• Title/Summary/Keyword: 홀수탄소원자경로

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Soot and PAH Formation in Counterflow Diffusion Flames of Ethylene-Propane (에틸렌/프로판 대향류 확산화염에서 PAH 와 매연의 생성특성)

  • Yoon, Seung-Suk;Lee, Sang-Min;Hwang, Jun-Young;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.6
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    • pp.817-822
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    • 2002
  • Sooting characteristics of counterflow ethylene/propane mixture flames have been experimentally studied to investigate the fuel structure effect on PHM and soot formation. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon (PAH) concentration, respectively. Importance of $C_{3-}$species on PAH growth as well as the H-abstraction-C$_2$ $H_2$addition (HACA) mechanism has been emphasized, considering that PAH growth rate is greater for with mixed fuel than fer pure fuel flames. It was also confirmed that HACA pathways are the dominant soot growth mechanism. A new PAH growth model including both $C_{2-}$ and $C_{3-}$growth mechanisms is proposed based on the experimental results.