• Title/Summary/Keyword: 혼합챔버

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Review on Proton Exchange Membranes for Microbial Fuel Cell Application (미생물 연료 전지 적용을 위한 양성자 교환막에 대한 검토)

  • Kim, Ji Min;Patel, Rajkumar
    • Membrane Journal
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    • v.30 no.4
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    • pp.213-227
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    • 2020
  • As unrenewable energy resources have depleted over the years, the demand for renewable energy has increased promoting research for more effective methods to produce renewable energy. The field of fuel cell development, specifically microbial fuel cells (MFCs), has developed because of the dual performance potential of the technology. MFCs convert power by facilitating electrode-reducing organisms such as bacteria (microbes) as a catalyst to produce electrical energy. MFCs use domestic and industrial wastewater as fuel to initiate the process, purifying the wastewater as a result. Proton exchange membranes (PEM) play a crucial role in MFCs as a separator between the anodes and cathodes chambers allowing only protons to effectively pass through. Nafion is the commercially used PEM for MFCs, but there are many setbacks: such as cost, production time, and less effective proton conductivity properties. In this review there will be largely two parts. Firstly, several newly developed PEM are discussed as possible replacements of Nafion. Secondly, MFC based on PEM, blended PEM and composite PEM are summarized.

The Effect of the Core-shell Structured Meta-aramid/Epoxy Nanofiber Mats on Interfacial Bonding Strength with an Epoxy Adhesive in Cryogenic Environments (극저온 환경에서 에폭시 접착제의 물성 향상을 위한 나노 보강재의 표면 개질에 관한 연구)

  • Oh, Hyun Ju;Kim, Seong Su
    • Composites Research
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    • v.26 no.2
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    • pp.129-134
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    • 2013
  • The strength of adhesive joints employed in composite structures under cryogenic environments, such as LNG tanks, is affected by thermal residual stress generated from the large temperature difference between the bonding process and the operating temperature. Aramid fibers are noted for their low coefficient of thermal expansion (CTE) and have been used to control the CTE of thermosetting resins. However, aramid composites exhibit poor adhesion between the fibers and the resin because the aramid fibers are chemically inert and contain insufficient functional groups. In this work, electrospun meta-aramid nanofiber-reinforced epoxy adhesive was fabricated to improve the interfacial bonding between the adhesive and the fibers under cryogenic temperatures. The CTE of the nanofiber-reinforced adhesives were measured, and the effect on the adhesion strength was investigated at single-lap joints under cryogenic temperatures. The fracture toughness of the adhesive joints was measured using a Double Cantilever Beam (DCB) test.

Separation Technology of Pure Zirconia from Zirconsand by the Ar-H2 Arc Plasma Fusion and Sulfuric Acid Leaching with Microwave Irradiation (Ar-H2플라즈마 건식제련과 마이크로웨이브침출을 통한 지르콘샌드로부터 고순도 지르코니아 분리)

  • Lee, Jeong-Han;Hong, Sung-Kil
    • Resources Recycling
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    • v.25 no.3
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    • pp.49-54
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    • 2016
  • In this study, zircon sand is separated into zirconia and silica by using the Ar-$H_2$ arc plasma refining. And then silica is removed from it by the microwave leaching method to produce a high pure zirconia. Plasma melting consist of two sequential processes; reduction process with Ar gas only followed by refining process with Ar-$H_2$ gas. After cooling in chamber. The solid phase obtained at $240^{\circ}C$ were found to be composed of 20% sulfuric acid solution. The solution was used as a leaching solution with microwave irradiation to obtain a high purity zirconia.

The Phase Transition and Breakdown Characteristics of SF6 in a Temperature Decline (온도저하에 따른 SF6의 상전이 및 절연특성)

  • Kim, Jong-Whan;Choi, Eun-Hyuck;Park, Kwang-Seo;Yoon, Dae-Hee;Kim, Lee-Kook;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.8
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    • pp.144-149
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    • 2005
  • In this paper, insulations characteristics by temperature changes($+30{\sim}-40[^{\circ}C]$) of $SF_6$ gas in the experimental chamber were studied. From this result, The breakdown characteristics classify the vapor stage of $SF_6$ according the Paschen's law, the gas & liquid coexisted stage of voltage value increases & much deviation and the VB low stage as the interior of chamber gets filled with mixture of $SF_6$ that are not liquefacted and remaining air which couldn't be ventilated. In addition the ability of insulation of liquid $SF_6$ was higher than that of the highly pressurized $SF_6$ gas. In this research, we want to provide the base data on designing insulation of high-temperature superconductor and the cryogenic equipments by investigating the insulation characteristics of $SF_6$.

Secondary Flow Patterns of Liquid Ejector with Computational Analysis (액체상 이젝터의 2차측 액체 송출량 특성 전산해석)

  • Kwon, Kwisung;Yun, Jinwon;Sohn, Inseok;Seo, Yongkyo;Yu, Sangseok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.2
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    • pp.183-190
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    • 2015
  • An ejector is a type of non-powered pump that is used to supply a secondary flow via the ejection of a primary flow. It is utilized in many industrial fields, and is used for fueling the vehicle because of less failures and simple structure. Since most of ejectors in industry are gas-to-gas and liquid to gas ejector, many research activities have been reported in optimization of gas ejector. On the other hand, the liquid ejector is also applied in many industry but few research has been reported. The liquid ejector occurs cavitation, and it causes damage of parts. Cavitation has bees observed at the nozzle throat at the specified pressure. In this study, a two-dimensional axisymmetric simulation of a liquid-liquid ejector was carried out using five different parameters. The angle of the nozzle plays an important role in the cavitation of a liquid ejector, and the performance characteristics of the flow ratio showed that an angle of $35^{\circ}$ was the most advantageous. The simulation results showed that the performance of the liquid ejector and the cavitation effect have to be considered simultaneously.

Effect of Temperature on Interlaminar Fracture Toughness of Filament-Wound Carbon/Epoxy Composites (필라멘트 와인딩된 카본/에폭시 복합재의 층간파괴인성에 미치는 온도 영향)

  • Im, JaeMoon;Shin, KwangBok;Hwang, Taekyung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.5
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    • pp.491-497
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    • 2015
  • This paper reports an experimental study for evaluating the effect of temperature on the mode I, mode II and mixed-mode interlaminar fracture toughness of adhesive joints with a curved cross-section of filament-wound dome-separated composite pressure vessel. Mode I and mixed-mode interlaminar fracture toughness were evaluated using DCB specimens, while mode II interlaminar fracture toughness was determined using ENF specimens. $[{\pm}10^{\circ}]_6$, $[{\pm}27^{\circ}]_6$ and ($[{\pm}10^{\circ}]_3/FM73/[{\pm}27^{\circ}]_3$) winding specimens with the curved cross-section were considered. In-situ temperature environments were simulated with a range of $-30^{\circ}C-60^{\circ}C$ using an environmental chamber and furnace. Experimental results on the effect of temperature indicate that interlaminar fracture toughness tends to be high at low temperature and is degraded with increase in temperature. For specimen types, it was found that interlaminar fracture toughness of $[{\pm}10^{\circ}]_3/FM73/[{\pm}27^{\circ}]_3$ winding specimens considered as adhesive joints of dome and helical part was higher than other specimens.

Behavior of cement-based permeation grouting in cohesionless soil considering clogging phenomena (폐색효과를 고려한 사질토의 시멘트 침투 그라우팅 거동 특성)

  • Seo, Jong-Woo;Lee, In-Mo;Kim, Byung-Kyu;Kwon, Young-Sam
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.2
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    • pp.485-500
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    • 2018
  • The behavior of cement-based permeation grouting is divided into three different groups depending on the grain size distribution of the soils: (1) zone of cement-based permeation grouting not feasible; (2) zone of cement-based permeation grouting feasible; and (3) zone in which an accelerating agent should be added to limit the penetration depth. In the cement-based permeation grouting feasible zone, the concept of a representative pore radius was proposed. The ratios of the representative pore radius to the mean pore radius were obtained by performing laboratory test and comparing with clogging theory; these values were in the range of 1.07 and 1.35 depending on the grain size distribution of the soils. In addition, a functional relationship between the lumped parameter (${\theta}$), the representative pore radius and the w/c ratio were derived by comparing and matching experimental results with predictions from theory. In the zone in which the accelerating agent should be added, the controlling process of gel time to limit the penetration depth was experimentally verified. The test results matched well with those obtained from theory utilizing the developed grout penetration program on condition that the viscosity increasing tendency of grout suspension with time is properly taken into account.

Unfrozen Water Content and Unconfined Compressive Strength of Frozen Soils according to Degree of Saturations and Silt Fractions (포화도와 실트 함량에 따른 동결토의 부동 수분량 및 일축압축강도 특성)

  • Kim, Sang Yeob;Hong, Won-Taek;Hong, Seung Seo;Baek, Yong;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.32 no.12
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    • pp.59-67
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    • 2016
  • The strength of frozen soils is affected by size and shape of particles, and the amount of ice and unfrozen water. The objective of this study is to characterize the unfrozen water content and the unconfined compressive strength of the frozen soils according to the degree of saturations and silt fractions. The specimens are mixtures of sand, silt, and water. The silt fractions (SF), which are the ratio of the silt weight ($W_{silt}$) to the sand weight ($W_{sand}$), are 10% and 30%. In addition, the degrees of the saturation are 5%, 10%, 15%, and 20%. The specimens are frozen under the temperature of $-10^{\circ}C$ conditions. The uniaxial compression tests are conducted for 24 hours, 48 hours, and 72 hours after freezing to determine proper freezing time. The freezing time of 24 hours is chosen because the unconfined compressive strengths of specimens after 24 hours freezing times are similar to each other. Furthermore, the unfrozen water content is monitored during freezing using the TDR system. The unfrozen water content increases with the increase of the silt fraction and degree of saturation. The unconfined compressive strength of the frozen soils exponentially increases with increasing the degree of saturation. This study shows that the amount of ice has more influence on the strength of the frozen soils than the amount of unfrozen water.

Study on Correlation between Dynamic Cone Resistance and Shear Strength for Frozen Sand-Silt Mixtures under Low Confining Stress (낮은 구속응력에서 모래-실트 혼합토의 동결강도 평가를 위한 동적 콘 저항력 및 전단강도 상관성 연구)

  • Kim, Sangyeob;Lee, Jong-Sub;Hong, Seungseo;Byun, Yong-Hoon
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.1
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    • pp.5-12
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    • 2016
  • Investigation of in-situ ground in cold region is difficult due to low accessibility and environmental factors. In this study, correlation between dynamic cone resistance and shear strength is suggested to estimate the strength of frozen soils by using instrumented dynamic cone penetrometer. Tests were conducted in freezing chamber after preparing sand-silt mixture with 2.3% water content. Vertical stresses of 5 kPa and 10 kPa were applied during freezing, shearing, and penetration phase to compare the dynamic cone resistance and shear strength. The dynamic cone resistance, additionally, is calculated to minimize the effect of energy loss during hammer impact. Experimental results show that as the shear strength increases, the dynamic cone penetration index (DCPI) decreases nonlinearly, while the dynamic cone resistance increases linearly. This study provides the useful correlation to evaluate strength properties of the frozen soils from the dynamic cone penetration and direct shear tests.

Uniformity of Large Gypsum-cemented Specimens Fabricated by Air Pluviation Method (낙사법으로 조성된 대형 석고 고결시료의 균질성)

  • Lee, Moon-Joo;Choi, Sung-Kun;Choo, Hyun-Wook;Cho, Yong-Soon;Lee, Woo-Jin
    • Journal of the Korean Geotechnical Society
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    • v.24 no.1
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    • pp.91-99
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    • 2008
  • The method to prepare the large cemented sand specimen for calibration chamber test by air-pluviation is investigated in this study. The uniformity of cemented specimen is evaluated by performing the CPTs, DMTs, and bender element tests in the calibration chamber. The sand particles, pre-wetted with 0.5% water content, are mixed with gypsum to provide the homogeneous coating of gypsum particles on the grain surface. It was shown that the pre-wetting of particle surface is effective to minimize the potential for segregation between sands and gypsum during air-pluviation. It was observed that the extreme void ratios ($e_{max}\;and\;e_{mix}$) of the mixture of pre-wetted sand and gypsum powder increase at lower gypsum content while those of the mixture of dry sand and gypsum decrease with increasing gypsum content. It was also shown from the test results that large cemented specimens reconstituted in calibration chamber by rainer system are quite uniform in vertical and horizontal directions.