• Applied Chemistry for Engineering
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• v.7 no.4
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• pp.679-690
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• 1996

Acrylic copolymer was synthesized from 2-dimethylaminoethyl methacrylate and alkylmethacrylate containing long chain hydrocarbon group. To facilitate emulsification in water, acrylic copolymer was treated with acetic acid, and therefore acetated acrylic copolymer was produced. Acetated acrylic copolymer was perfectly emulsified in water and showed increased emulsion stability. Polymer as a cement dispersion agent(PDCM-PSD) was prepared by blending the newly synthesized acetates acrylic copolymer with sodium gluconate, oleic acid, and triethanolamine. The applicability of the blended polymer was examined, and it was found that the effects of dispersion and water-proof(0.3~0.5) were excellent.

• Journal of the Society of Disaster Information
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• v.11 no.3
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• pp.329-336
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• 2015

When diatomite powder was used as an admixture in mortar, its effects on the mortar strength was examined by experimental tests. For the tests, 4 kinds of commercially available diatomite powder were purchased ; one non-calcined product, one calcined product, and flux-calcined product two. The compressive and flexural strength of the mortar according to the increase of added amount of calcined diatomite powder increased at all test ages(7, 28, and 56 days). However, the use of non-calcined diatomite powder worsened the fluidity of mortar severely and that caused much more required water content. And flux-calcined product did not show useful effect on the mortar strength.

• Proceedings of the Korean Society of Disaster Information Conference
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• 2022.10a
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• pp.301-302
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• 2022

최근 들어 염해, 콘크리트의 탄산화, 동결융해 등의 열화요인 의하여 발생할 수 있는 콘크리트의 내구성에 대한 다양한 연구가 진행되고 있는데, 이러한 열화요인은 독립적이 아닌 복합열화의 형태로 작용하게 되는데, 열화현상을 저감하는 한 방편으로 플라이애쉬와 같은 혼화재를 사용하디도 한다. 플라이애쉬는 유동성 증진을 통한 내구성의 향상과, 수화열 저감을 통한 균열감소 및 장기강도 증진 등의 효과가 있으며, 시멘트를 대체함으로써 경제적인 효과를 유발하는 장점도 가지고 있다. 그러나 플라이애쉬는 품질편차가 크고, 경우에 따라서 미연탄소분에 의한 AE제 흡착 등으로 인한 콘크리트의 내구성 및 강도를 저하시킬 수 있는 요소를 내포하고 있으므로 사용 시 주의가 필요하다. 본 연구에서는 열화를 저감하고, 내구성을 갖는 고강도 콘크리트를 제조하기 위하여 다양한 배합비의 플라이애쉬 혼입 콘크리트를 실험한 후 그 결과를 분석·고찰함으로써 내구성 콘크리트의 제작 시 혼화재로서의 적용성 및 타당성을 검증하고자 하며, 플라이애쉬를 내구성 재료로 그 활용을 극대화하고, 다양한 플라이애쉬의 사용량과 물/결합재비(W/B)에 대하여 내구성이 높은 고강도 콘크리트 제조방법을 범용화하며, 그 품질을 평가하는 것을 목적으로 한다.

• Journal of the Korea Concrete Institute
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• v.15 no.1
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• pp.43-51
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• 2003

Recently, to consider financial and constructive aspect usage of Admixture such as Blast-Furnace Slag and Fly-Ash, are increased. Also the use of cold-weather-concrete is increased. Blast-Furnace Slag, a by-product of steel industry, have many advantage to reduce the heat of hydration, increase in ultimate strength and etc. But it also reduces early-age strength, so it is prevented from using of Blast-Furnace Slag at cold-weather-concrete. In this study, for the purpose of increasing usage of Blast-Furnace Slag at cold-weather-concrete, it is investigated the strength properties of concrete subjected to frost damage for the cause of early age curing. The factors of this experience to give early frost damaged were Freezing temperature(-1, -10, $-15^{\circ}C$), Early curing age(0, 12, 24, 48hour), Freezing times(0, 12, 24, 48hour). According to this study, if early curing is carried out before haying frost damage, the strength of concrete used admixture, subjected to frost damage, is recovered. And that properties are considered, the effect of using admixture like blast-furnace-slag, is very high

• Journal of the Korea Concrete Institute
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• v.27 no.4
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• pp.427-434
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• 2015

The objective of this study is to establish an rational mixture-proportioning procedure for low-$CO_2$ concrete using supplementary cementitious materials (SCMs) achieving the targeted $CO_2$ reduction ratio as well as the conventional requirements such as initial slump, air content, and 28-day compressive strength of concrete. To evaluate the effect of SCM level on the $CO_2$ emission and compressive strength of concrete, a total of 12537 data sets were compiled from the available literature and ready-mixed concrete plants. The amount of $CO_2$ emission of concrete was assessed under the system boundary from cradle to concrete production stage at a ready-mixed concrete plant. Based on regression analysis using the established database, simple equations were proposed to determine the mixture proportions of concrete such as the type and level of SCMs, water-to-binder ratio, and fine aggregate-to-total aggregate ratio. Furthermore, the $CO_2$ emissions for a given concrete mixture can be straightforwardly calculated using the proposed equations. Overall, the developed mixture-proportioning procedure is practically useful for determining the initial mixture proportions of low-$CO_2$ concrete in the ready-mixed concrete field.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.2
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• pp.94-99
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• 2018

The purpose of this study is to investigate the effect of combinations of different accelerators mixed on the early age strength development of concrete of 21 to 27MPa in the curing temperature of $10^{\circ}C$ compared with existing early strength agent. The present study was assessed the early strength development of combinations of three different accelerating admixtures with early strength type agent comparing to single accelerating admixture with early strength type agent. As a result of this study, the effect of $CaBr_2+NaSCN+DEA$ combination on strength development showed better than $CaBr_2$ or NaSCN alone with early strength type agent. Therefore, we observed that concrete using $CaBr_2+NaSCN+DEA$ combination with early strength agent was achieved 5MPa 12hours earlier than use of $CaBr_2$ or NaSCN alone.

• Journal of the Korea Institute of Building Construction
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• v.16 no.6
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• pp.571-578
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• 2016

Recently, review on viability of various industrial by product and natural materials as raw material for concrete has been actively done in aspect of environment-friendly issue and depletion of natural resource. This study conducted fundamental study on the possibility of utilizing mud flat as admixture and filling material for concrete. First, chemical analysis on the viability of mud flat as admixture was done and the researchers compared it with the substance of fly ash and blast furnace slag. According to the result, substance content was proven to be inadequate. In addition, as the replacement rate of mud flat increased, compressive strength and tensile strength decreased. According to the estimated result of chemical substance analysis, possibility of utilizing mud flat as admixture was low. According to the result of experiment done as filling material, 10% ~ 30% replacement rate of mud flat manifested more than 8 Mpa of compressive strength of block which may be utilized for secondary product. However, additional experiment such as making block is required afterward. According to the result of flow experiment, as the replacement rate of mud flat increased, flow value decreased, and through chloride content analysis test, it was proven that mud flat is inappropriate to be applied as steel beam using structure since it has high content of sodium. It may be utilized as products that does not use steel beam such as internal brick.

• Journal of the Korea Institute of Building Construction
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• v.17 no.5
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• pp.445-451
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• 2017

Because of the supply-demand problem of aggregate, recently, the construction sites using 100% crushed sand are increasing and the use of low quality aggregate such as farmland sand is increasing too. When the low quality aggregate is used, the various quality defect of concrete such as the strength reduction, the increase of shrinkage and bleeding can be occurred. Therefore, in this study, the performance improvement PC admixture was developed to minimize the quality defect of plain concrete of basement parking area, when the low quality aggregate was used at the plain concrete of basement parking area. The slump loss to elapsed time test, the compressive strength test, the bleeding test and the drying shrinkage test were carried out.

• Journal of the Korea Concrete Institute
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• v.22 no.2
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• pp.219-228
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• 2010

It has been well known that concrete structures exposed to acid and sulfate environments such as sewer, sewage and wastewater, soil, groundwater, and seawater etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to concrete matrix by forming expansive hydration products due to the reaction between portland cement hydration products and acid and sulfate ions. Objectives of this experimental research are to investigate the effect of mineral admixtures on the resistance to acid and sulfate attack in concrete and to suggest high-resistance concrete mix against acid and sulfate attack. For this purpose, concretes specimens with three types of cement (ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC) composed of different types and proportions of admixtures) were prepared at water-biner ratios of 32% and 43%. The concrete specimens were immersed in fresh water, 5% sulfuric acid, 10% sodium sulfate, and 10% magnesium sulfate solutions for 28, 56, 91, 182, and 365 days, respectively. To evaluate the resistance to acid and sulfate for concrete specimens, visual appearance changes were observed and compressive strength ratios and mass change ratios were measured. It was observed from the test results that the resistance against sulfuric acid and sodium sulfate solutions of the concretes containing mineral admixtures were much better than that of OPC concrete, but in the case of magnesium sulfate solution the concretes containing mineral admixtures was less resistant than OPC concrete due to formation of magnesium silicate hydrate (M-S-H) which is non-cementitious.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.214-221
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• 2018

In this paper, the effects of ferronickel slag powder and admixture on the strength of VR sewer pipe were analyzed. the substitution rate was tested as a variable, and the strength development was studied through the flexural strength, compressive strength and using SEM microscopic analysis. bending strength, compressive strength results and micro analysis using SEM showed the correlation in each case. the substitution rates were 20% and 30% relative to the mass of the OPC respectively, and were substituted according to a constant ratio of ferronickel slag fine powder and mixture. when the substitution ratio was 20%, the strength development was excellent. also, bending strength and compressive strength were the best when the ferronickel slag fine powder, quicklime, gypsum and calcium chloride were used as the admixture, dense microstructural patterns appeared. the possibility of progressive strength development is shown after 28 days.