• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2013.04a
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• pp.41-41
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• 2013

화학산업이 발달함에 따라 화학 산업 현장에서 사용되고 있는 가연성물질들의 여러 가지 화재 및 폭발 위험이 증가되고 있으며, 화재 및 폭발의 예방 안전을 위한 화학공정설계 및 대처에 있어, 물질의 연소특성치 데이터를 필요로 한다. 인화점은 가연성 액체를 다루는 공정에서 안전한 취급과 사고방지를 위해 중요한 자료가 되며, 화재의 위험을 나타내는 지표로서 가연성액체의 액면 가까이서 인화할 때 필요한 증기를 발산하는 액체의 최저온도, 그리고 가연성증기의 포화증기압이 공기와 혼합기체의 폭발한계 하한농도와 같게 되는 온도로 정의한다. 본 연구에서는 2성분계 혼합물에 대해 인화점을 측정하였고, 측정값을 Raoult의 법칙과 다중회귀분석(Multiple Regression)을 도입하여 이론값과 비교 하였다. 따라서 본 연구에서 제시된 방법론에 의해 아직까지 밝혀지지 않은 순수가연성액체와 가연성혼합물의 인화점을 예측하는 방법을 전개하고자 하며, 실험에서 찾고자하는 자료에 도움을 주고자 한다. 본 연구를 바탕으로 혼합물의 인화점 예측 방법과 실험에서 측정한 자료를 화재 및 폭발을 방지하는 기초 자료로 제공하고자하며, 산업현장에서 취급되고 있고 위험성 평가가 되지 않은 보다 많은 물질에 대한 이론 및 실험 연구에 활용 되도록 하는데 그 목적이 있다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.12
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• pp.769-776
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• 2016

In this study, a numerical simulation of a vanadium redox flow battery was investigated for reactions involving an electrochemical species using comprehensive conservation laws and a kinetic model. For a 3-D geometry of the cell, the distributions of electric potential, vanadium concentration, overpotential, and ohmic loss were calculated. The cell temperature and initial vanadium ion concentration were set as variables. The voltage and electrochemical loss were calculated for each variable. The effects of each variable's impact on the electrochemical performance of a vanadium redox flow battery was numerically analyzed using the calculated overpotential in the electrode and the ohmic loss in the electrolyte phase. The cell temperature increased from $20^{\circ}C$ to $80^{\circ}C$ when the voltage efficiency decreased from 89.34% to 87.29%. The voltage efficiency increased from 88.65% to 89.25% when the vanadium concentration was changed from $1500mol/m^3$ to $3000mol/m^3$.

• Journal of the Korean Chemical Society
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• v.51 no.4
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• pp.331-338
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• 2007

A rapid, simple and sensitive spectrophotometric method was developed for the determination of cobalt(II) using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATSC) as a analytical reagent. The metal ion in aqueous medium forms a brown coloured complex with HMBATSC at pH 6.0. The complex has two absorption maxima at 375 nm and 390 nm. At 375 nm, the reagent shows considerable absorbance, while at 390 nm the reagent does not shows appreciable absorbance. Hence, analytical studies were carried out at 390 nm. Beer's law is obeyed in the range of 0.059-2.357 μg ml-1 of Co(II). The molar absorptivity and Sandall's sensitivity of the method are 2.74×104 l mol-1 cm-1 and 0.0024 μg cm-2 respectively. The interference of various diverse ions has been studied. The complex has 1:2 [Co(II)- HMBATSC] stoichiometry. A method for the determination of cobalt(II) by second order derivative spectrophotometry has also been proposed. The proposed methods were applied for the determination of cobalt(II) in alloy steels, vitamin B12 and in some biological samples.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.550-564
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• 2020

Distillation columns are one of the main equipment used for the separation of chemical components in petrochemical process design. However, in spite of the efficient operation in wide range, and the advantage of data collection for equipment verification, the distillation columns are inherently known for high energy consumption and capital cost. Hence, the trade-off analysis needs to be done between investment cost and operation cost to develop the most economical distillation columns. This study was conducted using Aspen Plus, a popular process simulation program, in the pursuit of broad application by as many process engineers as possible. In this paper, design variables for optimization of distillation columns were defined to improve emphatically the design quality with reducing erratic practice of many engineers. In addition, by eliminating unnecessary reviewing step and establishing systematic and efficient procedures, the amount of time for design and human resources were minimized. Aspen Process Economic Analyzers (APEA) program was introduced in order to calculate the investment cost reliably, and the efficient systematic procedure for utilization of APEA was established.

• Journal of the Korean Electrochemical Society
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• v.26 no.4
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• pp.56-63
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• 2023

The development of renewable energy technologies, such as solar, wave, and wind power, has led to the diversification of water electrolysis technologies, which can be easily coupled with renewable energy sources in terms of economics and scale. Water electrolysis technologies can be classified into three types based on operating temperature: low-temperature (<100 ℃), medium-temperature (300-700 ℃), and high-temperature (>700 ℃). It can also be classified by the type of electrolyte membrane used in the system. However, the concepts of thermodynamic and thermo-neutral voltages calculations and are very important factors in the evaluation of energy consumption and efficiency of water electrolysis technologies, are often confused. This review aims to contribute to a better understanding of the calculation of operating voltage and efficiency of PEM water electrolysis technologies and to clarify the differences between thermodynamic voltage and thermo-neutral voltage.

• Journal of the Korean Chemical Society
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• v.54 no.2
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• pp.248-256
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• 2010

This study investigated the effects of the level of enrichment for analogies upon students' mapping, conceptual understanding, and the types of mapping errors in concept learning about Boyle's Law. Analogical reasoning ability test was administered and the score was used as a blocking variable. Three types (simple, enriched, and extended analogies) of learning materials according to the level of enrichment for analogies were studied by randomly assigned middle school students, and a conceptions test and a mapping test were administered immediately. The retention tests of both were administered four weeks later. Analyses of the results revealed that there was no main effect in the level of enrichment for analogies, but there was interaction effect with analogical reasoning ability in the post test on mapping. And the score of enriched analogy group was significantly higher than those of simple analogy group, but the score differences among three groups were not significant in the retention test on conceptual understanding. The frequency of the total mapping errors in the simple analogy group was the highest, and the frequencies of most types of mapping errors in the enriched and the extended analogy groups were less than those in the simple analogy group. There were also some differences in the frequencies of mapping errors with respect to the level of analogical reasoning ability. Therefore, these results will help science teachers plan and practice instructions using analogy.

• Journal of The Korean Association For Science Education
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• v.27 no.1
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• pp.28-36
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• 2007

This study investigated the influences of small group discussion and students' visual learning style in learning chemical concepts with drawing and writing as methods to assist students in connecting and integrating multiple external representations. Seventh graders (N=449) at a coed middle school were assigned to individual drawing (ID), pair drawing (PD), individual writing (IW), and pair writing (PW) groups. All students learned "Boyle's Law" and "Charles's Law" for two class periods. Analyses of the results revealed that the students in the PD group, regardless of students' visual learning style, scored significantly higher than those in the ID group in a conception test. The scores of the students with strong visual learning preference in the PW group were significantly higher than those in the IW group in the conception test, while the scores of the students with weak visual learning preference were not significantly different between the two groups. Although the conception test scores of the PD group were higher than those of the PW group, the difference was relatively small. It was found that most students in both PD and PW groups perceived pair drawing and pair writing positively upon cognitive and motivational aspects.

• Journal of the Korean Chemical Society
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• v.66 no.6
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• pp.493-508
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• 2022

Chemistry is the subject which includes properties, change, and composition of matter. Chemistry has the system which explains observable properties and change with microscopic level, it explains them using scientific theory and laws. In the national-level curriculum, the properties and changes of matter are continuously dealt with from elementary school to high school, and the curriculum are organized so that students could strengthen their understanding about matter. In other words, understanding of the properties and changes of matter is the base to explain everyday life with the view of chemistry, and these two are classified as domains of chemistry in the 2015 revised science curriculum. In this study, we confirmed students' understanding about properties of matter and change of matter, through the analysis about results of the National Assessment of Educational Achievement (NAEA). For that purpose, this study analyzed the 12 items about properties of matter, and 19 items about change of matter, which were used in the NAEA from 2015 to 2019. According to the results of classifying and analyzing questions according to the core concept, the understanding about the two domains significantly changed between the proficient achievement-level students and basic achievement-level students. Depending on the achievement-level, there was a difference in explaining the phenomenon by using the perspective of particles, and by associating scientific concepts and models, or there was a difference in understanding the inquiry related to these two domains. Based on this analysis, this study discussed some implications to be improved on teaching-learning for 'properties of matter', and 'change of matter'.

• Journal of Adhesion and Interface
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• v.24 no.3
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• pp.95-99
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• 2023

In this study, LiDAR-detectable black materials are synthesized by coating and reduction of titanium dioxide onto plate-type natural mica, which evaluated practical LiDAR verification. In detail, black TiO₂@Mica materials are fabricated by utilizing a sol-gel reaction to coat titanium dioxide onto natural mica, followed by reduction using sodium tetrahydridoborate. Subsequently, Black TiO₂@Mica materials are dispersed in hydrophilic transparent varnish and sprayed onto the glass substrate to assess applicability as paints. As a result, Black TiO₂@Mica-based paints exhibit true blackness (L^*=12.1) and a higher NIR reflectance (30.2 R%). In addition, it was confirmed that as-synthesized Black TiO₂@Mica materials are successfully recognized by a LiDAR sensor. This phenomenon is attributed to Fresnel's reflection law, in which light reflection occurs at the interface between natural mica and titanium dioxide with different refractive indices. In this regard, the findings of the study are expected to contribute to the potential utilization of LiDAR-detectable materials in various fields such as autonomous vehicles, robotics, and drones.

• Journal of the Korean Chemical Society
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• v.43 no.2
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• pp.213-224
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• 1999

Preconceptions of middle school students related to chemical change the students are surveyed. The students are divided into experimental group that are learned by concept change theory teaching model, and control group that are learned by traditional teaching method based on science textbooks. After the planned classes, the tendencies of concept change of the two groups according to students learning motivations are analyzed. New teaching methods, which based on concept change learning model and students learning motivations, developed by this research. And the effects of the new teaching method are testified. As a result, it is proved that most of the students have a lot of preconceptions, and persist the wrong conceptions after the classes. This tendency is same in the control group and in the experimental group.