• Applied Chemistry for Engineering
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• v.30 no.5
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• pp.606-614
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• 2019

A mixing ratio of the oil in water (O/W) emulsion of palm oil and the non-ionic surfactant (Tween-Span type) possessing different hydrophile-lipophilie balance (HLB) values was evaluated in this work. An optimum condition was determined through analysis of main and interaction effects of each quantitative factor using central composite design model-response surface methodology (CCD-RSM). Quantitative factors used by CCD-RSM were an emulsification time, emulsification speed, HLB value and amount of surfactant. On the other hand, the reaction parameters were the viscosity and mean droplet size of O/W emersion. Optimized conditions obtained from CCD-RSM were the emulsification time of 12.7 min, emulsification speed of 5,551 rpm, HLB value of 8.0 and amount of surfactant of 5.7 wt.%. Ideal experimental results under the optimized experimental condition were the viscosity of 1,551 cP and mean droplet size of 432 nm which satisfy the targeted values. The average error value from our actual experiment for verifying the conclusions was below to 2.5%. Therefore, a high favorable level could be obtained when the CCD-RSM was applied to the optimized palm oil to water emulsification.

• Proceedings of the KAIS Fall Conference
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• 2012.05a
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• pp.426-430
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• 2012

본 연구에서는 3차원 수치 해석 기법으로 SDR 반응기 내 유동 특성을 모사하여 유동 분포 및 체류 시간등을 확인하고 혼합 특성 개선을 위한 방법에 대해 연구하였다. 본 연구 대상 SDR 반응기는 입구 덕트와 반응기 본체의 접속 구간에 가이드 베인(Guide vane)이 설치되어 있고 그 바로 하부 지점에 흡수제를 분무하는 노즐이 설치되어 있다. 이는 처리가스가 반응기로 유입될 때 가이드 베인에 의해 선회류를 형성하여 분무된 흡수제와의 혼합을 촉진시키기 위한 목적으로 설치하였다. 시간당 1,971$m^3/min$ at $260^{\circ}C$의 처리가스가 반응기 상부로 유입되어 가이드 베인을 거쳐 선회류를 형성한 후흡수제와 혼합되어 하부로 배출되는 구조이다. 유동 특성을 분석한 결과, 처리가스가 반응기 중앙으로 강하게 편중되고 있었으며 반응기 양 측면으로 부상 기류가 형성되고 있음을 확인할 수 있다. 또한 강한 편류에 의해 체류시간도 매우 짧은 것으로 판단되는 바, 가이드 베인의 기류 안내 각도가 적합하지 못함을 확인할 수 있었다. 이는 곧 혼합 특성 저하에 따른 미반응 액적의 다량 발생과 함께 고착에 의한 스케일 형성 가능성이 매우 클 것으로 예상되므로 혼합 특성을 개선할 수 있는 설계 변경이 필요할 것으로 판단되었다. 따라서 편류를 해소하고 노즐 근처에서의 체공시간을 확보할 수 있도록 가이드 베인의 안내 각도를 더 크게 변경한 결과, 기존 설계상에서 본체 중앙에 형성되는 편류가 해소되고 선회류의 전개 각도가 커지면서 체류시간 역시 약 5초 이상으로 유지되고 있음을 확인할 수 있었다. 따라서 가이드 베인의 각도만 변경하더라도 본체 형상의 추가적인 변경없이 유동의 혼합 특성을 개선시킬 수 있을 것으로 판단되었다.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.300-307
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• 2022

Time-resolved serial femtosecond crystallography (TR-SFX) is a powerful technique for determining temporal variations in the structural properties of biomacromolecules on ultra-short time scales without causing structure damage by employing femtosecond X-ray laser pulses generated by an X-ray free electron laser (XFEL). The mixing rate of reactants and biomolecule samples, as well as the hit rate between crystal samples and x-ray pulses, are critical factors determining TR-SFX performance, such as accurate image acquisition and efficient sample consumption. We here develop two distinct sample delivery systems that enable ultra-fast mixing and on-demand droplet injecting via pneumatic application with a square pulse signal. The first strategy relies on inertial mixing, which is caused by the high-speed collision and subsequent coalescence of droplets ejected through a double nozzle, while the second relies on on-demand pneumatic jetting embedded with a 3D-printed micromixer. First, the colliding behaviors of the droplets ejected through the double nozzle, as well as the inertial mixing within the coalesced droplets, are investigated experimentally and numerically. The mixing performance of the pneumatic jetting system with an integrated micromixer is then evaluated by using similar approaches. The sample delivery system devised in this work is very valuable for three-dimensional biomolecular structure analysis, which is critical for elucidating the mechanisms by which certain proteins cause disease, as well as searching for antibody drugs and new drug candidates.

• Journal of the Korean Society of Propulsion Engineers
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• v.10 no.3
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• pp.9-17
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• 2006

The influences of recess length of a liquid/liquid swirl coaxial injector on spray characteristics were investigated. It was revealed that the internal impinging phenomenon played an important role in the spray characteristics, such as spray angle and breakup length. Also, as the recess length increased, the mean drop size increased due to the increase of effective film thickness and mixing efficiency increased, but in the case of very deep recess length, the mixing efficiency decreased.

• Journal of ILASS-Korea
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• v.4 no.1
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• pp.13-18
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• 1999

It has been known that spray characteristics have an important effect on the mixture formation and directly influence the engine performances and the emissions. Up to now, the measurement of droplet size is well developed such as PDPA and PMAS though the behavior of small droplets during secondary atomization is not clear. Particle image velocimetry(PIV), a planar measuring technique, is a very efficient tool for studying complicated behavior and a fast and reliable method to track numerous droplets during injection. In this study, two-color scanning PIV is designed to obtain quasi-instantaneous two dimensional velocity data by using he-ion laser, rotating mirror and beam splitter. This PIV method which has high temporal and spatial resolution provides the information about the small complex droplet behavior.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.1
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• pp.99-112
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• 1997

Mixing process of impinging jets of liquid oxidizer and liquid fuel is simulated by using water and sodium carbonate (Na$_{2}$CO$_{3}$) solution. The shapes of liquid sheets are visualized and flowrate distributions are measured by collecting droplets using measuring cells. Mixing charateristics are studied by using acid-base titration. Stable liquid sheets are formed and two liquid jets are well mixed for symmetric impinging jets. Similarity in flowrate distribution for various measuring heights is observed. For asymmetric impinging jets, liquid sheets become unstable as the difference in the velocities of jets increases. In some extreme cases, liquid sheets are not formed and the jets are separated. Dimensionless variables are adopted demonstrating similarly in flowrate distribution. Mixing characteristics vary significantly with experiment conditions.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.10a
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• pp.308-313
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• 2005

실리콘 잉고트의 절단공정에서 발생하는 폐실리콘 슬러지는 실리콘과 실리콘카바이드 등의 유가자원이 함유되어 있으며, 이 중 실리콘 분말은 실리콘 화합물인 알콕시실란 등을 제조하는데 원료로 사용이 가능하다. 본 연구에서는 폐실리콘 슬러지로부터 분리, 합성된 사에 톡시실란(TEOS)을 원료로 이용하여 실리카 나노분말을 합성하였다. TEOS 원료물질을 외부 혼합형 이류체 노즐을 이용하여 미세액적으로 분무하고 화염 속으로 도입시키고 화염열분해 반응을 진행시켜 실리카 나노분말을 합성하였다. 합성된 실리카 나노입자의 특성은 투과형 전자현미경 및 BET에 의하여 입자형상 및 평균 입자크기가 분석되었다. 주요 공정변수인 분산공기의 압력, 반응가스의 조성을 변화시켜 실험한 결과 평균크기가 $9{\sim}68nm$인 실리카 나노분말을 제조하였다.

• Journal of Power System Engineering
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• v.3 no.3
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• pp.36-43
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• 1999

Many of thermodynamic-based diesel combustion simulations incorporated a model of fuel spray which attempts to describe how the spray develops according to time. Because the spray geometry is an essential aspect of the fuel-air mixing process, it is necessary to be calculated quantitatively for the purpose of heat release and emission analysis. In this paper, we proposed the calculating method of non-evaporation spray behaviors by injection rate shapes under actual operating conditions of diesel engine. We confirmed the utility of this calculating model as the calculated results were compared with the measured results. This calculating program can be applied usefully to study on the diesel spray behavior.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.10
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• pp.2690-2698
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• 1995

Fuel atomization and mixture formation in an gasoline engine has influence on the engine performance and pollutant emission. The throttle valve installed in an intake system plays a greater role in control of mixture quantity in accordance with engine drive condition. In this study, the characteristics of secondary atomization developed at the downstream of the valves were observed using an image processing method. Two major kinds of valves, solid and perforated ones, are chosen in order to compare the valve performance with the experimental parameters of air flow rate, valve opening angle, and valve shapes. For the perforated valve, we can obtain the relatively small sized droplets, and nearly uniformed and dense distributed sprays with low loss coefficient than for the solid valve.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.11a
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• pp.175-178
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• 2011

본 연구에서는 기존의 고압으로 작동되는 고압 미분무 건과는 달리 Twin-Fluid의 Turbulence 및 Break-up 현상 등을 이용하여 저압상태에서 작동하며 경량화 및 소형화에 성공하여 기존 소방관의 진입이 어려운 장소 또는 수원으로부터 멀리 떨어진 곳에서 원활한 소화활동을 위해 개발한 저압용 미분무 건의 성능을 화재소화능력 시험을 통해 입증하였다. 화재 소화능력 시험을 수행한 결과 물과 질소가 Mixing Chmaber 내부에서 혼합되면서 두 유체간의 상호작용 및 운동 에너지으로 인해 물의 액적이 미세하게 Atomizing되어 목재화재는 물론 유류화재의 진압에 있어서도 우수한 성능을 확인할 수 있었다.