• Title/Summary/Keyword: 화학적 전처리

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Reduction Factors of Pesticides with Different Physicochemical Properties under Washing and Cooking Conditions (물리화학적 특성이 다른 농약의 세척 및 조리방법에 의한 감소계수 산출)

  • You, Young-Hwa;Lee, Young-Sun;Kwon, Hoon-Jeong
    • Korean Journal of Food Science and Technology
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    • v.43 no.5
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    • pp.537-543
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    • 2011
  • The reduction factor of pesticides is getting more crucial these days. However, most studies have focused on the relationship between pesticides and commodities. This study was conducted to examine the pesticide reduction factor based on their physicochemical properties. Five pesticides were selected among 288 insecticides by considering the presence of an ionizable group, the log P, and boiling points. The correlation coefficients between log P and removal by tap water, 5% acetic acid, 20% ethanol, and 0.15% detergent were -0.835 (p<0.001), 0.336 (p=0.221), 0.659 (p<0.01), and -0.939 (p<0.001), respectively. Removal by blanching was affected by log P as it showed a positive correlation with a log P of 0.620 (p<0.05). Removal by frying showed a strong negative correlation with a log P of -0.913 (p<0.001). The results suggest that removing pesticides was affected largely by log P and by vapor pressure during cooking, whereas during washing, the matrix of the food also contributed to the reduction.

Preparation and Characterization of Bamboo-based Activated Carbon by Phosphoric Acid and Steam Activation (인산 및 수증기 활성화에 의한 대나무 활성탄 제조 및 특성 연구)

  • Park, Jeong-Woo;Ly, Hoang Vu;Oh, Changho;Kim, Seung-Soo
    • Clean Technology
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    • v.25 no.2
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    • pp.129-139
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    • 2019
  • Bamboo is an evergreen perennial plant, and it is known as one of the most productive and fastest-growing plants in the world. It grows quickly in moderate climates with only moderate water and fertilizer. Traditionally in Asia, bamboo is used for building materials, as a food source, and as versatile raw materials. Bamboo as a biomass feedstock can be transformed to prepare activated carbon using the thermal treatment of pyrolysis. The effect of process variables such as carbonization temperature, activation temperature, activation time, the amount of steam, and the mixing ratio of phosphoric acid and bamboo were systematically investigated to optimize the preparation conditions. Steam activation was proceeded after carbonization with a vapor flow rate of $0.8{\sim}1.8mL-H_2O\;g-char^{-1}\;h^{-1}$ and activation time of 1 ~ 3 h at $700{\sim}900^{\circ}C$. Carbon yield and surface area reached 2.04 ~ 20.59 wt% and $499.17{\sim}1074.04m^2\;g^{-1}$, respectively, with a steam flow rate of $1.4mL-H_2O\;g-char^{-1}\;h^{-1}$ for 2 h. Also, the carbon yield and surface area were 24.67 wt% and $1389.59m^2\;g^{-1}$, respectively, when the bamboo and phosphoric acid were mixed in a 1:1 weight ratio ($700^{\circ}C$, 2 h, $1.4mL-H_2O\;g-char^{-1}\;h^{-1}$). The adsorption of methylene blue into the bamboo activated carbon was studied based on pseudo first order and second order kinetics models. The adsorption kinetics were found to follow the pseudo second order model, which is governed by chemisorption.

A Study on the On-line Measurement of Biochemical Oxygen Demand of livestock Wastewater (축산 폐수의 생물화학적 산소요구량 자동 측정 방법에 관한 연구)

  • Kim, Hyoung-Mo;Kim, Jin-Kyong;Shin, Kwan-Suk;Kim, Jun-Hyung;Jung, Jae-Chil;Kim, Tai-Jin
    • KSBB Journal
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    • v.23 no.4
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    • pp.317-322
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    • 2008
  • The Biochemical Oxygen Demand(BOD) is one of important parameters for the most widely used method of organic pollution in wastewater and wastewater treatment effluent. As the conventional BOD test needs 5-day long incubation period, it is thus incompatible with real time control of wastewater treatment plant. To resolve this problem, in the present study an on-line Dissolved Oxygen(DO) monitoring system was used to observe the transient change of dissolved oxygen concentration in livestock wastewater. The system was composed of BOD sensor, amplifier and computer. It was observed that the concentration of the microorganism in the livestock wastewater was relatively constant during the growth period of initial one hour, which allowed the assumption of the constant Oxygen Uptake Rate(OUR) within one hour of measurement. It was thus concluded that the present scheme provided a protocol for automatic measurement of BOD in livestock wastewater, which can be applicable to optimal control of livestock wastewater treatment plant.

The study of Rolled Steel Process Wastewater by Superconducting High Gradient Magnetic Separation (초전도 마그네트를 이용한 고구배 자기분리 열연강판 폐수처리에 관한 연구)

  • Kim, Tea-Hyung;Ha, Dong-Woo;Oh, Sang-Soo;Kim, Ho-Sup;Ko, Rock-Kil;Kwon, Jun-Mo;Lee, Nam-Jin;Kim, Young-Hun;Kang, Chae-Hun;Ha, Tae-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.05a
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    • pp.11-11
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    • 2009
  • 종래의 산업폐수 처리기술로는 중금속 함유 폐수에 수용성의 금속염을 첨가하여 가성소다 혹은 소석회를 이용하여 pH를 조정하고 고분자 응집제를 첨가하여 금속의 수산화물을 생성시켜 이를 부상 혹은 침전시켜 Sludge화하여 제거하는 방법이 주로 사용되고 있다. 그 외 질소, 인, 유기물이 함유된 폐수의 경우에는 Biological Oxidation Techniques, 활성탄 흡착방식이 주로 채택되고 있다.[1-3] 이러한 폐수처리기술은 화학약품 사용량이 과다하고 이는 Sludge 생성량을 증대하고 2차 폐수처리가 필요로 하는 경우가 많고, 처리장이 면적이 넓어야 하고 대용량의 Sludge 제거창치가 필요하여 고비용의 처리공정으로 문제점을 가지고 있다.[2-3] 이에 본 연구에서는 이러한 기존 기술의 문제점을 보완할 수 있고 기존 기술로는 완벽하게 처리하기 곤란한 악성 폐수들에 대한 새로운 고도처리기술로 초전도 마그네트를 이용한 고구배 자기분리기술에 대한 기초연구를 하였다. 본 연구에서 사용한 고구배 자기분리 시스템은 무헬륨 전도냉각방식으로 자기분리를 위해 사용한 필터는 SUS 430 재질의 메쉬 형태로 제작하여 실험하였다. 또한, 자기분리 처리를 위한 전처리 공정으로는 응집제를 첨가하여 자기분리 효율을 높이고자 하였다. 자기분리 처리대상수로는 포항제철에 압연 강판에 사용되는 냉각수를 대상으로 자기분리 처리에 대한 효과를 실험하였다. 또한, 자기분리에 대한 특성을 평가하기 위해 강자성의 $Fe_3O_4$ 미세자성분말을 첨가하여 처리수내의 들어있는 유기물질에 대해 자기분리 자장 및 유속에 대한 처리효율을 미치는 영향을 조사하였다. 자기분리 처리는 1~6 Tesla에서 자기필터는 디스크 형태로 다층으로 연속적으로 적층하였으며, 처리유속은 1~4 l/min으로 하였다. 고농도인 처리폐수를 자가분리 인가 자장에 따라 처리하여 고농도에서는 70%, 저농도에서는 98 %까지 처리되었다. 또한, 자기분리용 필터는 SUS 430 재질의 mesh 망을 사용하였으며 인가자장 및 유속변화에 대한 실험 결과 탁도 및 농도는 필터 크기의 영향은 거의 차이가 없었으며 단지 인가자장 및 유속에 따라서 지수적으로 감소하였다. 자기분리된 용액 내 $Fe_3O_4$ 입도 분석 결과 자기분리 이전에 분포하던 $10\sim20\;{\mu}m$의 입자는 거의 제거되었으며 2 ${\mu}m$ 이하의 입자들은 실험 횟수에 따라 점점 직경이 작은 쪽으로 분포가 좁아졌으며, 마그네타이트의 자화율을 분석한 결과 약 0.8 Tesla에서 포화 되었으며 처리수의 탁도 및 농도가 자장에 따라 감소하는 것으 알 수 있었다.

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Development of a Multichannel Eddy Current Testing Instrument(I) (다중채널 와전류탐상검사 장치 개발(I))

  • Lee, Hee-Jong;Nam, Min-Woo;Cho, Chan-Hee;Yoon, Byung-Sik;Cho, Hyun-Joon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.155-161
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    • 2010
  • Recently, the electromagnetic techniques of the eddy current testing(ECT), alternating current field testing, magnetic flux leakage testing and remote field testing have been used as a nondestructive evaluation method based on the electromagnetic induction. The eddy current testing is now widely accepted as a NDE method for the heat exchanger tube in the electric power industry, chemical, shipbuilding, and military. The ECT system mainly consists of the synthesizer module, analog module, analog-to-digital converter, power supplier, and data acquisition and analysis program. In this study, the synthesizer module and the analog module which are essential to the ECT system were primarily developed. The developed ECT system is basically a multifrequency type which is able to inject the maximum four frequencies based on the frequency and time domain multiplexing method. Conclusively, we confirmed that the EC signal was processed appropriately in each circuit modules, and the Lissajous EC signal was displayed in the impedance plane.

Development of High Efficiency Dehumidifiers in low temperature (저온에서 고효율 제습기 개발)

  • Kim, Jong-Ryeol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.206-211
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    • 2016
  • Various applications require dry air at low temperature, such automation equipment, semiconductor manufacturing, chemical production lines, and coating processes for the shipbuilding industry. Four evaporators for low temperature (below $0^{\circ}C$) were installed for a dehumidification system. Moist air is cooled sequentially over three evaporators. The first evaporator has an evaporation temperature of $13^{\circ}C$, that of the second evaporator is $5^{\circ}C$, and that of the third evaporator is maintained at $-1.3^{\circ}C$. In the fourth evaporator implantation thereby the moisture contained in the moisture air. A pressure regulator (CPCE 12) is used at this point and is defrosted when the vapor pressure is below a set value. The non-implantation moisture of the air is a heating system that uses the waste heat of a condenser with high temperature. It develops the cooling type's dehumidifier, which is important equipment that prevents the destruction of protein and measures the temperature and humidity at each interval by changing the front air velocity from 1.0 m/s to 4.0 m/s. The cooling capacity was also calculated. The greatest cooling capacity was 1.77 kcal/h for a front air velocity of 2.0 m/s

Determination of Additives Content in Aviation Turbine Fuel Using Multi-dimensional GC-MS (Multi-dimensional GC-MS를 이용한 항공터빈유의 첨가제 분석)

  • Youn, Ju Min;Jang, Yoon Mi;Yim, Eui Soon;Kim, Seong Lyong;Kang, Yong
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1260-1268
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    • 2018
  • To improve fuel performance and specific characteristics of long storage and moving through fuel systems additives should be added in kerosene type aviation turbine fuel (AVTUR) such as antioxidant, fuel system icing inhibitor (FSII), electric conductivity improvers and so on. The dosage of additives has to be analyzed qualitatively and quantitatively due to inspect the quality of abnormal fuel and distinguish other petroleum products. Multi-dimensional GC-MS (MDGC-MS) with Deans switching technique are applied the determination of antioxidant and FSII, which are added with AVTUR containing complex mixture of hydrocarbons. Antioxidant and FSII in the range of 2.5-20 mg/L was quantitatively and qualitatively analyzed using MDGC-MS and the detection limit was about twice as low as that of the 1-dimensional GC-MS results. The method in this study has been higher peak resolution compared with GC-MS and could be simultaneously analyzed different two additives without sample pre-treatment.

발아조건 및 휴면타파 처리에 따른 수단그라스(Sorghum sudanense(Piper.) Stapf) 품종별 발아검정

  • Young-Jun Moon;Ji-Su Kyeong;Chae-Yeon Kwon;Ji-Yeong Jung;Seon-Yeong Im;Dong-Jin Lee
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.38-38
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    • 2022
  • 녹비작물은 천연비료로서 화학비료 사용량을 감소시키고 이산화탄소를 흡수해 농업분야에서 온실가스 저감을 위해 사용하고 있다. 녹비작물을 이용하여 지속가능한 친환경 농업의 필요성이 증대되고 있는 실정이다. 화본과 녹비작물은 두과 녹비작물에 비해 탄소 물질의 함량과 biomass가 상대적으로 높아 토양 내 유기물증진을 위한 재배에 적합하다. 이에 화본과 녹비작물 중 하나인 수단그라스의 발아 및 휴면특성 검정을 진행하여 발아 적정조건을 찾아 유기종자 생산기술 개발을 위한 자료로 활용하고자 한다. 본 연구에서는 수단그라스 4품종(GW104G, Cadan99B, TE-Evergreen, Sweet home)을 공시품종으로 사용하였다. 표준발아검사에 따라 각 품종별 종자를 100립씩 3반복 치상하여 10일간 발아검정 진행 후 발아율, 발아세, 평균발아일수, 발아속도를 조사하였다. 첫 번째 실험은 침종시간 및 치상온도별 실험으로 시간별(무처리/5/10/15/20/25hr)로 침종한 후, 생장상(10/20/30/40℃)에 보관하여 정상아 개수를 파악하였다. 두 번째 실험은 휴면타파 실험으로 1~5일 동안 종자를 예냉(무처리/5/10/15℃)과 고온(50℃) 처리한 후, 첫 번째 실험 결과에 따라 발아 최적 조건(침종 20hr, 치상온도 20℃)에서 발아시킨 후 정상아 개수를 파악하였다. 수단그라스 4품종의 치상온도별 발아율은 20℃에서 평균 92±6.9%로 가장 높았으며, TE-evergreen의 경우 치상온도 10℃에서 10시간, 20℃에서 20시간, 30와 40℃에서 15시간 침종한 값이 유의적으로 높은 발아율을 보였다. 수단그라스 4품종의 평균발아일수(MGT)는 침종 20시간과 치상온도 30℃일 때 평균 1.21±1.14일로 가장 빨랐으며 발아속도(GR)는 침종 20시간과 치상온도 20℃의 조건일 때 89.9±5.92로 가장 빨랐다. 수단그라스 4품종의 휴면타파 온도별 발아율은 10℃에서 평균 92±9.3%로 가장 높았다. TE-evergreen의 경우 휴면타파 온도 5, 10, 15℃에서 4~5일 동안 처리한 값이 무처리와 50℃처리에 비해 유의적으로 높은 발아율을 보였다. 수단그라스 발아검사 결과, 20시간 침종 후 20~40℃에서 2~3일간 발아시킬 경우 90%이상의 발아율을 보이므로 파종을 위한 종자 전처리를 할 경우 이와 같은 조건에서 진행하는 것이 바람직 할 것으로 사료된다.

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Combination Treatment with Arsenic Trioxide and Sulindac Induces Apoptosis of NCI-H157 Human Lung Carcinoma Cells via ROS Generation with Mitochondrial Dysfunction (NCI-H157 폐암 세포주에서 활성산소종의 생성과 미토콘드리아 기능변화를 한 Arsenic Trioxide와 Sulindac 병합요법의 세포고사효과)

  • Kim, Hak-Ryul;Yang, Sei-Hoon;Jeong, Eun-Taik
    • Tuberculosis and Respiratory Diseases
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    • v.59 no.1
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    • pp.30-38
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    • 2005
  • Background : Arsenic trioxide ($As_2O_3$) has been used to treat acute promyelocytic leukemia, and it induces apoptosis in a variety of solid tumor cell lines including non-small cell lung cancer cells. However, nonsteroidal antiinflammatory drugs (NSAID) can enhance tumor response to chemotherapeutic drugs or radiation. It was previously demonstrated that a combination treatment with $As_2O_3$ and sulindac induces the apoptosis of NCI-H157 human lung carcinoma cells by activating the caspase cascade. This study aimed to determine if a combination treatment augmented its apoptotic potential through other pathways except for the activation of the caspase cascade. Material and Methods : The NCI-H157 cells were treated with $As_2O_3$, sulindac and antioxidants such as glutathione (GSH) and N-acetylcysteine (NAC). The cell viability was measured by a MTT assay, and the level of intracellular hydrogen peroxide ($H_2O_2$) generation was monitored fluorimetrically using a scopoletin-horse radish peroxidase (HRP) assay. Western blotting and mitochondrial membrane potential transition analysis were performed in order to define the mechanical basis of apoptosis. Results : The viability of the cells was decreased by a combination treatment of $As_2O_3$ and sulindac, and the cells were protected using antioxidants in a dose-dependent manner. The increased $H_2O_2$ generation by the combination treatment was inhibited by antioxidants. The combination treatment induced changes in the mitochondrial transmembrane potential as well as the expression of the Bcl-2 family proteins, and increased cytochrome c release into the cytosol. However, the antioxidants inhibited the effects of the combination treatment. Conclusion : Combination treatment with $As_2O_3$ and sulindac induces apoptosis in NCI-H157 human lung carcinoma cells via ROS generation with a mitochondrial dysfunction.

Correlation of Arsenic and Heavy Metals in Paddy Soils and Rice Crops around the Munmyung Au-Ag Mines (문명 금은광산 주변 논토양에서 As 및 중금속의 토양과 벼작물의 상관성 평가)

  • Kwon, Ji Cheol;Park, Hyun-Jung;Jung, Myung Chae
    • Economic and Environmental Geology
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    • v.48 no.4
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    • pp.337-349
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    • 2015
  • This study has focused on investigation of correlation for As and heavy metals in paddy soil and rice crops sampled in the vicinity of the abandoned Munmyung Au-Ag mine. Soil samples extracted by various methods including aqua regia, 1 M $MgCl_2$, 0.01 M $CaCl_2$ and 0.05 M EDTA were analyzed for As and heavy metals (Cd, Cu, Pb and Zn). Rice grain samples grown on the soils were also analyzed for the same elements to evaluate the relationships between soils and rice crops. According to soil extraction methods, As and heavy metal contents in the soils were decreased in the order of aqua regia > 0.01 M $CaCl_2$ > 1 M $MgCl_2$ > 0.05 M EDTA. In addition to correlation analysis, statistically significant correlation with the four extraction methods (p<0.01) were found in the soil and rice samples. As calculation of biological accumulation coefficients (BACs) of the rice crops for As and heavy metals, the BACs for Cd, Zn and Cu were relatively higher than those for As and Pb. This study also carried out a stepwise multiple linear regression analysis to identify the dominant factors influencing metal extraction rates of the paddy soils. Furthermore, daily intakes of As and heavy metals from regularly consumed the rice grain (287 g/day) grown on the contaminated soils by the mining activities were estimated, and found that Cd and As intakes from the rice reached up to 73.7% and 51.8% for maximum allowance levels of trace elements suggested by WHO, respectively. Therefore, long-term consumption of the rice poses potential health problems to residents around the mine, although no adverse health effects have yet been observed.