• Title/Summary/Keyword: 혼합열

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Liquefaction Characteristics of Polypropylene-Polystyrene Mixture by Pyrolysis at Low Temperature (Polypropylene-Polystyrene 혼합물의 저온 열분해에 의한 액화특성)

  • Cho, Sung-Hyun;Kim, Chi-Hoi;Kim, Su-Ho;Lee, Bong-Hee
    • Clean Technology
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    • v.16 no.1
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    • pp.26-32
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    • 2010
  • The low temperature pyrolysis of polypropylene (PP), polystyrene (PS) and polypropylene-polystyrene (PP-PS) mixture in a batch reactor at the atmospheric pressure and $450^{\circ}C$ was conducted to investigate the synergy effect of PP-PS mixture on the yield of pyrolytic oil. The pyrolysis time was varied from 20 to 80 mins. The products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of Ministry of Knowledge Economy. The analysis of the product oils by GC/MS(Gas chromatography/Mass spectrometry) showed that new components were not detected by mixing of PP and PS. There was no synergy effect according to the mixing of PP and PS. Conversions and yields of PP-PS mixtures were linearly dependent on the mixing ratio of samples except for heavy oil yields. Heavy oil yields showed almost constant regardless of the mixing ratio.

Analysis on Thermogravimetric Characteristics about Copyrolysis of Waste Wood Chip and Linear Low Density Polyethylene (선형 저밀도 폴리에틸렌과 폐목재 우드칩 혼합열분해의 열중량 특성 분석)

  • Lee, Young-Man;Bae, Wookeun;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.87-90
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    • 2011
  • Copyrolysis of biomass/plastic mixture was carried out from room temperature to $600^{\circ}C$ with varing the heating rates of 10, 20, and $30^{\circ}C/min$ using a thermogravimetric analyzer. Waste wood chip (WWC) and linear low density polyethylene (LLDPE) were selected as a biomass and plastic, respectively. Individual pyrolysis temperature ranges were $430{\sim}550^{\circ}C$ and $230{\sim}600^{\circ}C$ for LLDPE and WWC, respectively. For the copyrolysis of WWC and LLDPE, the decomposition temperature range of WWC was not varied, while the decomposition temperature range of LLDEP was increased to a higher temperature. The results imply that the interaction might occur between LLDEP and WWC during copyolyis of LLDPE and WWC.

Extended Unmixing-Mixing Scheme for Prediction of 3D Behavior of Porous Composites (다공성 복합재료의 삼차원 거동 예측을 위한 분리-혼합 기법의 확장)

  • Choi, Hoi Kil;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.2
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    • pp.91-97
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    • 2013
  • Pyrolysis and surface recession of charring composites are progressed primarily in the thickness direction. The unmixing-mixing scheme is applied to describe the in-plane and through-thickness behaviors of porous composites. The extended unmixing-mixing equations are based on transverse isotropy of unidirectionally fiber-reinforced composites. The strain components of gas pressure in pores, thermal expansion, and chemical shrinkage are included in the constitutive model. By analyzing micromechanical representative volume elements of porous composites, the validity of the derived equations are examined.

Study on Hydration Heat Analysis of Pier Foundation-Column Using Low Heat Concrete (저발열 콘크리트를 사용한 교각 기초-기둥의 수화열 해석에 관한 연구)

  • Jeon, Joong-Kyu;Kim, Sun-Gil;Jeon, Chan-Ki;Kim, Ki-Hyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.217-224
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    • 2014
  • This study carried out to evaluate the hydration heat analysis and fundamental characteristics such as air content, slump and compressive strength for field application of low heat concrete with premixed cement. The results of experiment show that low heat concrete with premixed cement have sufficient performances on the workability and compressive strength. In addition, hydration heat analysis shows that low heat concrete with premixed cement make sure of target thermal cracking index. Therefore, it is desirable to apply the low heat concrete with premixed cement on pier foundation-column.

Measurement of Radiative Heat Flux of Nozzle Exit (노즐 후방부의 Radiative Heat Flux 측정)

  • An, Won Geun;Park, Hui Ho;Hwang, Su Gwon;Kim, Yu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.5
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    • pp.87-92
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    • 2003
  • In rocket systems, somtimes special devices or equipments are installed near the nozzle exit area where high temperature and pressure combustion gas flows. To pretect these subsystems from severe thermal environment, it is necessary to have accurate thermal data measured from the experimental liquid rocket firing test. Test variables were combustion pressure (200, 300, 400 psi) and mixture ratio (1.5, 2.0, 2.5) and quartz was used as a heat probe. Measurement technique used in this research can be also applied to measure the radiative heat flux inside the combustion chamber which is important imput data for the liquid rocket regenerative cooling system design.

단요소 충돌형 분사기에 의한 액체추진제 연소성능의 수치적 연구

  • 황용석;윤웅섭
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1999.04a
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    • pp.2-2
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    • 1999
  • 액체추진제 로켓엔진에서 분사기의 미립화 및 혼합 특성과 그에 따른 연소 특성은 성능과 안정성을 결정하는 중요한 파라미터이며 분사기는 제한된 설계 조건하에서 최대의 열방출율을 발휘하도록 설계되어야 한다. 여기서 연소효율은 연료와 산화제의 혼합특성과 충돌 분무의 미립화의 정도에 의해 결정되므로 충돌 분무 유동성의 혼합, 미립화 특성과 이에 따른 인조성능 특성을 명확하게 밝힘으로써 최대 엔진성능을 위한 설계가 가능하게 된다. 분사기의 설계에는 분사요소형태, 분사공의 형상 및 유동시스템 등이 포함되며 특히 분사요소 형태의 선택에는 추진제, 연소실냉각방법, 연소실 형상, 자동조건 및 엔진의 수명 등이 중요한 제한조건으로 고려된다. 이런 형태의 분사 요소들 중, 충돌형 분사기는 저장성 추진제를 사용하는 중, 저추력의 액체추진제 로켓엔진에 주로 사용된다. 이 분사형태는 미립화 성능이 높지 않고, 분사공 직경 및 운동량비에 따른 혼합성능이 만감하며 blow apart 등에 의한 열부하 혹은 안정성에 대한 문제가 있으나 양호한 혼합효율, 신뢰성과 제작의 용이함으로 인하여 광범위하게 사용된다.

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A Study on the Effect of Mid Layer on Supersonic 2D Double Shear Layer (초음속 2차원 2단 혼합층에서 중간층의 역할)

  • Kim, Dongmin;Baek, Seungwook
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.9-17
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    • 2015
  • The basic flow configuration is composed of a plane, double shear layer where relatively thin mid gas layer is sandwiched between air and fuel stream. The present study describes numerical investigations concerning the combustion enhancement according to a variation of mid layer thickness. In this case, the effect of heat release in turbulent mixing layers is important. For the numerical solution, a fully conservative unsteady $2^{nd}$ order time accurate sub-iteration method and $2^{nd}$ order TVD scheme are used with the finite volume method including k-${\omega}$ SST model. The results consists of three categories; single shear layer consists of fuel and air, inert gas sandwiched between fuel and air, cold fuel gas sandwiched between fuel and air. The numerical calculations has been carried out in case of 1, 2, 4 mm of mid layer thickness. The height of total gas stream is 4 cm. The combustion region is broadened in case of inert gas layer of 2, 4 mm thickness and cold fuel layer of 4 mm thickness compared with single shear layer.

Assessment of Practical Use of Recycling Oil from the Pyrolysis of Mixed Waste Plastics (혼합폐플라스틱의 열분해를 통한 회수오일의 이용가능성 평가)

  • Phae Chae-Gun;Kim Young-shin;Jo Chang-Ho
    • Journal of Energy Engineering
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    • v.14 no.2 s.42
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    • pp.159-166
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    • 2005
  • In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

Thermophoresis of highly absorbing, emitting particles suspended in a mixed convection flow system (혼합 대류 유동시스템에 부유된 고흡수 방사하는 입자의 열 확산)

  • Yoa, S. J.
    • Journal of the korean Society of Automotive Engineers
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    • v.14 no.3
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    • pp.115-125
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    • 1992
  • 혼합 대류 이상 유동 시스템에 부유된 슈트와 미분탄과 같은 고흡수, 방사하는 입자의 열확산적 입자이동에 대한 복사 및 부력효과를 수치적으로 검토하였다. 기체 및 입자유동의 지배방정식 들은 Euler 관점의 two-fluid model의 근간에서 수행되었으며, 에너지 보존식의 비선형 복사 생 성항은 P-1 근사방법에 의해 계산되었다. 혼합 대류 유동에서의 입자의 열확산 현상은 복사 열 전달과 커플링되며, 복사효과의 증가는 부력효과를 상대적으로 감소시켜 부력효과에 의한 입자 부착율을 완화시켰다. 복사효과가 무시될 때 Grashof 수의 증가에 따라 입자의 확산효과는 감 소되었으며, 복사효과가 함께 작용될 때 입자 부착율은 증가됨을 보였다.

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