• Korean Journal of Materials Research
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• v.6 no.1
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• pp.106-115
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• 1996

본 연구에서는 PET(PentaEthoxy Tanatalum:Ta(OC2H5)5) 유기금속 화합물 전구체를 사용하여 차세대 초고집적회로 제조시 고유전체 물질로 유망한 Ta2O5 박막을 열화학증착 방법에 의하여 증착하였다. 본 증착실험을 통하여 여러 가지 운속기체, 기판온도, 반응압력 등의 공정변수가 층덮힘에 미치는 영향을 고찰하였으며 Monte Carlo 전산모사 결과와 기판온도 변화에 따른 층덮힘 패턴의 변화에 대한 실험결과를 비교하여 부착계수를 산출하였다. 운송기체로는 N2, Ar, He을 바꿔가며 실험하였으며 He>N2>Artns으로 층덮힘이 양호한 것으로 나타났다. 이는 운송기체의 종류에 따라 운동량 확산도, 열 확산도, 물질 확산도 등의 이동현상 특성값들이 다르기 때문이라 생각된다. 기판온도의 증가는 운송기체의 종류에 관계없이 층덮힘을 악화시켰으며 도랑내부에서의 Knudsen 확산과 표면반응물의 탈착에 비해 표면반응이 보다 지배적인 역할을 담당함을 알 수 있었다. 또한 질소를 운송기체로 사용한 경우에 부착계수의 겉보기 활성화 에너지는 15.9Kcal/mol로 나타났다. 그리고 3Torr 이하에서 반응압력이 증가하는 반응압력이 증가하는 경우에는 물질 확산도의 감소 효과 때문에 층덮힘이 악화되었다. 본 연구결과 3Torr, 35$0^{\circ}C$에서 He 운송기체를 이용한 경우가 가장 우수한 층덮힘을 얻을 수 있는 최적 공정 조건임을 알 수 있었다.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2008.04a
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• pp.21-24
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• 2008

This study proposes a optimized shape of diffuser profile through investigating the scattering and diffusion characteristics of diffusers. The scattering coefficient according to ISO 17497-1 evaluates uniformity of reverberant sound field of late reflections, while the diffusion coefficient according to AES-4id-2001 evaluates polar response of early reflections. Thus both scattering and diffusion characteristics should contribute to design shape of diffusers to maximize physical performance. To find out design method, the previous results on hemisphere diffusers are reviewed. The frequency characteristics of scattering coefficients depended on the structural height of the diffusers, while amount of scattering coefficients depended on the surface coverage density of the diffusers. However absorptive properties also increased with augment of surface coverage density, thus optimum coverage density should be considered. For the directional diffuser, three types of 2D-diffusers are proposed; semicylinder of h=5mm, semi-truncated cone of h=5-25mm and semicylinder of h=25mm. As results, diffusers with the maximum height of 25mm show the highest scattering coefficients, while diffuser of h=5mm shows high scattering coefficients only at the high-frequency bands. Diffusion coefficient will be investigated for diffusive properties of the early reflection.

• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.723-729
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• 2015

The moment analysis of cyclic adenosine monophosphate (cAMP) was performed using chromatograms that were obtained with the pulse input method from an octadecyl silica (ODS) high-performance liquid chromatography (HPLC) column. The general rate (GR) model was employed to calculate the first absolute moment and the second central moment. Three important coefficients for moment analysis, which are molecular diffusivity ($D_m$), external mass transfer coefficient ($k_f$), and intra-particle diffusivity ($D_e$), were estimated by the Wilke-Chang equation, Wilson-Geankoplis equation, and comparing van Deemter equation to theoretical plate number equation, respectively. Experiments were conducted by various conditions of flow rates, methanol volume ratio of the mobile phase, and solute concentration. After the moment analysis, results were organized by van Deemter plots. Also van Deemter coefficients were compared each other to effect $H_{ax}$, $H_f$, and $H_d$ on height equivalent to a theoretical plate (HETP, $H_{total}$). The value of intraparticle diffusion ($H_d$) was the primary factor which makes for HETP whereas external mass transfer ($H_f$) was disregardable factor.

• Korean Journal of Remote Sensing
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• v.23 no.4
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• pp.311-321
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• 2007

The diffuse attenuation coefficient for down-welling irradiance $K_d({\lambda})$, which is the propagation of down-welling irradiance at wavelength ${\lambda}$ from surface to a depth (z) in the ocean, and underwater visibility are important optical parameters for ocean studies. There have been several studies on $K_d({\lambda})$ and underwater visibility around the world, but only a few studies have focused on these properties in the Korean sea. Therefore, in the present study, we studied $K_d({\lambda})$ and underwater visibility around the coastal area of the Yellow Sea, and developed $K_d({\lambda})$ and underwater visibility algorithms for ocean color satellite sensor. For this research we conducted a field campaign around the Yellow Sea from $19{\sim}22$ September, 2006 and there we obtained a set of ocean optical and environmental data. From these datasets the $K_d({\lambda})$ and underwater visibility algorithms were empirically derived and compared with the existing NASA SeaWiFS $K_d({\lambda})$ algorithm and NRL (Naval Research Laboratory) underwater visibility algorithm. Such comparisons over a turbid area showed small difference in the $K_d({\lambda})$ algorithm and constants of our result for underwater visibility algorithm showed slightly higher values.

• Journal of Korea Water Resources Association
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• v.33 no.1
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• pp.39-50
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• 2000

Generally speaking, a hydrodynamic model needs a friction coefficient (Manning coefficient or Chezy coefficient) and eddy viscosity. For numerical solution the coefficients are usually determined by recursive calculations. The eddy viscosity in numerical model plays physical diffusion in flow and also acts as numerical viscosity. Hence its value has influence on the stability of numerical solution and for these reasons a consistent evaluation procedure is needed. By using records of stage and discharge in the downstream reach of the Han river, I-D models (HEC-2 and NETWORK) and 2-D model (SMS), estimated values of Manning coefficient and an empirical equation for eddy viscosity are presented. The computed results are verified through the recorded flow elevation data.n data.

• Journal of the Korean Chemical Society
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• v.38 no.6
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• pp.427-434
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• 1994

The retention behaviors of poly(ethylene-co-vinyl acetate)s have been studied by thermal field-flow fractionation(ThFFF) with respect to effective separation and characterization of thermal diffusion coefficients($D_{\tau}$) as one of the physicochemical properties of polymers. The eight copolymers are different in vinyl acetate composition ranging from 25% to 70% and in molecular weight ranging from 110,000 to 285,000. The carrier solvents are THF, toluene and chlorobenzene which have different viscosities and thermal conductivities. It is shown that the retention of a copolymer is dependent on the type of the carrier, the molecular weight and chemical composition of the copolymer. The results show that the retention of a copolymer increases when either vinyl acetate composition or the molecular weight increase. $D_{\tau}$ values measured by experiments vary from 1.36∼5.97 $\cm^2/(s.K)$ depending on the copolymer composition and the type of the carrier solvent. These values increase $(r^2{\geq}0.928)$ with increase of weight % of vinyl acetate. THF is found to be the proper carrier solvent for separation of copolymers employed in this study due to the fact that a $D_{\tau}$ value greatly changes with variation of copolymer composition. From the above results, ThFFF can be used for separation of copolymers with similar molecular sizes but different compositions.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.40 no.6
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• pp.555-561
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• 2020

In this study, the applicability of Hunt's analytical solution for a two-layered leaky aquifer system, which was developed to estimate stream depletion due to the groundwater pumping of the upper shallow aquifer, was evaluated. The 5-year averaged stream depletions were estimated using Hunt's analytical solution for various combinations of hydraulic characteristic values such as transmissivity, storage coefficient of the two aquifers, interlayer leakage coefficient, stream-well distance, hydraulic conductivity of the streambed, and stream width. Through comparison with the numerical solution accurately simulated with a MODFLOW groundwater flow model, the analytical solution derived by regarding the stream width as a point was evaluated. It was found that the error in the stream depletion calculated by the analytical solution can be reduced to less than 0.05 when the stream-well distance is greater than the stream width or when the stream depletion factor (SDF) is more than about 3,000 days. In addition, when the streambed hydraulic conductivity is less than 1 m/d, the hydraulic diffusion coefficient of the lower aquifer layer is less than 100 ㎡/d, the hydraulic diffusion coefficient ratio of the upper and lower aquifer layers is 5 or more, and the leakage coefficient between the layers is less than 0.0004 m/d, the overall analytical solutions were overestimated compared with the numerical solutions.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.18 no.12
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• pp.1994-2000
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• 1993

A new lattice structure using decision feedback and augmented prediction for estimating and suppressing the narrowband interference is presented. The performance of the proposed interference canceller is compared to the conventional interference cancellation filter. The reference signal of the interference canceller is formed by using the chip decisions, which is correlated with the narrowband interference components of the received signal. The decision feedback technique reduce the distortion of the desired signal which is introduced by the interference canceller through the use of feedback chip decisions. And by linear prediction of the error signal, the residual interference component of can be eliminated, Using this unconteminated error signal to update the adaptive filter coefficients, the performance of the rejection can be improved. In the simulation, it is assumed that the processing gains are 7 and 15, signal to interference ratio is -10[dB], and 5% interference band. The results show that the BER performance of the proposed filter structure is improved by 1~3dB.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.29 no.10A
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• pp.1123-1130
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• 2004

This paper proposes the fast OVSF code generation method using the multi-stage spreading scheme based on the single code indexing scheme. The conventional OVSF indexing scheme based on the code-tree structure uses two numbers as the codeword indices, the layer number and the code number of the corresponding layer. However, the single code index number implicitly includes the information of the spreading factor as well as the code number. Since the binary representation of the single code indices shows the pattern of the codeword, the orthogonality between two different codewords can be determined by comparing their code indices instead of much longer codewords. The above useful property also makes the codeword can be generated directly kom its single code index. In this paper, the multi-stage spreading scheme is applied to generate the long code by spreading two shorter codewords with the appropriate code indices. The proposed fast code generation algorithm is designed for 3GPP UMTS systems and verified by the simulations.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.585-593
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• 2007

This paper presents a model for durability evaluation of concrete structures exposed to marine environment, considering mainly a build-up of surface chloride $(C_s)$ as well as diffusion coefficient (D) and chloride threshold level $(C_{lim})$. In this study, time dependency of $C_s$ and D were extensively studied for more accurate evaluation of service life of concrete structures. An analytical solution to the Fick's second law was presented for prediction of chloride ingress for time varying $C_s$. For the time varying $C_s$, a refined model using a logarithm function for time dependent $C_s$ was proposed by the regression analysis, and averaging integrated values of the D with time over exposed duration were calculated and then used for prediction of the chloride ingress to consider time dependency of D. Durability design was also carried out for railway concrete structures exposed to marine environment to ensure 100 years of service life by using the proposed models along with the standard specification on durability in Korea. The proposed model was verified by the so-called performance-based durability design, which is widely used in Europe. Results show that the standard specification underestimates durability performances of concrete structures exposed to marine environment, so the cover depth design using current durability evaluation in the standard specifications is very much conservative. Therefore, it is found that utilizing proposed models considering time dependent characteristics of $C_s$ and D can evaluate service lift of concrete structures in marine environment more accurately.