• Title/Summary/Keyword: 혼합면적식

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Preparation and Characterization of Bamboo-based Activated Carbon by Phosphoric Acid and Steam Activation (인산 및 수증기 활성화에 의한 대나무 활성탄 제조 및 특성 연구)

  • Park, Jeong-Woo;Ly, Hoang Vu;Oh, Changho;Kim, Seung-Soo
    • Clean Technology
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    • v.25 no.2
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    • pp.129-139
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    • 2019
  • Bamboo is an evergreen perennial plant, and it is known as one of the most productive and fastest-growing plants in the world. It grows quickly in moderate climates with only moderate water and fertilizer. Traditionally in Asia, bamboo is used for building materials, as a food source, and as versatile raw materials. Bamboo as a biomass feedstock can be transformed to prepare activated carbon using the thermal treatment of pyrolysis. The effect of process variables such as carbonization temperature, activation temperature, activation time, the amount of steam, and the mixing ratio of phosphoric acid and bamboo were systematically investigated to optimize the preparation conditions. Steam activation was proceeded after carbonization with a vapor flow rate of $0.8{\sim}1.8mL-H_2O\;g-char^{-1}\;h^{-1}$ and activation time of 1 ~ 3 h at $700{\sim}900^{\circ}C$. Carbon yield and surface area reached 2.04 ~ 20.59 wt% and $499.17{\sim}1074.04m^2\;g^{-1}$, respectively, with a steam flow rate of $1.4mL-H_2O\;g-char^{-1}\;h^{-1}$ for 2 h. Also, the carbon yield and surface area were 24.67 wt% and $1389.59m^2\;g^{-1}$, respectively, when the bamboo and phosphoric acid were mixed in a 1:1 weight ratio ($700^{\circ}C$, 2 h, $1.4mL-H_2O\;g-char^{-1}\;h^{-1}$). The adsorption of methylene blue into the bamboo activated carbon was studied based on pseudo first order and second order kinetics models. The adsorption kinetics were found to follow the pseudo second order model, which is governed by chemisorption.

Sorptive Removal of Radionuclides (Cobalt, Strontium and Cesium) using AMP/IO-PAN Composites (AMP/IO-PAN 복합체를 이용한 방사성 핵종(코발트, 스트론튬, 세슘)의 흡착 제거)

  • Park, Younjin;Kim, Chorong;Shin, Won Sik;Choi, Sang-June
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.259-269
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    • 2013
  • Applicability of ammonium molybdophosphate/iron oxides-polyacrylonitrile (AMP/IO-PAN) composites on the removal of radionuclides in the radioactive wastewater generated from nuclear power plants was investigated. The composites were characterized using the following analytical techniques: X-ray diffraction (XRD), Fourior transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), particle size analyzer (PSA), nitrogen adsorption-desorption and magnetic property measurement system (MPMS). 10wt% of AMP/IO-PAN composite has a saturation magnetization of 2.038 emu/g. Single-solute sorptions of Co, Sr and Cs onto 10wt% of AMP/IO-PAN composite were investigated. The maximum sorption capacities ($Q^0$) predicted by the Langmuir model on 10wt% of AMP/IO-PAN composite were 0.097, 0.086 and 0.66 mmol/g for Co, Sr and Cs, respectively. The maximum sorption capacities ($Q^0$) of Cs predicted by Langmuir model on 0, 10, 20 and 30wt% of AMP/IO-PAN composites were 0.702, 0.655, 0.602 and 0.559 mmol/g, respectively. The maximum sorption capacities ($Q^0$) of Cs decreased with increasing the iron oxide content in the AMP/IO-PAN composites.

Yield Driven VLSI Layout Migration Software (반도체 레이아웃의 자동이식과 수율 향상을 위한 자동화 시스템의 관한 연구)

  • 김용배;신만철;김준영;이윤식
    • Proceedings of the Korean Information Science Society Conference
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    • 2001.04a
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    • pp.37-39
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    • 2001
  • 반도체 설계는 급속한 기능 추가와 기가 헬쯔에 육박하는 고속 동작에 부응하는 제품의 설계와 빠른 출시를 위하여 다방면의 연구를 거듭하고 있다. 하지만, 인터넷과 정보 가전의 모바일 기기에서 요구하는 폭발적인 기능의 추가와 가전기기의 최소화를 위하여서는 그 요구를 감당하지 못하고 있다. 이를 위한 방안으로 설계 재활용과 System-On-Chip의 설계가 수년 전부터 대두되었으나 아직 큰 실효를 거두지 못하고 있다. SoC설계는 다기능을 한 칩에 구성하는 방법을 시도하고 있고, 설계 재활용은 기존의 설계(IP)를 다른 것과 혼합하여 필요한 기능을 제공하는 방법이 시도되고 있다. 이 두가지의 VLSI 설계 방식 흐름을 가능하도록 하기 위한 연구로써, 레이아웃 이식에 관한 연구를 진행하였다. IP 재활용을 위하여서는 다양한 공정변화에 신속히 대응하고, 기존의 설계 설계규칙으로 설계된 면을 현재의 공정인 0.25um, 0.18um 테크놀러지에 맞도록 변환하는 VLSI 소프트웨어 시스템을 필요로 한다. 레이아웃 설계도면을 분석하여 소자 및 배선을 인식하는 알고리즘을 연구와 개발하고, 도면을 첨단 테크놀러지의 설계 규칙에 부응하도록 타이밍, 소비 전력, 수율을 고려한 최적의 소자 및 배선의 크기를 조절하는 방법을 고안하며, 칩 면적을 최적화할 수 있는 컴팩션 알고리즘을 개발하여 레이아웃 설계 도면을 이식할 수 있는 자동화 소프트웨어 시스템을 연구하였다. 더불어, 현재 반도체 소프트웨어 시스템의 최대 문제점에 해당하는 처리 속도와 도면의 처리 능력을 비교, 검토하여 본 연구가 속도면에서 평균 27배 효율면에서 3배 이상의 상대우위를 점하였다.전송과 복원이 이루어질 것이다.하지 않은 경우 단어 인식률이 43.21%인 반면 표제어간 음운변화 현상을 반영한 1-Best 사전의 경우 48.99%, Multi 사전의 경우 50.19%로 인식률이 5~6%정도 향상되었음을 볼 수 있었고, 수작업에 의한 표준발음사전의 단어 인식률 45.90% 보다도 약 3~4% 좋은 성능을 보였다.으로서 hemicellulose구조가 polyuronic acid의 형태인 것으로 사료된다. 추출획분의 구성단당은 여러 곡물연구의 보고와 유사하게 glucose, arabinose, xylose 함량이 대체로 높게 나타났다. 점미가 수가용성분에서 goucose대비 용출함량이 고르게 나타나는 경향을 보였고 흑미는 알칼리가용분에서 glucose가 상당량(0.68%) 포함되고 있음을 보여주었고 arabinose(0.68%), xylose(0.05%)도 다른 종류에 비해서 다량 함유한 것으로 나타났다. 흑미는 총식이섬유 함량이 높고 pectic substances, hemicellulose, uronic acid 함량이 높아서 콜레스테롤 저하 등의 효과가 기대되며 고섬유식품으로서 조리 특성 연구가 필요한 것으로 사료된다.리하였다. 얻어진 소견(所見)은 다음과 같았다. 1. 모년령(母年齡), 임신회수(姙娠回數), 임신기간(姙娠其間), 출산시체중등(出産時體重等)의 제요인(諸要因)은 주산기사망(周産基死亡)에 대(對)하여 통계적(統計的)으로 유의(有意)한 영향을 미치고 있어 $25{\sim}29$세(歲)의 연령군에서, 2번째 임신과 2번째의 출산에서 그리고 만삭의 임신 기간에, 출산시체중(出産時體重) $

Performance Evaluation of a Portable GC for Real-time Monitoring of Volatile Organic Compounds (휘발성 유기화합물의 실시간 모니터링을 위한 휴대형 GC의 성능 평가)

  • You, Dong-Wook;Seon, Yeong-Sik;Oh, Jun-Sik;Yi, Bongyoon;Kim, Hyun Sik;Jung, Kwang-Woo
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.327-333
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    • 2020
  • Performance of a portable GC that can be utilized for the real time determination of volatile organic compounds in air was evaluated. It employs purified/compressed ambient air as the carrier gas eliminating the need for high pressure gas tanks. The compact system with dimensions of 35 × 26 × 15 ㎤ and weight of 5 kg is powered by either a 24 V DC external adapter or battery pack. Chromatograms of the mixture sample including benzene, toluene, ethylbenzene, and oxylene at concentrations of 1 ppmv and 20 ppmv represent a good reproducibility: 3.79% and 0.48% relative standard deviations (RSDs) for peak area variations; 0.40% and 0.08% RSDs for retention times. The method detection limit was 0.09 ppmv. A 30 m long, 0.28 mm I.D. column operated at an optimal condition yielded a peak capacity of 61 with good resolution for a 10 min isothermal analysis. The relative standard deviations (RSD) of the peak area variations and retention times during consecutive measurements over 27 h were less than 2.4%RSD and 0.5%RSD, respectively. Thus, this instrument makes it suitable for continuous and field analysis of low-concentration VOC mixtures in the indoor/outdoor environment as well as the spillage accident of hazardous chemicals.

Agroforestry Site-suitability Analysis in Suan-gun, Hwanghaebuk-do, North Korea (임농복합경영 대상지 적지 분석: 북한 황해북도 수안군을 중심으로)

  • Sookyung, Kwon;Soyoung, Park;Soonduck, Kwon
    • Journal of Korean Society of Forest Science
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    • v.111 no.4
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    • pp.667-675
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    • 2022
  • Agroforestry is an ecological and economic land-use system that enables sustainable agriculture by combining forestry, agriculture, and livestock industries. North Korea chose agroforestry as a strategy for the restoration of sloping land and deforested land. Agroforestry was proposed for the inter-Korean forest cooperation subcommittee meeting and is currently highlighting carbon removal and promoting the '2050 Carbon Neutral Strategy' and 'Korea Peninsula Green Détente.' The study area, Suan-gun, Hwanghaebuk-do, is a constant deforestation monitoring area and a pilot site for management by the International Center for Research in Agroforestry. The requirements for agroforestry were analyzed through literature analysis. The agroforestry site-suitability map was visualized by applying GIS overlap analysis. Approximately 8,839 ha of sloping area was selected as suitable for agroforestry management, which is about 15% of Suan. We compared the map with Google Earth images and visually detected the land use status, such as agroforestry in Suan, to verify the results. As a future study, we will consider both natural-environment and socioeconomic factors and evaluate the relative importance of the factors to produce a high-accuracy agroforestry sitesuitability map at the national scale with the goal of producing basic data for the inter-Korea forest cooperation policy for long-term goals.

Sorption Behavior of $^{241}Am,\;^{152}Eu,\;^{160}Tb\;and\;^{60}Co$ in the Geological Materials: Eu as an Optimum Analogue for Fate and Transport of Am Behavior in Subsurface Environment (지질매체내에서의 $^{241}Am,\;^{152}Eu,\;^{160}Tb,\;^{60}Co$의 흡착특성비교: 지표지질내에서의 Am의 거동특성을 위한 최적 유사체로서의 Eu)

  • Lee, Seung-Gu;Lee, Kil-Yong;Cho, Soo-Young;Yoon, Yoon-Yeol;Kim, Yong-Je
    • Economic and Environmental Geology
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    • v.40 no.4
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    • pp.361-374
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    • 2007
  • Rare earth elements(REEs) have been used as an useful tool in understanding the various geological processes such as evolution and differentiation in the crust. The REEs also have been used as an analog of actinides for radioactive wastes at the water-rock interactions. Using physicochemical properties of the REEs and actinides, we have shown that Eu is an optimum analogue for understanding the behavior of Am in subsurface environments. Factors affecting sorption behavior of radioactive nuclides in groundwater were investigated by batch experiments. Four nuclides such as $^{241}Am,\;^{152}Eu,\;^{160}Tb\;and\;^{60}Co$ were selected to test our hypothesis, and $^{160}Tb$ and $^{60}Co$ were specifically used to compare to the sorption behavior between $^{241}Am-^{152}Eu$ and other radioactive nuclides. Four different rock samples and one groundwater were used in the batch experiments where solution pH for all experiments was fixed at 5.5. Our results demonstrate that $^{241}Am,\;^{152}Eu,\;and\;^{160}Tb$ show similar sorption behavior whereas $^{60}Co$ is different in sorption behavior at the mineral-water interface, suggesting that the sorption behavior of $^{60}Co$ is affected by different rock types. Our results also show that 1) Eu in REEs is optimum analogue of fate and transport of Am in subsurface environments, and 2) mineral compositions such as $SiO_2,\;TiO_2,\;P_2O_5$ and distribution of REEs such as Eu anomaly play key roles in affecting sorption behavior of radioactive nuclides even though physicochemical properties of geological materials such as specific surface area and cation exchange capacity can not be ruled out.

Variations of Physical Properties Depending on the Height of Reactor in Vertical Composting Process (수직형 퇴비화공정에서 반응조 높이구간별 퇴비화물질의 물성변화에 관한 연구)

  • Kim, Yong Seong;Kim, Byung Tae;Lee, Chang Hae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.4
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    • pp.115-124
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    • 2007
  • The material compressions in the vertical composting reactor affect to the biodegradation rates of the organic wastes. This study investigated the variations of physical properties of the composting materials according to the height of reactor due to affect to the settlement in the vertical composting reactor. The variations of decreased temperature after peak temperature showed the different patterns depending on the reactor heights. The variation width of re-increased temperature after peak temperature was reduced as the mixing operations were increased, and increased as the height of reactor elevated. The moisture content and the variation width of the moisture content were increased higher as the height of the reactor became higher. The variations of the bulk density at each height of vertical reactor showed the same tendency comparing with those of the moisture content. The relationship between bulk density and moisture content had shown the quadratic equation (r2=0.94). The dry solid contents at each reactor height were decreased as the height of reactor were increased. The results of the variation of the physical properties during the composting process were caused by the downward compression of the material into the reactor. Settlement rate in the vertical composting reactor was estimated about 2.184cm/day. To increase the biodegradation efficiency in the vertical reactor, the conditions of air path in the composting material matrix have to be investigated afterwards.

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