactured fine dust removing system. As a result, it was confirmed that the efficiency of removal of fine dust and gaseous organic compounds was more than 90%. The developed system is expected to be highly usable in the future because it can remove particulate dust from the existing plant hood system without any installation cost.

Experiment on the Correlation between Mass Flux of Heptane and Material Property of Wall in Compartment Fire (구획 화재 시 벽면 재료 특성과 헵탄의 질량유속 상관관계 실험)

  • Park, Jung Wook;Shin, Yeon Je;Kim, Jeong Yong;You, Woo Jun
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.39-44
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    • 2019
  • In this study, the relationships between the material properties of the wall and the fuel mass flux in compartment fire. The fire resistant board (fire-board) and steel plate compartments are constructed with a 0.3 m width, 0.5 m height and 3.0 m length. To obtain the mass loss rate considering the location of the fire origin in compartment, experiments of a heptane pool fire are performed with a combustion area of $0.01m^2$ and $0.0225m^2$. The results show that the initial mass flux of heptane, $0.0087kg/m^2{\cdot}s$, is increased to $0.166kg/m^2{\cdot}s$ for fire board and $0.019kg/m^2{\cdot}s$ for steel plate. It means that the fire-scenario should be considered with the thermal characteristics of the material properties and geometric shapes of the compartment to predict fire propagation accurately in a compartment space.

Numerical Study of Evaporation and Ignition of in-line Array Liquid Droplets (액적 배열의 증발과 착화에 관한 수치해석적 연구)

  • 김충익;송기훈
    • Fire Science and Engineering
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    • v.13 no.1
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    • pp.37-47
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    • 1999
  • The spreading fire of very small floating particles after they are ignited is fast and t therefore dangerous. The research on this area has been limited to experiments and global simulations which treat them as dusts or gaseous fuel with certain concentration well m mixed with air. This research attempted micro-scale analysis of ignition of those particles modeling them as liquid droplets. For the beginning, the in-line array of fuel droplets is modeled by two-dimensional, unsteady conservation equations for mass, momentum, energy and species transport in the gas phase and an unsteady energy equation in the liquid phase. They are solved numerically in a generalized non-orthogonal coordinate. The single step chemical reaction with reaction rate controlled by Arrhenius’ law is assumed to a assess chemical reaction numerically. The calculated results show the variation of temperature and the concentration profile with time during evaporation and ignition process. Surrounding oxygen starts to mix with evaporating fuel vapor from the droplet. When the ignition condition is met, the exothermic reactions of the premixed gas initiate a and burn intensely. The maximum temperature position gradually approaches the droplet surface and maximum temperature increases rapidly following the ignition. The fuel and oxygen concentration distributions have minimum points near the peak temperature position. Therefore the moment of ignition seems to have a premixed-flame aspect. After this very short transient period minimum points are observed in the oxygen and fuel d distributions and the diffusion flame is established. The distance between droplets is an important parameter. Starting from far-away apart, when the distance between droplets decreases, the ignition-delay time decreases meaning faster ignition. When they are close and after the ignition, the maximum temperature moves away from the center line of the in-line array. It means that the oxygen at the center line is consumed rapidly and further supply is blocked by the flame. The study helped the understanding of the ignition of d droplet array and opened the possibility of further research.

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Release Characteristics of Fission Gases with Spent Fuel Burn-up during the Voloxidation and OREOX Processes (사용후핵연료의 연소도 변화에 따른 산화 및 OREOX 공정에서 핵분열기체 방출 특성)

  • Park, Geun-Il;Cho, Kwang-Hun;Lee, Jung-Won;Park, Jang-Jin;Yang, Myung-Seung;Song, Kee-Chan
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.39-52
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    • 2007
  • Quantitative analysis on release behavior of the $^{85}Kr\;and\;^{14}C$ fission gases from the spent fuel material during the voloxidation and OREOX process has been performed. This thermal treatment step in a remote fabrication process to fabricate the dry-processed fuel from spent fuel has been used to obtain a fine powder The fractional release percent of fission gases from spent fuel materials with burn-up ranges from 27,000 MWd/tU to 65,000 MWd/tU have been evaluated by comparing the measured data with these initial inventories calculated by ORIGEN code. The release characteristics of $^{85}Kr\;and\;^{14}C$ fission gases during the voloxidation process at $500^{\circ}C$ seem to be closely linked to the degree of conversion efficiency of $UO_2\;to\;U_3O_8$ powder, and it is thus interpreted that the release from grain-boundary would be dominated during this step. The high release fraction of the fission gas from an oxidized powder during the OREOX process would be due to increase both in the gas diffusion at a temperature of $500^{\circ}C$ in a reduction step and in U atom mobility by the reduction. Therefore, it is believed that the fission gases release inventories in the OREOX step come from the inter-grain and inter-grain on $UO_2$ matrix. It is shown that the release fraction of $^{85}Kr\;and\;^{14}C$ fission gases during the voloxidation step would be increased as fuel burn-up increases, ranging from 6 to 12%, and a residual fission gas would completely be removed during the OREOX step. It seems that more effective treatment conditions for a removal of volatile fission gas are of powder formation by the oxidation in advance than the reduction of spent fuel at the higher temperature.

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