• Title/Summary/Keyword: 화학 반응

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Magnetizing of Natural Quartz and Scoria (자연산 퀄쯔와 스코리아의 마그네타이징)

  • 소대화;정종현
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.352-355
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    • 2003
  • 비자성이며 비전도성의 물리적 성질을 갖는 자연산 퀄쯔(quartz)와 용암석 스코리아를 대상으로 마그네타이징 처리를 하여 분석하였다. 마그네타이징 처리를 위하여 강력한 기계화학적 분쇄 반응을 시켰으며, 분쇄 반응시 알코올계의 솔벤트를 반응 용매로 사용하였다. 퀄쯔와 스코리아의 마그네타이징 처리에서 비교적 비중이 큰 퀄쯔의 경우와 비중이 작은 스코리아의 경우에도 분쇄된 분말이 물에 뜨는 것을 확인할 수 있으며, 친유성으로 기름에 대한 흡착 성질이 우수함을 확인하였다. 자연산 퀄쯔와 함께 스코리아를 바탕물질로 하여 기계-화학적 반응 기술로 고 분산성 흡착반응에 의한 고분자 물잘 생성을 유도하여 나노복합체를 제조하였다. 반응의 처리조건과 적용과정에 따라서 기계-화학적 반응을 통하여 얻어진 물질은 자기적 성질과 유전체 및 전기적 성질을 동시에 나타낸다. 부착성 융합 복합물질의 특징을 고려하여 시그니토마그네틱스(Segneto-magnetics)로 분류되는 합성분말은 특히 유류성분에 대하여 높은 흡착성을 가지며, 강한 자기적 성질을 띄는 10-50 nm 두께의 하나 또는 그 이상의 이질적 융합 화합물 층이 석영이나 수정체의 표면에 합성되어 특유의 자기, 전기적 성질을 나타낸다.

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Simulation of Silicon Carbide Converted Graphite by Chemical Vapor Reaction (Ⅰ) (화학적 기상 반응에 의한 탄화규소 피복 흑연의 시뮬레이션(Ⅰ))

  • Lee, Joon-Sung;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.38 no.9
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    • pp.846-852
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    • 2001
  • A two-dimensional Monte Carlo simulation has been used to investigate the effect of the reaction temperature on the formation of the silicon carbide conversion layer near the surface of graphite substrate The carbothermal reduction of silica is the reaction mechanism of silicon carbide formation on graphite substrate by chemical vapor reaction methods. The chemical composition of silicon carbide conversion layer gradually changes from carbon to silicon carbide because gaseous reactants diffuse through micropores within graphite substrate and react with carbon at the surface of inner pores. The simulation was carried out under the condition of reaction temperature at 1900K, 2000K, 2100K and 2200K for 500MCS. It was found from the results of simulation that the thickness of silicon carbide conversion layer increases with reaction temperature.

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Trends and Market Outlook in Electrochromic Technology (전기변색기술의 동향 및 시장전망)

  • Ryu, H.J.;Cho, S.M.;Ah, C.S.;Kim, T.Y.;Cheon, S.H.;Kim, J.Y.;Song, J.H.;Kim, Y.H.
    • Electronics and Telecommunications Trends
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    • v.30 no.6
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    • pp.12-20
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    • 2015
  • 전기변색기술은 전기화학적 반응으로 물질의 색을 바꾸는 기술이다. 이 반응에는 전자의 이동이 개입되며 전자의 이동에 따른 화학반응은 일반적인 화학반응과 차이를 나타낸다. 산화와 환원이라는 화학반응은 닫힌 회로 내에서 일어나며 오직 계면에서의 전위에 의존하게 된다. 이러한 전기변색기술을 응용한 분야는 자동차용 전기변색 거울, 스마트 윈도우와 같이 상용화에 성공한 분야도 있으며, 앞으로는 투명 디스플레이, 반사형 디스플레이 및 전가자격표시장치 등에 활용이 가능하다. 전기변색기술이 견인하는 세계시장규모는 에너지 절약 및 안전성에 대한 시대적인 요청으로 연평균 성장률 약 21%로 확대되어 2018년에는 약 50억달러의 규모로 성장할 수 있을 것으로 예측된다.

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Kinetic Theory for Chemical Reactions in Liquids (용액중에서의 화학반응에 관한 동역학적 이론)

  • Kook Joe Shin
    • Journal of the Korean Chemical Society
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    • v.25 no.5
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    • pp.291-299
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    • 1981
  • A test particle kinetic theory for reaction dynamics in liquids is presented at the repeated ring collision level for the hard sphere model. A kinetic equation for the equilibrium time correlation function of the reactive test particle phase space density is derived and the rate kernel expression for the reversible chemical reaction of the type A +B ${\rightleftharpoons$ C + D in the presence of inert solvent S is obtained by the projection operator method.

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Analysis of Teaching Types and Obstacles of Chemistry Teachers through Teacher Educational Programs for Responsive Teaching (반응적 교수를 위한 교사교육 프로그램을 통한 화학교사의 교수 유형 및 장애 요인 분석)

  • Kim, Jeong Soo;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.65 no.4
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    • pp.268-278
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    • 2021
  • The purpose of this study is to subdivide responsive teaching types proposed in the previous study in order to observe the change in the responsive teaching types in teacher educational programs, and to identify factors that impede changes in responsive teaching types. To this end, an educational program including introduction of responsive teaching, case analysis of responsive teaching, individual assignments and group discussions on facilitator type educational scenarios is provided for chemistry teachers who participated in a chemistry education course established in a graduate school of education. Based on previous research, when the teacher's teaching method was analyzed as evaluator, transfer, guide and facilitatore, a type that could not be classified was observed. In this study, responsive teaching types were added by adding two types: explorer and interpreter. In addition, through individual assignments and group discussion data, we could observe the factors that hinder teachers' responsive teaching changes. The obstacles that impede the change to responsive teaching were classified into teacher factors, student factors, and environmental factors. Among the obstacles, teacher factors include a belief in teacher-led instruction, a belief in the role of a teacher as a transfer of knowledge, a belief that the curriculum should be followed, a lack of understanding of the teacher about students, and a lack of the teacher's ability to lead student-led expansion. The student factor was distrust of the student's competence. Also, as an environmental factor, there was an educational environment such as multi-students class. Effective teacher education on responsive teaching can be achieved only when the perception related to these obstacles can be removed.

Immobilization of Proteins on Silicon Surfaces Using Chemical and Electrochemical Reactions of Nitrobenzenediazonium Cations (나이트로벤젠다이아조늄 양이온의 화학 및 전기화학 반응을 이용한 실리콘 표면상으로의 단백질 고정)

  • Kim, Kyu-Won;Haque, Al-Monsur Jiaul;Kang, Hyeon-Ju
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.70-74
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    • 2010
  • The immobilization of proteins on silicon surfaces using electrochemical reaction has been studied. Chemical deposition of nitrobenzendiazonium (NiBD) cations is employed to modify silicon surfaces. Electrochemical reduction of nitro-group to primary amine-group have been conducted on the modified surfaces to activate silicon surfaces for the protein immobilization. Attachment of gold nanoparticles was used to prove the reduction. The current method was applied to selective activation of a silicon nanowire and immobilize proteins on the selected nanowire. It has been demonstrated that the use of chemical and electrochemical reaction NiBD is efficient for the selective immobilization of proteins on silicon nanowire surfaces.

Understanding and Improvement of an Experiment Measuring Chemical Reaction Rates by Monitoring Volume Change of a Gas:On the Reaction between HCl(aq) and Mg(s) (기체 부피변화를 이용한 화학반응속도 측정 실험의 이해 및 개선 연구: HCl 수용액과 고체 Mg의 반응에 대하여)

  • Jeong, Dae-Hong;Bang, Jeong-A;Yun, Hui-Suk;Choe, Won-Ho
    • Journal of the Korean Chemical Society
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    • v.50 no.5
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    • pp.404-414
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    • 2006
  • this study we analyzed and improved an experiment measuring chemical reaction rates introduced in the high school science textbooks through an understanding of the phenomena observed in carrying out the experiment. For this purpose, the contents of textbooks related to the experiment were analyzed, and the problems observed in carrying out the experiment were addressed through experimental analysis. When the experiment was carried out by the method of aquatic transposition presented in textbooks, the observed volume change of H2 gas was delayed and chemical reaction rate was increased in the early stage of reaction period. To resolve these problems, an improved method for measuring the reaction rates was suggested. In the improved experiment the reaction rate was measured to be constant on time, which was interpreted in terms of the concentration of H+ and the surface area of magnesium.

A Study on the Electrolytic Reduction Mechanism of Uranium Oxide in a LiCl-Li$_2$O Molten Salt (LiCl-Li$_2$O 용융염계에서 우라늄 산화물의 전기화학적 금속전환 반응 메카니즘에 관한 연구)

  • 오승철;허진목;서중석;박성원
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.25-39
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    • 2003
  • This study proposed a new electrolytic reduction technology that is based on the integration of simultaneous uranium oxide metallization and Li$_2$O electrowinning. In this electrolytic reduction reaction, electrolytically reduced Li deposits on cathode and simultaneously reacts with uranium oxides to produce uranium metal showing more than 99% conversion. For the verification of process feasibility, the experiments to obtain basic data on the metallization of uranium oxide, investigation of reaction mechanism, the characteristics of closed recycle of Li$_2$O and mass transfer were carried out. This evolutionary electrolytic reduction technology would give benefits over the conventional Li-reduction process improving economic viability such as: avoidance of handling of chemically active Li-LiCl molten salt increase of metallization yield, and simplification of process.

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Photocatalysis and Its Applications (광촉매반응과 그 응용)

  • Jung, Kyoung Soo;Lee, Ho In
    • Journal of the Korean Chemical Society
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    • v.41 no.12
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    • pp.682-710
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    • 1997
  • Photocatalysis, which can be applied to get energy economically, to synthesize useful materials, and to remove environmentally harmful materials by transforming solar energy to chemical energy, has many advantages over conventional heterogeneous catalysis. In this review article, both heterogeneous and homogeneous photocatalyses were discussed focusing on the principles of photocatalysis, the modification of the photocatalysts, hydrogen formation by water decomposition, and environmental application of photocatalysis.

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