• Title/Summary/Keyword: 화학 물질 유출

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A Study on the Improvement of Marine Pollution and Marine Litter Managements in Korea (우리나라 해양오염 및 해양폐기물관리 개선에 관한 연구)

  • Park, Kwang-Ha;Kwon, Young-Du;Kim, Jong-Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.4
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    • pp.33-43
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    • 2013
  • That occur in the ocean and the efficient management of marine litter on marine pollution oil spill response one step further strategies are needed. Marine pollution accidents occurred in 2011, a total of 287 and was found in runoff 369 kL, respectively compared to the previous year decreased by 13% and 39%. Average amount of marine materials during 5-years represent the oil flow of 310.5 kL (heavy fuel oil of 106.0 kL, diesel of 178.9 kL, oily bilge water of 22.3 kL, other oil of 7.7 kL) and the waste of 62.3 tons, the hazardous and noxious substances (HNS) was 510.6 kL. Marine emissions in 2011 by type of waste that a total amount of dumping 3,972 $m^3$, and livestock manure 795 $m^3$(20%), waste water 1,431 $m^3$(36%), sewage sludge 887 $m^3$(22%), wastewater sludge, 813 $m^3$(21%), manure 5 $m^3$(0.1%), other 41 $m^3$(0.9%), respectively. The concept of marine waste and needs to be more clearly defined. Integrated management of hazardous chemicals according to the incident management system should be established. To remove of coastal pollution, response officer needs korean coast response system. Like the marine pollution response, coastal pollution response systems also require step response.

Evaluation on the adsorption and desorption capabilities of filter media applied to the nonpoint source pollutant management facilities (비점오염 저감시설에 적용되는 여재의 흡착 및 탈착 능력 평가)

  • Moon, Soyeon;Hong, Jungsun;Choi, Jiyeon;Yu, Gigyung;Kim, Lee Hyung
    • Journal of Wetlands Research
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    • v.17 no.3
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    • pp.228-236
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    • 2015
  • Urbanization causes many environmental, hydrological and ecological problems such as distortion of the natural water circulation system, increase in nonpoint source pollutants in stormwater runoff, degradation of surface water quality, and damage to the ecosystem. Due to the increase in impervious surface by urbanization, developed countries apply low impact development (LID) techniques as important alternatives to reduce the impacts of urbanization. In Korea, LID techniques were employed since 2012 in order to manage nonpoint source pollutants. LID technology is a technique for removing pollutants using a variety of physical, chemical and biological mechanisms in plants, microorganisms and filter media with the reduced effluence of stormwater runoff by mimicking natural water circulation system. These LID facilities are used in a variety of filter media, but an assessment has not been carried out for the comprehensive comparison evaluation of adsorption and desorption characteristics for the pollutant removal capacity. Therefore, this study was conducted to analyze the adsorption and desorption characteristics of various filter media used in the LID facilities such as sand, gravel, bioceramic, wood chips and bottom ash etc. in reducing heavy metals(Pb, Cu). In this study, the adsorption affinity for Pb in all filter media was higher than Cu. Pseudo second order equation and Langmuir-3 isotherm are more applicable in the adsorption kinetic model and adsorption isotherm model, respectively. As a result of the desorption experiment, the filter media does not exceed KSLT which is the hazardous substance leaching limit, showing the capability of the filter media in LID. The bioceramic and woodchip as filter medias were evaluated and exhibited excellent adsorption capacity for Pb.

Research on water quality and flow rate measurement by applying GPS electronic Floater standard experimental method when water environmental chemical accidents occur (수환경 화학사고 발생시 GPS 전자부자 표준실험법 적용을 통한 수질-수리 측정에 대한 연구)

  • Lee, Chang Hyun;Nam, Su Han;Kim, Young Do
    • Journal of Korea Water Resources Association
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    • v.56 no.12
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    • pp.845-853
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    • 2023
  • Recently, along with the increase in chemical accidents, the number of accidents-related disasters has been increasing continuously since 2012, and when looking at the hydrogen fluoride incident which is a representative example of domestic chemical incidents, there is insufficient technology applicable to the incident site. The result was that the damage spread. Therefore, in this paper, we will adapt the water pollution accident response system to a location-based approach, and introduce a measurement method for alternative index tracking using a GPS electronic floater of a location-based index measurement method for real-time response in the water environment when a chemical incident occurs. The research target area is Gumi City, which is the area where the hydrogen fluoride incident occurred, and Gamcheon is selected, and alternative tracking using GPS electronic floater is conducted in the corresponding target area through water quality and flow measurement. As a result, it is possible to measure water quality and flow at the same time in tracker experiments using GPS electronic floater based on the research results, it is believed that using GPS electronic floater will be of great help in disaster response systems for spill incidents in the river.

Physico-chemical Characteristics and In situ Fish Enclosure Bioassays on Wastewater Outflow in Abandoned Mine Watershed (폐광산 지역의 유출수에 대한 이.화학적 수질특성 및 Enclosure 어류 노출시험 평가)

  • An, Kwang-Guk;Bae, Dae-Yeul;Han, Jeong-Ho
    • Korean Journal of Ecology and Environment
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    • v.45 no.2
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    • pp.218-231
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    • 2012
  • The objectives of this study were to evaluate the physico-chemical water quality, trophic and tolerance guilds in the control ($C_o$) and impacted streams of the abandoned mine, along with the ecological health, using a multimetric health model and physical habitat conditions of Qualitative Habitat Evaluation Index (QHEI), during the period of three years, 2005~2007. Also, eco-toxicity ($EE_t$) enclosure tests were conducted to examine the toxic effects on the outflows from the mine wastewater, using the sentinel species of Rhynchocypris oxycephalus, and we compared the biological responses of the control ($C_o$) and treatment (T) to the effluents through a Necropybased Health Assessment Index ($N_b$-HAI). Tissue impact analysis of the spleen, kidney, gill, liver, eyes, and fins were conducted in the controlled enclosure experiments (10 individuals). According to the comparisons of the control ($C_o$) vs. the treatment (T) in physicochemical water quality, outflows from the abandoned mine resulted in low pH of 3.2, strong acid wastewater, high ionic concentrations, based on an electrical conductivity, and high total dissolved solid (TDS). Physical habitat assessments, based on Qualitative Habitat Evaluation Index (QHEI) did not show any statistical differences (p>0.05) in the sampling sites, whereas, the $M_m$-EH model values in a multimetric ecological health ($M_m$-EH) model of the Index of Biological Integrity (IBI), using fish assemblages, were 16~20 (fair condition) in the control and all zero (0, poor condition) in the impacted sites of mine wastewater. In addition, in enclosure eco-toxicity ($EE_t$) tests, the model values of $N_b$-HAI ranged between 0 and 3 in the controls during the three years, indicating an excellent~good condition (Ex~G), and were >100 (range: 100~137) in the impacted sites, which indicates a poor condition (P). Under the circumstances, organ tissues, such as the liver, kidney, and gills were largely impaired, so that efficient water quality managements are required in the outflow area of the abandoned mine watershed.

Study on Material Flow Analysis of Mercury in Paint (페인트 중 수은의 물질흐름분석 연구)

  • Cho, Yoon A;Jeong, Mi Jeong;Jeon, Tea Wan;Lee, Hee Sung;Kim, Yong Jun;Yeon, Jin Mo;Cho, Na Hyeon;Shin, Sun Kyoung
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.4
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    • pp.180-185
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    • 2017
  • For the management of mercury-containing products, the products were selected to do material flow analysis in preference of not having selected in previous studies. Domestically mercury have been added to pigment for prevention of bacterial growth. So, in this study paint containing pigment was selected as a target. 71 samples of paint products collected in 2014 and data of 38 samples of wastes (dust, sludge, paint) analyzed in 2010 were used in material flow analysis. The result shows that mercury was 0~0.25 mg/kg in products and 0.23~0.69 mg/kg in the wastes. In the material flow analysis, the amount of flow in the process of distribution was 10.06 kg/year, but the amount of flow in disposal like a landfill, incineration and recycling was much than distribution as 25.27 kg/year. It was caused by different sampling period between collecting products and data of wastes. Therefore, It could be possible to be affected from regulation by RoHS like decreasing usage of mercury in paint products or eradicated in the industry. Mercury contents in current paint products are very low to affect discharging to the environment.

Hydrophobic Polydimethylsiloxane Thin Films Prepared by Chemical Vapor Deposition: Application in Water Purification (화학적 증기 증착 방법을 통해 제조한 소수성 폴리디메틸실록산 박막: 수처리로의 응용)

  • Han, Sang Wook;Kim, Kwang-Dae;Kim, Ju Hwan;Uhm, Sunghyun;Kim, Young Dok
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.1-7
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    • 2017
  • Polydimethylsiloxane (PDMS) can be deposited on various substrates using chemical vapor deposition process, which results in the formation of PDMS thin films with thickness below 5 nm. PDMS layers can be evenly deposited on surfaces of nanoparticles composed of various chemical compositions such as $SiO_2$, $TiO_2$, ZnO, C, Ni, and NiO, and the PDMS-coated surface becomes completely hydrophobic. These hydrophobic layers are highly resistant towards degradation under acidic and basic environments and UV-exposures. Nanoparticles coated with PDMS can be used in various environmental applications: hydrophobic silica nanoparticles can selectively interact with oil from oil/water mixture, suppressing fast diffusion of spill-oil on water and allowing more facile physical separation of spill-oil from the water. Upon heat-treatments of PDMS-coated $TiO_2$ under vacuum conditions, $TiO_2$ surface becomes completely hydrophilic, accompanying formation oxygen vacancies responsible for visible-light absorption. The post-annealed $PDMS-TiO_2$ shows enhanced photocatalytic activity with respect to the bare $TiO_2$ for decomposition of organic dyes in water under visible light illumination. We show that the simple PDMS-coating process presented here can be useful in a variety of field of environmental science and technology.

Continuous Nitrate Removal using Bipolar ZVI Packed Bed Electrolytic Cell (영가철(Fe0) 충진 복극전해조를 이용한 질산성질소의 연속식 제거 연구)

  • Jeong, Joo-Young;Kim, Han-Ki;Shin, Ja-Won;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1B
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    • pp.79-84
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    • 2012
  • Nitrate is a common contaminant in groundwater aquifer. The present study investigates the performance of the bipolar zero valent iron (ZVI, $Fe^0$) packed bed electrolytic cell in removing nitrate in different operating conditions. The packing mixture consists of ZVI as electronically conducting material and silica sand as non-conducting material between main cathode and anode electrodes. In the continuous experiments for the simulated wastewater (contaminated groundwater, initial nitrate about 30 mg/L as N and electrical conductivity about 300 ${\mu}S/cm$), over 99% removal of nitrate was achieved in the applied voltage 600 V and at the flow rate of 20 mL/min. The optimum packing ratio (v/v) and flow rate were determined to be 1:1~2:1 (silica sand to ZVI), 30 mL/ min respectively. Effluent pH was proportional to nitrate influx concentration, and ammonia which is the final product of nitrate reduction was about 60% of nitrate influx. Magnetite was observed on the surface of the used ZVI as major oxidation product.

The Reclamation of Secondary Effluent to Industrial Water by Co-60 γ Irradiation (Co-60 γ선을 이용한 하수처리수의 공업용수로의 재이용)

  • Lee, Myun-Joo;Jeoung, Young-Do;Nho, Young-Chang;Shon, Jong-Sik
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.838-842
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    • 1999
  • In order to reclaim the effluent discharged from sewage treatment facilities application of an irradiation technique was investigated in this study for industrial water reuse. Samples were filtered using a sand filter to remove particles. Co-60 was used as an irradiation source and the irradiation dose was varied from 0.1 kGy to 15 kGy. The major source of colour in secondary treatment effluent was humic substances, which could be easily removed by irradiation with a dose 5 kGy. Bacteria could be also disinfected even at low doses. It was possible to get high quality water for industrial water reuse. But the effluent still contained a small amount of organic compounds. Further treatment, of residual organic compounds will be necessry if the higher quality water is required.

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Reduction of NPS pollution in the No-till field (무경운을 적용한 밭에서의 비점오염원 저감효과)

  • Lee, Su In;Won, Chul Hee;Shin, Min Hwan;Jeon, Je hong;Choi, Joong Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.426-426
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    • 2015
  • 무경운 농법은 경작지의 토양을 교란시키지 않고 작물을 재배하는 방법으로, 토양의 물리성 개선과 토양 침식 예방, 생산비 절감 등의 효과가 있어 전 세계적인 인정을 받고 있는 농업기술이다. 그러나 아직까지 무경운의 재배 지속 기간 등 많은 의문이 제기되고 있으며, 국내 환경조건에 맞는 실험적인 연구가 미흡한 실정이다. 이에 본 연구에서는 최적관리기법의 하나인 무경운(No-till)을 적용한 밭의 오염물질 저감효과를 장기적으로 살펴보고자 2011년부터 2014년까지 4년간의 모니터링을 실시하였다. 무경운 농법을 적용하기 위하여 동계피복작물(밀, 보리)을 재배작물 정식하기 전해 겨울에 파종하여 이듬해 6월 말 수확하였다. 이후 7월에서 8월 사이 재배작물(들깨, 무)을 정식하였다. 시비는 2011년에는 축산퇴비, 2012년에는 축산액비 그리고 2013년과 2014년에는 화학비료를 시비하였으며, 매년 경운과 무경운의 시비량은 동일하게 처리하였다. 유출 시험포의 면적은 $150m^2$(폭 5 m, 경사장 30 m)이며, 8개(경사도 3% 4개, 경사도 8% 4개)의 시험포를 조성하여 각각 2개씩 경운(관행)과 무경운을 적용하였다. 모니터링은 재배작물(들깨, 무) 정식 이후부터 작물 수확 전까지 강우사상에 대하여 이루어졌으며, 연구기간동안 총 13회의 강우 사상에 대하여 조사를 실시하였다. 경운대비 무경운 시험포의 평균 오염부하 삭감율을 분석한 결과 경사도 3% 시험포의 경우 BOD는 35.1%, $COD_{Cr}$은 37.4% 그리고 영양염류인 TN과 TP는 각각 36.9%와 33.5%가 삭감된 것으로 조사되었으며, 경사도 8% 시험포의 경우 BOD가 36.4%, $COD_{Cr}$은 45.8%, TN과 TP는 각각 45.5%와 40.6%가 삭감된 것으로 나타났다. 우리나라에서는 경운(관행) 농법이 영농관리 차원에서 대부분 이용되고 있으나, 본 연구 결과에 기초할 때 무경운 농법으로 영농할 경우 강우유출수 및 하천으로 유입되는 비점오염부하를 효과적으로 제어할 수 있을 것으로 기대된다.

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Set up Reduction Goals of Combined Sewer Overflow Pollutant Load Using Long-Term Rainfall-Runoff Model Simulation (장기간 강우-유출 모의를 통한 합류식하수관로시스템의 월류부하량 저감목표 설정 연구)

  • Lee, Gunyoung;Na, Yongun;Ryu, Jaena;Oh, Jeill
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.785-794
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    • 2013
  • Combined sewer overflows during rainfall events contain sewer sediments and surface pollutants. This can cause significant chemical, physical and biological problems to receiving watershed. However, there are no method that can commonly apply to decide criteria for controlling the pollutant load. In this study, it sets up the reduction goals of combined sewer overflow through long-term simulation using the rainfall-runoff model. From a review of domestic and foreign management standard of combined sewer overflow for this, it makes decision that 60% (phase 1), 85% (phase 2) of total pollutant load and frequency per year for reduction goals is more proper. Also, the result of analyzing long-term simulation (minimum 10 years) applied to research basin indicates that reduction goals of BOD pollutant load are 1,123 kg (phase 1) and 2,374 kg (phase 2), and overflow volumes for research objective achievement are $11,685m^3$ (phase 1) and $24,701m^3$ (phase 2).