• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.4
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• pp.15-22
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• 2020

The landfill gas produced in landfill is generally made up of methane(CH4) and carbon dioxide(CO2) of more than 90%, with the remainder made up of hydrogen sulfide(H2S). However, separate pre-treatment facilities are essential as hydrogen sulfide contained in landfill gas is combined with oxygen during the combustion process to generate sulfur oxides and acid rain combined with moisture in the atmosphere. Various desulfurization technologies have been used in Korea to desulfurize landfill gas. Although general desulfurization processes apply various physical and chemical methods, such as treatment of sediment generation according to the CaCO3 generation reaction and treatment through adsorbent, there is a problem of secondary wastes such as wastewater. As a way to solve this problem, a biological treatment process is used to generate and treat it with sludge-type sulfide (S°) using a biological treatment process.In this study, as a basic study of technology for utilizing the biological treatment by-products of hydrogen sulfide in landfill gas, an experiment was conducted to use the by-product as a mixture of concrete. According to the analysis of the mixture concrete strength of sulfur products, the mixture of sulfur by-products affects the strength of concrete and shows the highest strength value when mixing 10%.

• Journal of the Korea Institute of Building Construction
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• v.17 no.3
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• pp.245-252
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• 2017

Recently, structures such as large retailers, outlets and warehouses have been increasing in accordance with changes in consumption patterns. Since these structures include ultra-flat slab members, they are thoroughly managed to control slab cracking by the plastic and drying shrinkage. In order to control the cracking of the slab member, a chemical crack reduction method is used. In particular, the use of the shrinkage reducing agent has been examined. However, domestic research results are limited. In this study, the shrinkage properties of concrete using shrinkage reducing agent and the drying shrinkage properties according to the mixing factors were investigated. The performance of domestic shrinkage reducing agent was appeared similar to that of overseas high-grade shrinkage reducing agent. As the shrinkage reducing agent usage increased, the drying shrinkage reduction effect increased. At the age of 100 days, the dry shrinkage rate of specimen with the shrinkage reducing agent of 1.5%was shown about half that of the specimen without the shrinkage reducing agent. The shrinkage reducing agent was gound to have no specific performance change for the use of the admixture.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.639-645
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• 2008

The objectives of this research are to (1) observe changes in particle size distribution due to formation of microflocs during coagulation process (2) identify the membrane fouling potential on cross flow system (3) investigate the mechanism of membrane fouling. The rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. The pretreatment of the raw water significantly reduced the fouling of the UF membrane. Also, the rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane. That is, during the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation not only improved dissolved organics removal efficiency but also flux recovery efficiency.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1076-1081
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• 2012

For the purpose of development of the latex suitable for latex modified concrete, experimental researches on the preparation of carboxylated styrene butadiene latex by the method of the two-step emulsion polymerization and application to concrete were performed. Sodium dodecylbenzene sulfonate and sodium salt of lauryl sulfonate were selected as anionic emulsifiers, and nonylphenoxy poly(ethyleneoxy) ethanols (n=10, 20, 40) as latex stabilizer. Potassium persulfate and sodium bisulfite were used as redox initiator, besides $Na_2HPO_4$ and $K_2CO_3$ as electrolytes. Polymerization recipe of latex suitable for latex modified concrete were suggested from the experimental researches on the effects of anionic emulsifiers and their concentration on the polymerization stability, and the effect of electrolytes concentration on the particle size of latex. Physical properties, such as slump, air contents, compressive and flexural strength, of latex prepared by suggested polymerization recipe were examined. The experimental results showed that latex modified concrete satisfied the quality standards in slump and air contents. Furthermore, it was turned out that the compressive and the flexural strength of latex modified concrete with 28 days curing time showed appreciably improvements.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.310-315
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• 2019

This study conducted a series of studies to find alternative ways to use Chlorine Bypass System-dust(CBS-dust) in cement production. The results of engineering characteristics of CBS-dust are summarized as follows. First of all, the density of CBS-dust is 2.40, lighter than cement and the pH was 12.50 which was strong alkaline. In terms of particle size, it was 11.70 ㎛ which was finer than cement. With chemical properties, calcium oxide(CaO) was the highest as 35.10%, potassium oxide(K₂O) was 32.43%, potassium chloride(KCl) was 19.46%, sulfur oxide(SO₃) was 6.81%, and the remaining chemical components are SiO₂, Fe₂O₃, Al₂O₃, MgO, and the like. Therefore, if CBS-dust is used as early-strength chemical admixtures in the concrete secondary products that use a large amount of mineral admixtures without rebar, it can be an effective method for increasing the strength of concrete as an alkali activator and preventing early-frost damage of Cold Weather Concrete.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.789-794
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• 2012

For the purpose of development of the latex suitable for polymer cement mortar, experiments on the preparation of carboxylated styrene butadiene latex by the method of the two-step emulsion polymerization were performed. Methyl methacrylate, methacrylic acid and acrylic acid were selected as carboxylic co-monomer, styrene and butadiene as monomer, sodium dodecylbenzene sulfonate and sodium salt of lauryl sulfonate as anionic emulsifiers, and nonylphenoxy poly (ethyleneoxy) ethanol (n=10, 20, 40) as latex stabilizer. Potassium persulfate and sodium bisulfite were also used as redox initiator, and sodium monohydrogen phosphate and potassium carbonate as electrolytes. The effects of categories and concentration of carboxylic co-monomer, molecular weight control agent, crosslinking agent, and styrene/butadiene monomer ratio on the characteristics of latex were investigated. Polymerization recipes for preparation of polymer cement mortar could be proposed. The prepared latexes were tested for the physical properties such as compressive and flexural strength when latexes were mixed with cement mortar. The results showed that the latex could be adapted to polymer cement mortar. Also, it was recognized that the compressive and flexural strength were exhibited 25.4% and 45.3% respectively higher improvement than the quality standards at 28 days curing time.

• Journal of the Korea Concrete Institute
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• v.24 no.1
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• pp.37-44
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• 2012

Recently, due to developments in construction technology, the use of high-performance concrete became popular. High-performance concrete when compared to the ordinary concrete can better satisfy required performances by using mineral admixture and superplasticizer. Various studies on the effect of admixture materials on the quality of high-performance concrete have been reported. But there exist limited number of reported results on the effect of cement qualities, which is the most important constituent material in concrete. Therefore, in this study, the relationship between the quality of cement and the flowability of high flowing concrete is investigated. Qualities of domestically produced cement were identified, and then the influence of the qualities of cement on the flowability of high flowing concrete is evaluated. The result showed that the dosage of required superplasticizer was dependent on cement fineness, to brain, free-CaO, and interstitial phase, which all trigger initial hydration process of cement. Particularly, the results showed that fineness of cement has a high impact on the dosage of the superplasticizer. For strength property of concrete, the dosage of superplasticizer had a significant effect on the early age strength, but had negligible effect in the long term strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.55-61
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• 2023

This study aims to develop CLSM fill material for emergency restoration using landfill coal ash. As a result of examining physical properties such as particle size distribution and fines content of landfill coal ash, bottom ash, fly ash, and general soil were mixed, and SP was found to have a density of 2.03 and a residual particle pass rate of 7.8 %. CLSM materials that secure fluidity in unit quantities without using chemical admixtures such as glidants and water reducing agents have a high risk of material separation due to bleeding. As a result of this experiment, it was found that the bleeding ratio did not satisfy the standard in the case of the specimen with a large amount of fly ash and a lot of addition of mixing water. As a result of the compressive strength test, the strength development of 0.5 MPa or more for 4 hours was found to be satisfactory for the specimens using hemihydrate gypsum with a unit binder amount of 200 or more, and the remaining gypsum showed poor strength development. Although it is judged that landfill coal ash can be used as a CLSM material, it is necessary to identify and apply the physical and chemical characteristics of coal ash buried in the ash treatment plant of each power generation company.

• Applied Chemistry for Engineering
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• v.2 no.3
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• pp.209-215
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• 1991

The effect of agitation on the dispersion of organic phase was investigated in an immiscible liquid system (n-hexane/40 wt % p-TSA aqueous solution). Four different types of six-bladed turbine impellers were used : a flat blade type and three screen blade types. The experimental results showed that the extent of dispersion of organic phase at the same agitation speed was decreased in the order of flat blade, 60 mesh, 40 mesh, and 20 mesh screen blades. Otherwise, it was increased with increasing the concentration of TBA as a surfactant agent and with decreasing volume fraction of organic phase. Also, the minimum agitation speed for a complete dispersion was increased in the order of flat blade, 60 mesh, 40 mesh, and 20 mesh screen blades. However, the minimum power consumption did not vary significantly. In this condition, the relationship between Power number and Reynolds number was expressed as $N_p=a\;N_{Re}{^b}$, where the values of constant a and constant b were ranged 2200~4100 and -0.69~-0.63 respectively.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.486-490
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• 1999

In this study, to improve the required properties of tile cement mortar such as excellent water retention capacity (WRC), workability, open time, sag resistance, and tile adhesive strength, tile cement mortars containing the several additives with different ratio were compared and analyzed. By adding small amount of synthesized starch to hydroxypropyl methylcellulose (HPMC) which is used for improving WRC, the decrease of moisture evacuation from mortar surface was observed and the workability of mortar was improved with long open time. Polyacrylamide (PAAm) and ethylencvinyl acetate (EVAc) were also added in order to increase the adhesion of tile. As a results, the saggings of mortar itself and tile were decreased and the adhesive strength of mortar between base and tile was enhanced. By adding melment, the workability was improved by increasing the fluidity of mortar. It is postulated that the properties of tile cement mortar was improved by adding 0.80~1.20% of HPMC, 0.10~0.15% of starch, 0.001~0.015% of PAAm, 0.05~0.10% of EVAc and 0.003~0.005% of melment to the cement mortar.