• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.9 no.2
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• pp.198-209
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• 1997

This paper is concerned about the performance of alternative refrigerants of R-502 which has been widely used in transport and low temperature refrigeration. A breadboard heat pump was constructed with counterflow heat exchangers and tested with R-502 and transitional alternatives of R-402A and R-402B and long-term alternatives of R-404A and R-507 to compare the performance of each refrigerant. Measurements were conducted at two different condensing temperatures of $43.3^{\circ}C$ and $52.0^{\circ}C$ and the evaporating temperature was varied over a range from $-25^{\circ}C$ to $-5^{\circ}C$. The evaporator superheat and condenser subcooling were maintained constant at about $5^{\circ}C$ for all tests. Test results showed that all alternative fluids tested in this research work can be used as 'drop-in' fluids to replace R-502 without any major problem. It is also found that in the long run HFC alternatives are to be used due to their favorable environmental characteristics and better performance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.4
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• pp.411-422
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• 1998

In this study, experiments were carried out to provide nucleate pool boiling heat transfer data for a plain tube and 4 different low fin tubes employing 2 refrigerant mixtures of R410A, R407C, and 12 pure fluids. Low fin tubes were machined on a 19.05mm nominal outside diameter copper block according to the manufacturer's low fin tube specifications. Cartridge heaters were used to generate uniform heat flux on the tubes. For all refrigerants, heat flux varied from 10㎾/$\m^2$ to 80㎾/$\m^2$. It is found that heat transfer coefficients(HTCs) of high vapor pressure refrigerants are usually higher than those of low pressure fluids. On the other hand, the fin effect was more prominent with low pressure refrigerants than with high pressure ones. Optimum fin density as well as the increase in heat transfer coefficient with the increase in fin density were found to be strongly fluid dependent. HTCs of Rl23, a low pressure alternative refrigerant, were similar to those of Rll while HTCs of R134a, an intermediate pressure alternative refrigerant, were roughly 20% higher than those of Rl2. Finally, HTCs of R32, R125, R143a, and R410A were all higher than those of R22 by 30~50%.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.462-469
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• 2016

This paper presents the results of thermodynamic cycle analysis and performance tests of alternative mixtures in low temperature applications. Two near-azeotropic binary mixtures R-152a/R-1270 (35:65 by wt.%) and R-290/E170 (35:65 by wt.%) are considered in this study. They have zero ODP (Ozone Depletion Potential) and much lower GWP (Global Warming Potential) than R-404A which is an alternative of R-502. Refrigeration cycle characteristics such as cooling capacity, coefficient of performance, suction and discharge pressures and temperatures are compared to those for the baseline refrigerants (R-502 and R-404A) cycles. The performance tests are conducted at the evaporation and condensation temperatures of $5^{\circ}C$ and $45^{\circ}C$, subcooling and superheating temperatures of $5^{\circ}C$, respectively. Performance comparisons between baseline and alternative refrigerants are conducted on the same cooling capacity. The system performance of newly proposed refrigerant mixtures show promising results.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.4
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• pp.654-666
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• 1995

R502 has been extensively used as a working fluid in transport refrigerating vehicles and low temperature refrigerating machines but is to be phased out by the end of 1995 due to ozone layer depletion problem. In this study, both theoretical cycle analysis and experiments were carried out to examine the best substitutes for R502. Theoretical results indicate that the alternatives available in the market today may replace R502 without significant changes in the system without suction line heat exchanger(SLHX). When the system contains a SLHX, however, COPs of the alternatives increase up to approximately 15~20% than those without the SLHX. But simultaneously, the discharge temperatures of the compressor also increrease significantly with the SLHX. Actual test results obtained from the experiment with a transport vehicle's refrigerator indicate the similar trend as those of the theoretical results. Especially, HFCs and their mixtures show lower discharge temperature than those of R502, which is one of the desirable features. Further research is needed to study the effect of the SLHX on the performance of the real machine as well as on the oil return for reliability of the system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.3
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• pp.292-302
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• 1998

In this study, 14 refrigerant mixtures composed of R32, R125, R134a, R143a, R152a, and R1270(Propylene) were tested in a breadboard heat pump in an attempt to replace R22 used in most of the residential air conditioners and heat pumps. The heat pump was of 1 ton capacity and water was employed as the secondary heat transfer fluids. All tests were conducted under ARI test A condition. Ternary mixtures composed of R32, R125, and R134a were shown to have 4∼5% higher COP and capacity than R22 and hence they seem to be very promising candidates to replace R22. On the other hand, ternary mixtures containing R125, R134a, and R152a have lower COP and capacity than R22. R32/R134a binary mixtures show a 7% increase in COP and have the similar capacity to that of R22 and hence they are also good candidates to replace R22. Special care must be exercised when a suction line heat exchanger is used with these mixtures in air conditioners. Finally, the compressor discharge temperatures of all mixtures tested were lower than those of R22 by 15.g∼34.7t, which indicates that these mixtures would offer better system reliability and longer life time than R22.

• Journal of Energy Engineering
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• v.18 no.3
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• pp.203-211
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• 2009

Vapor pressure of HFC-404a and polyol ester system were measured at 56 points from 263.15 to 323.15 K and from 0 to 90 mass %polyol ester. It was found that below 273.15 K, the effect of the polyol ester on the vapor pressure was negligible up to 30 mass % polyol ester. The vapor pressure of the system significantly decreased as the mass fraction of polyol ester increased over 50 percent. Raoult's model and Flory-Huggins model were tested for data reduction. Empirical vapor pressure equations were obtained in terms of temperature and mass fraction of polyol ester.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.254-266
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• 1996

Boiling heat transfer coefficients of pure refrigerants(R22, R32, R125, R134a, R290, and R600a) and refrigerant mixtures(R32/R134a and R290/R600a) are measured experimentally and compared with several correlations. Convective boiling term of Chen's correlation predicts experimental data for pure refrigerants fairly well(root-mean-square error of 12.1% for the quality range over 0.2). An analysis of convective boiling heat transfer of refrigerant mixtures is performed for an annular flow to study degradation of heat transfer. Annular flow is the subject of this analysis because a great portion of the evaporator in refrigeration or air conditioning system is known to be in the annular flow regime. Mass transfer effect due to composition difference between liquid and vapor phases, which is considered as a driving force for mass transfer at interface, is included in this analysis. Correction factor $C_F$ is introduced to the correlation for the pure substances through annular flow analysis to apply the correlation to the mixtures. The flow boiling heat transfer coefficients are calculated using the correlation considering nucleate boilling effect in the low quality region and mass transfer effect for nonzazeotropic refrigerant mixtures.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.2
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• pp.730-740
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• 1996

Boiling heat transfer coefficients of pure refrigerants (R22, R32, R134a, R125, R290, and R600a) and refrigerant mixtures (R32/Rl34a, R290/ R600a, and R32/R125) are measured experimentally and compared with Chen's correlation. The test section is a seamless stainless steel tube with inner diameter of 7.7mm and uniformly heated by applying electric current directly to the tube. Heat fluxes range from 10 to 30kW$^2$. Mass fluxes are set to 424 ~ 742kg/m$^{2}$s for R22, R32, R134a, R32/R134a, and R32/Rl25 ; 265 ~ 583kg/m$^{2}$s for R290, R600a, and R290/R600a. Heat transfer coefficients depend strongly on heat flux at a low quality region and become independent as quality increases. Convective boiling term in the Chen's correlation predicts experimental data of the pure refrigerants fairly well (relative error of 12.1% for the data of quality over 0.2). The correlation for pure substances overpredicts the heat transfer coefficients for nonazeotropic refrigerant mixtures.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.2
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• pp.210-218
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• 1998

Experimental results for forced convection condensationof Refrigerant-22 and ternary Refrigerant-407c(HFC-32/125/134a 23/25/52 wt%) considered as a substitute R-22 inside horizontal micor-fin tubes are presented. The test section was horizontal double-tubed counterflow condenser with a length 4000 mm micro-fin tube having 9.53 mm OD., 0.2 mm fin height and 60 fins. The refrigerants R-22 and R-407c were cooled by a coolant circulated in a surrounding annulus. The range of parameters of mass velocity was varied from 102.1 to 301.0kg/($\textrm{m}^{2}.s$) with inlet quality 1.0. Both refrigerant R-22 and its alternative refrigerant R-407c were tested within the same range of parameters. At the given experimental conditions for R-22 and R-407c the pressure drops for R-407c were considerably higher than those for R-22 at micro-fin tubes. Over the mass velocity range tested the PF(penalty factor)was lower than the increasing ratio of heat transfer area by fins. Based on the data correlation was proposed for predicting the frictional pressure drops for R-22 and R-407c for a duration of condensation inside a horizontal micro-fin tube.

• Proceedings of the SAREK Conference
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• 2005.11a
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• pp.268-273
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• 2005

Because of environmental issues caused by CFC, HCFC or HFC refrigerants, new alternative refrigerants has gained a significant attention. This paper presents experimental information on heat transfer coefficient and pressure drop behavior during evaporation process of R32/290 mixtures in a horizontal smooth tube. A smooth tube with outer diameter of 5 mm and length of 5 m was selected as a test tube. Heat transfer coefficients and pressure drop characteristics were measured for a range of mass fluxes from 497 to 994 $kg/m^2s$, heat fluxes from 12 to 20 $kW/m^2$ and for several mixture compositions(100/0, 75/25, 58.4/41.6, 2s/75, 100/0 by wt% of R32/290). The differences of measured heat transfer characteristics among various R32/290 refrigerant mixtures were analyzed for various compositions.