• Proceedings of the Korean Radioactive Waste Society Conference
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• 2007.05a
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• pp.151-152
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• 2007

ACP(Advanced Spent Fuel Conditioning Process)의 금속전환로에 $U_{3}O_{8}$을 공급하기 위하여 20 kgHM/batch의 $UO_{2}$ 펠릿(pellets)을 처리할 수 있는 공기산화로가 개발되고 있다. 그림 1은 산소농도 조절이 가능한 공기산화로이다. 공기산화로 이전의 공정인 슬리팅 장치에서 탈피복된 $UO_{2}$ 펠릿은 공기산화로로 운반되고, $500^{\circ}C$온도에서 공기를 공급하여 일정한 입도범위의 균질한 $U_{3}O_{8}$을 만든다. 그리고 다음공정의 금속전환장치로 이동된다. 본 논문에서는 모의연료의 산화에 대한 정확한 산소농도를 측정하고자 한다. 이를 위해서 갈바닉 센서와 지르코니움 센서가 사용되었고, 그 특성이 비교되었다. 14종의 금속 산화물이 혼합된 모의연료를 제조하여 산화실험이 수행되었으며, 시간변화에 따라 산소농도가 측정되었다. 산소농도 컨트롤러와 산소 센서를 사용한 공기산화로는 산소조절기에 의해 산소농도 100%까지 측정될 수 있다. 그림 2는 공기산화로의 산소농도를 조절할 수 있는 산소농도 측정시스템이다. 유량조절기(Mass Flow Controller)를 사용하여 질소와 산소의 혼합비를 변화시킬 수 있다. 또한 산소농도 측정시스템은 측정된 산소농도 값을 이용하여 $UO_{2}$의 산화시간을 계산하기 위하여 제작하였다. 산화시간 계산방법은 다음과 같다. 산소와 질소의 가스는 각각 40 L의 압력 봄베에 의해서 산소농도를 조절할 수 있는 공기산화로의 산소농도 측정시스템 안으로 유입된다. 유입된 산소와 질소의 배합은 컨트롤시스템 안에 있는 산소 유량조절기와 질소 유량 조절기를 사용하여 조절하며, 일정하게 혼합된 산소농도는 장치의 입구와 출구에서 산소 센서에 의해서 측정된다. 투입된 $UO_{2}$ 펠릿이 $500^{\circ}C$에서 반응하면서 공기산화로의 내부에 있는 산소농도가 감소된다. 이때 초기에 같았던 입력과 출력 농도가 시간의 흐름에 따라 감소되며, 펠릿이 완전히 산화됨과 동시에 출력 산소농도가 입력농도와 다시 같아질 때까지 소요된 구간이 산화시간이 된다.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.2
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• pp.19-26
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• 2000

This paper presents the effects of initial pressure of mixture on CO, $CO_2$ and NOx emissions in constant volume combustion chamber. The CO, $CO_2,O_2,N_2$ concentrations in the chamber are determined by thermal conductivity detection (Gas-chromatograph) wile the NOx concentration is measured by chemiluminescent detection (NOx Analyser). Methane-air mixture is used as premixed fuel and the measurements are taken with equivalence ratios($\phi$) varing from 0.6 to 1.3, and initial pressures of methane-air mixture varing from 0.1MPa to 0.8MPa in constant volume combustion chamber. The NOx concentration steadily increases with increasing equivalence ratio, peaks in lean flame ($\phi$=0.85~0.9), and then rapidly decreases. However, as the initial pressure of mixture is increased, the equivalence ratio corresponding to the point of peak [NOx] shifts towards leaner conditions. This is caused by a similar shift in the peak [CH], which is caused by the variation with pressure and equivalence ratio of the rate of CH production from $CH_2$ and OH. The maximum combustion pressure peaks at $\phi$ =1.05 and the $CO_2$ concentration peaks at $\phi$=0.95~1.0 while the CO concentration rises sharply at the condition of fuel-rich mixtures. This is caused by complete combustion at $\phi$=0.95.

• Clean Technology
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• v.25 no.3
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• pp.245-255
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• 2019

Pressurized oxy-fuel combustion is a promising technology for $CO_2$ capture with a benefit of improving power plant efficiency compared with atmospheric oxy-fuel combustion. Prior to $CO_2$ compression in this process, a flue gas condenser (FGC) is used to remove $H_2O$ while recovering the latent heat. At the same time, the FGC has a potential for high-efficiency removal of $SO_x$ and $NO_x$ by exploiting their good solubility in water. In this study, experiments were carried out in a lab-scale, direct contact FGC under different pressures varying between 1 and 20 bar to evaluate the removal efficiency of $SO_2$ and $NO_x$ for individual gases and their mixture. In the tests for individual gases, 20% and 76% of $NO_x$ was removed at 1 bar and 10 bar, respectively. Even higher removal efficiencies were achieved for $SO_2$, and also these were maintained for longer as the pressure increased. In the tests for $SO_2$ and $NO_x$ mixture, the removal efficiency of $NO_x$ increased from 13% at 1 bar to 56% at 20 bar because of higher solubility at elevated pressures. $SO_2$ in the mixture was initially dissolved almost completely and then increased by 1,219 ppm at 1 bar and by 165 ppm at 20 bar. Overall, the removal efficiency of $SO_2$ and $NO_x$ was increased at elevated pressures, but it was lower in the mixture compared with individual gases at identical conditions because of a lower pH and associated chemical reactions in water.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11a
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• pp.334-339
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• 1996

Midloop 운전중 RHR 기능 상실사고를 모의 실험한 Bethsy 6.9d에 대해 CATHARE2 코드를 이용하여 해석하였다. 이 실험의 초기조건은 계통수위를 고온관 중간까지 낮추고, 그 윗부분은 비응축 가스로 차 있는 midloop 상태를 유지하는 것이다. 잔열은 원자로 정지 2일 후를 가정한 노심출력을 사용하였으며, 계통내 방출유로는 상부의 Upper head vent와 가압기 vent 및 고온관 1에 연결된 Letdown line과 수위지시계 방출유로가 열려 있다고 가정하였다. 또한 세 개의 loop중 증기발생기 한대만 이유 가능하고, 나머지 두 대는 이차측이 공기로 가득 차 있는 상태를 유지하였다. 이 연구의 주된 목적은 midloop 운전중 RHR 기능 상실사고에 대한 위와같은 상태에서 계통의 열수력적 현상을 실험을 통해 이해하고 코드 예측능력을 평가하는 것이다. CATHARE2 코드 계산결과 대체적으로 실험의 현상을 잘 모의하고 있으나 다음 사항에 대해서는 차이를 보이고 있다. 첫째 노심내 물의 혼합을 적절히 모의하지 못하여, 노심내 국부적 증기 발생 시점이 실험에 비해 약 250초 빨리 나타났다. 둘째 노심에서 고온관으로의 물의 유입이 많아 고온관에서 기포율이 실험에 비해 낮게 나타났다. 마지막으로 밀림관(surge line)에서 물의 유입에 의한 압력차가 실험보다 높게 나타났다.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.124-132
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• 2016

In order to estimate the effect of flow distributors connected to an upper nozzle of CMT(Core Makeup Tank) on the thermal-hydraulic characteristics in the tank, a simplified 2 inch Small Break Loss of Coolant Accident(SBLOCA) was simulated by skipping the decay power and Passive Residual Heat Removal System(PRHRS) actuation. The CMT is a part of safety injection systems in the SMART (System Integrated Modular Advanced Reactor). Each test was performed with reliable boundary conditions. It means that the pressure distribution is provided with repeatable and reproducible behavior during SBLOCA simulations. The maximum flow rates were achieved at around 350 seconds after the initial opening of the isolation valve installed in CMT. After a short period of decreased flow rate, it attained a steady injection flow rate after about 1,250 seconds. This unstable injection period of the CMT coolant is due to the condensation of steam injected into the upper part of CMT. The steady injection flow rate was about 8.4% higher with B-type distributor than that with A-type distributor. The gravity injection during hot condition tests were in good agreement with that during cold condition tests except for the early stages.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.174-174
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• 2015

국내의 국지성 집중호우와 같은 기후변화와 토지피복율 증가 등 복합적인 원인으로 인한 표면 유출수의 증가로 도시에서의 내수침수가 매년 빈번하게 발생하고 있다. 이러한 도심지 돌발홍수로 인한 피해에 대한 구조적인 대책으로 지하방수로가 효과적인 방안으로 대두되고 있으며, 현재 신월빗물저류배수시설이 설계단계에 있다. 그러나 미국, 일본 등의 국외의 기설치된 지하방수로에서 발생되는 Geyser 현상으로 인한 피해에 대한 연구는 국외에 비해 미비한 편이므로, 선행적으로 Geyser에 대한 물리기반의 동수역학적인 이해가 필요한 실정이다. Geyser는 홍수 시 급격한 유량의 유입으로 단파가 발생하여 지하방수로 내 공기의 압축이 발생하고 수직관을 통해 공기가 물과 함께 지상으로 분출되면서 발생된다. 따라서 공기와 물의 혼합 유동을 모의해야 하며 동시에 단파의 불연속성을 모의하기 위해서는 기존의 상용프로그램으로는 다소 어려움이 있다. 이에 본 연구에서는 지하방수로의 Geyser 현상의 발생 예측을 위해 1차원 Saint-Venant 방정식을 지배방정식으로 선정하였으며, 단파 발생을 수치적으로 안정적으로 모의하기 위해 Roe Approximate Riemann 수치기법을 사용하였다. 또한 공기의 압력항을 고려하기 위해서 수정된 형태의 Preissmann slot 모형을 적용하였다. Geyser 현상의 영향인자로서 지하방수로 수평관의 직경, 마찰계수, 바닥경사, 초기수위, 유입유량을 고려하였으며 상류에서 유입되는 유량에 의한 하류에서의 동수역학적 거동을 분석하였다. 5개의 영향인자의 변화에 따른 단파의 유입속도 및 공기부 압력의 변화를 관찰하여 Geyser 현상에 대한 동수역학적 검토를 수행하였다. 추후 본 연구결과를 적절히 활용한다면 지하방수로의 사용 안정성을 확보하고, 홍수발생 시 모니터링 인자도출에 도움이 될 것으로 예상된다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.3403-3409
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• 2014

Hot-firing tests were carried out using a mixing head with 19 swirl coaxial injectors and a combustion chamber with internal cooling channels. The propellants of liquid oxygen and kerosene(Jet A-1) were burned in a range of chamber pressures (59~82 bar) and mixture ratios (2.0~3.0). The temperature of water used as the cooling fluid was measured at the inlet and outlet of the cooling channels, and the heat flux was calculated. The aim of this study was to examine the effect of combustion instability on heat transfer in a subscale thrust chamber, and detect the temperature variation of cooling water. During several hot-firing tests, combustion instability was encountered which caused a 5~20% increase in heat flux. The peak heat flux took place in the initial stages of combustion instability.

• The Journal of the Petrological Society of Korea
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• v.7 no.2
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• pp.77-97
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• 1998

We analyzed geochemical and radiogenic isotope data to investigate the genesis and source characteristics of the Onjeongri granite in the northern part of the Gyeongsang Basin. Field observation and K-Ar ages confirm late Cretaceous intrusion (ca. 87 Ma) of the Onjeongri granite. The hornblende geobarometery gives less than 2 kbar for the emplacement pressure of the Onjeongri granite. Geochemical and isotopic compositions suggest that the Onjeongri granite was formed in a relatively immature arc system. $SiO_2$ contents show a negative linear relationship with initial $^{87}Sr/^{86}Sr$ ratios, and an apparent positive correlation with $^{207}Pb/^{204}Pb$ ratios, suggesting an incomplete mixing or assimilation. However, the isotopic data known for any exposed rocks of the study area do not fit as an endmember, implying that the contaminant might reside in the lower crust. A review of published isotopic ages, geochemical, and Sr and Nd isotopic data for the Cretaceous to Tertiary granites in the Gyeongsang Basin indicates the followings. 1) Granitic magmatism in the Gyeongsang Basin were episodic. 2) Granitic rocks in the basin were derived from young (< 0.9 Ga) lower crust, and their isotopic signatures reflect heterogeneous source region. Geochemical and isotopic signatures of granitic rocks in the basin are difficult to explain by upper crustal contamination. 3) Granites in the Gyeongsang Basin have closely related to those in the San in Belt of the Inner Zone of Southwest Japan in terms of age, petrography, and isotopic and geochemical composition. 4) Sr-Nd isotopic signatures of the Onjeongri granite are relatively primitive compared with granitic rocks in the other parts of the Gyeongsang Basin and in the Inner Zone of Southwest Japan.

• Geotechnical Engineering
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• v.12 no.5
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• pp.17-26
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• 1996

The undrained behavior of Asan marine soil was investigated by using an automated triaxial testing device. The stress-strain behavior at the preand postfailure state of marine soil under undrained compression and eatension conditions was compared with the behavior of pure silt, pure clay and the overall behavior of Asan marine soil was predicted with the modified Camflay model and the bounding surface model. The marine soil sampled in Asan bay area was clayey silts with 70oA silt-30% clay content and the testing samples were prepared in both undisturbed and remolded conditions. All samples are normally consolidated with 400 kPa of effective mean confining pressure and each sample is unloaded to 200, 100, 67 kPa, respectively. And then the shear test was performed with different confining pressure. According to experimental results, there exists an unique failure line whose slope is lower than silt's and higher than clay's. It is identified that the undrained shear strength of normally consolidated samples increases after crossing the phase transformation line because of volume dilation tendency which is not seen in clay. Overconsolidated samples show different soil behavior compared with pure silt due to its tendency of change in volume. It is also found that the overall behavior of Asan marine soil cannot be predicted precisely with the modified Cam-clay model and the bounding surface model.

• Economic and Environmental Geology
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• v.35 no.5
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• pp.379-393
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• 2002

Within the Boseong-Jangheung area of Korea, five hydrothermal gold (-silver) quartz vein deposits occur. They have the characteristic features as follows: the relatively gold-rich nature of e1ectrurns; the absence of Ag-Sb( -As) sulfosalt mineral; the massive and simple mineralogy of veins. They suggest that gold mineralization in this area is correlated with late Jurassic to Early Cretaceous, mesothermal-type gold deposits in Korea. Fluid inclusion data show that fluid inclusions in stage I quartz of the mine area homogenize over a wide temperature range of 200$^{\circ}$ to 460$^{\circ}$C with salinities of 0.0 to 13.8 equiv. wt. % NaCI. The homogenization temperature of fluid inclusions in stage II calcite of the mine area ranges from 150$^{\circ}$ to 254$^{\circ}$C with salinities of 1.2 to 7.9 equiv. wt. % NaCI. This indicates a cooling of the hydrothermal fluid with time towards the waning of hydrothermal activity. Evidence of fluid boiling including CO2 effervescence indicates that pressures during entrapment of auriferous fluids in this area range up to 770 bars. Calculated sulfur isotope composition of auriferous fluids in this mine area (${\delta}^34S$_{{\Sigma}S}$$\textperthousand$) indicates an igneous source of sulfur in auriferous hydrothermal fluids. Within the Sobaegsan Massif, two representative mesothermal-type gold mine areas (Youngdong and Boseong-Jangheung areas) occur. The ${\delta}^34S values of sulfide minerals from Youngdong area range from -6.6 to 2.3$\textperthousand$ (average=-1.4$\textperthousand$, N=66), and those from BoseongJangheung area range from -0.7 to 3.6$\textperthousand$ (average=1.6$\textperthousand$, N=39). These i)34S values of both areas are comparatively lower than those of most Korean metallic ore deposits (3 to 7TEX>$\textperthousand$). And, within the Sobaegsan Massif, the ${\delta}^34S values of Youngdong area are lower than those of Boseong-Jangheung area. It is inferred that the difference of ${\delta}^34S values within the Sobaegsan Massif can be caused by either of the following mechanisms: (1) the presence of at least two distinct reservoirs (both igneous, with ${\delta}^34S values of < -6 $\textperthousand$ and 2$\pm$2 %0) for Jurassic mesothermal-type gold deposits in both areas; (2) different degrees of the mixing (assimilation) of 32S-enriched sulfur (possibly sulfur in Precambrian pelitic basement rocks) during the generation and/or subsequent ascent of magma; and/or (3) different degrees of the oxidation of an H2S-rich, magmatically derived sulfur source ${\delta}^34S = 2$\pm$2$\textperthousand$) during the ascent to mineralization sites. According to the observed differences in ore mineralogy (especially, iron-bearing ore minerals) and fluid inclusions of quartz from the mesothermal-type deposits in both areas, we conclude that pyrrhotite-rich, mesothermal-type deposits in the Youngdong area formed from higher temperatures and more reducing fluids than did pyrite(-arsenopyrite)-rich mesothermal-type deposits in the Boseong-Jangheung area. Therefore, we prefer the third mechanism than others because the ${\delta}^34S values of the Precambrian gneisses and Paleozoic sedimentary rocks occurring in both areas were not known to the present. In future, in order to elucidate the provenance of ore sulfur more systematically, we need to determine ${\delta}^34S values of the Precambrian metamorphic rocks and Paleozoic sedimentary rocks consisting the basement of the Korean Peninsula including the Sobaegsan Massif.