• Title/Summary/Keyword: 혼성성

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Crystal Chemistry and Fine-scale Paragenesis of Chuncheon Nephrite (춘천 연옥의 결정화학과 미시적 공생관계에 관한 연구)

  • 노진환;최진범
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.2
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    • pp.96-114
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    • 2000
  • 춘천 연옥은 색깔에 따라 세가지 유형 (연녹색, 암녹색, 및 회색 연옥)으로 구분되고 이들은 각기 서로 다른 조직과 조성을 나타낸다. 연녹색 연옥이 이중에서 가장 일반적인 유형이다. 연옥은 주로 극미립의 연옥질 투각섬석으로 구성되고 여기에 미량의 휘석, Mg-녹니석 및 방해석이 불순물로서 수반된다. 연옥질 투각섬석 결정들은 그 폭이 5$\mu\textrm{m}$ 이하의 극미립질 침상 결정형을 이루며 서로 치밀하게 얽혀있는 연옥 특유의 조직을 나타낸다. 주사전자현미경 하에서 (110)의 벽개면의 발달이 현저하고, 주사탐침현미경 하에서는 벽개면을 가로지르는 방향으로 특징적인 조선이 나타나는 것이 특징이다. 연옥질 투각섬석은 투과전자현미경 하에서 흔히 단쇄형과 복쇄형이 결합한 3중쇄형 격자가 복쇄형의 투각섬석 구조 내에서 불규칙적으로 협재되는 혼성격자 구조가 발달하는 것이 특징이다. 드물지만 5중쇄형 격자와 4중쇄형 격자도 관찰되는데, 이 같은 불규칙한 격자 혼재상은 회색 연옥에서 보다 현저한 경향을 보인다. 이와 같은 혼성격자 구조형의 존재는 춘천 연옥이 열역학적으로 비평형 상태에서 형성되었음을 시사하는 것으로 여겨진다. 리트벨트법에 의한 구조검증을 통해서 구해진 연옥질 투각섬석들의 격자상수 값들은 X-선회절의 경우, a=9.837(1)~9.9804(4)$\AA$, b=18.046(2)~18.062(1)$\AA$. c=5.2765(7)~5.2803(3)$\AA$, $\beta$=104.717(9)~104.786(3)$^{\circ}$로 계산되었다. 이에 비해서 중성자 회절법에 의해서 측정되 격자 상수 값은 a=9.8841(6)~9.8933(7)$\AA$, b=18.1429(7)~18.161(2)$\AA$, c=5.3024(3)~5.3060(7)$\AA$, $\beta$=104.698(7)~104.771(4)$^{\circ}$로서 X-선회절에 의한 값들과 약간의 차이를 보인다. 연옥질 투각섬석은 Ca에 대한 Mg의 치환에 의해 M(4) 자라의 크기가 작아지면서 b축의 단위포도 함께 줄어드는 결정화학적 특징을 나타낸다. 이는 중성자 회절분석에 의해서 구해진 M(4)의 자리점유율과 M(4)-O의 원자간 거리에 의해서도 확인된다. 그러나 연옥질 투각섬석에 대한 리트벨트법에 구조검증 결과는 연옥의 유형별 미시적 광물상과 혼성격자 구조형의 특징에 별다른 연계성이 없는 것으로 나타났다.

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Parametric Characterization of Zinc Oxide Nanostructures Forming Three-Dimensional Hybrid Nanoarchitectures on Carbon Nanotube Constructs (산화아연 나노구조의 탄소나노튜브와의 혼성구조 형성 특성 연구)

  • Ok, Jong G.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.541-548
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    • 2015
  • We study the structural and functional characteristics of zinc oxide (ZnO) nanostructures that are grown on carbon nanotube (CNT) constructs via step-wise chemical vapor deposition (CVD). First, we optimize the CVD process to directly grow ZnO nanostructures on CNTs by controlling the growth temperature below $600^{\circ}C$, where CNTs can be sustained in a ZnO-growing oxidative atmosphere. We then investigate how the morphology and areal density of ZnO nanostructures evolve depending on process parameters, such as pressure, temperature, and gas feeding composition, while focusing on the effect of underlying CNT topology on ZnO nucleation and growth. Because various types of ZnO nanostructures, including nanowires, nanorods, nanoplates, and polycrystalline nanocrystals, can be conformally formed on highly conductive CNT platforms, this electrically addressable three-dimensional hybrid nanoarchitecture may better meet a wide range of nanoelectronic application-specific needs.

Synthesis and Characterization of Poly(Urethane-Methyl methacrylate) Hybrid Emulsion as a Plastic Coating Resin (플라스틱 코팅용 Poly(Urethane-MMA) 혼성 에멀젼 합성 및 특성 연구)

  • Yeom, Ji-Yoon;Baek, Kyung-Hyun;Lee, Jun-Young;Yi, Gyoung-Bae;Yoo, Byung-Won;Kim, Jung-Hyun
    • Journal of Adhesion and Interface
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    • v.8 no.1
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    • pp.8-14
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    • 2007
  • Poly(urethane-methyl methacrylate) hybrid emulsions can be controlled with their thermal, mechanical and anti-chemical properties as plastic coating materials. In this study, water dispersed poly(urethane-methyl methacrylate) hybrid emulsions were prepared by prepolymer synthesis and soap free emulsion polymerization. For imparting hydrophilicity on polyurethane prepolymer, 2,2-bis (hydroxymethyl) propionic acid was added to the polyurethane prepolymer with methyl methacrylate monomer and was neutralizated by triethylamine (TEA). After neutralization, the prepolymer mixture was dispersed in the water phase with stable droplets. The synthesis was carried out with chain extension from the ethylene diamine and initiation of methyl methacrylate by soap free emulsion polymerization. Stable poly(urethane-methyl methacrylate) hybrid emulsion was successfully obtained with different synthetic conditions and acrylic monomer contents. Poly(urethane-methyl methacrylate) hybrid emulsion were characterized and compared with tensile strength, viscosity, and adhesion properties.

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Liquid Crystal Polymers (X). Synthesis and Properties of New Thermotropic Main Chain Copolyesters with Either Mixed Polymethylene Spacers or Mixed Mesogenic Units (액정 중합체 (제10보). 혼합폴리에틸렌 격자나 메소젠 단위를 갖고 있는 새로운 주사슬 혼성폴리에스테르의 합성 및 성질)

  • Jung-Il Jin;Robert W. Lenz;S. Antoun
    • Journal of the Korean Chemical Society
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    • v.26 no.3
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    • pp.188-193
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    • 1982
  • Four new thermotropic copolyesters were prepared and their liquid crystal properties were investigated by differential scanning calorimetry and on a hot-stage of a polarizing microscope. Three copolyesters had same mesogenic unit, triad aromatic ester structure, interconnected through a random combination of either odd-even, or odd-odd, or even-even number of methylene groups in the polymethylene flexible spacers. Another random copolyester consisted of mesogenic units of 1 : 1 mixture of central methyl-and bromohydroquinone moieties with two flanking p-oxybenzoate units connected by decamethylene spacer. All of the polyesters formed nematic liquid crystal phase upon melting. The transitions for melting and nematic ${\to}$ isotropic transformations could be reversibly observed by DSC as well as by microscopic study. The thermodynamic properties for their liquid crystal ${\to}$ isotropic phase transitions were discussed in relation to their chemical structures.

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Treatment of the cleft lip and palate patient with few remaining posterior teeth using hybrid telescopic crown denture (치주질환에 이환된 소수 잔존치를 가지는 구순구개열 환자에서의 상악 혼성 이중관 의치를 이용한 수복증례)

  • Park, Jin-Wook;Cho, Jin-Hyun
    • Journal of Dental Rehabilitation and Applied Science
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    • v.33 no.4
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    • pp.284-290
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    • 2017
  • For individuals with cleft lip and palate, the removable partial dentures (RPDs) have been an important treatment option. Some modifications from conventional prosthetic treatment may be necessary to achieve satisfactory functional and esthetic results in cleft patients. In case of cleft palate patient with periodontally compromised and only posterior few remaining teeth, removable partial prosthesis connected to telescopic crown can be the alternative treatment option. When connected to the RPD, telescopic crowns increase the prosthetic stability and retention, optimize favorable force transmission to the long dental axis, and improve esthetics. And the cross arch stabilization of double crown denture helps to stabilize both divided maxillary ridges in CLP patient. This case present one adult CLP patient using an RPD connected with hybrid telescopic crowns with friction pins to improve not only retention and stability but also aesthetics.

An Intermediate Moisture Food from a Composite Meat of Squid and Pork (혼성육(混成肉)을 원료(原料)로 한 중간수분식품(中間水分食品)의 시제(試製))

  • Jo, J.S.;Kwon, T.W.
    • Korean Journal of Food Science and Technology
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    • v.4 no.4
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    • pp.265-270
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    • 1972
  • An attempt was made in this study to investigate the possibility of processing squid along with pork into an intermediate moisture food, as an acceptable new item in Korea. To obtain a palatable and low cost product, portions of mixture consisting of equal amounts of ground squid and pork were cooked in soy sauce for 20 min, soaked in glycerol for 20 min at $80^{\circ}C$, and then air dried for 90 min at $60^{\circ}C$. During storage for 42 days in saturated humidity incubator at $37^{\circ}C$, the total microbial counts of the products packaged in polyethylene (0.05 mm), polypropylene (0.05 mm) and plastic laminated aluminum foil were decreased from 230 per gram to 40, 20 and 10 per gram respectively. In another long range storage test of 6 months, the results paralleled the above trends. Even though the TBA value of the samples increased during the storage, it was not so serious as to damage on the organoleptic quality of this product. The results indicate that stored product was as acceptable as the freshly prepared one.

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Determination of cross section of composite breakwaters with multiple failure modes and system reliability analysis (다중 파괴모드에 의한 혼성제 케이슨의 단면 산정 및 제체에 대한 시스템 신뢰성 해석)

  • Lee, Cheol-Eung;Kim, Sang-Ug;Park, Dong-Heon
    • Journal of Korea Water Resources Association
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    • v.51 no.9
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    • pp.827-837
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    • 2018
  • The stabilities of sliding and overturning of caisson and bearing capacity of mound against eccentric and inclined loads, which possibly happen to a composite caisson breakwaters, have been analyzed by using the technique of multiple failure modes. In deterministic approach, mathematical functions have been first derived from the ultimate limit state equations. Using those functions, the minimum cross section of caisson can straightforwardly be evaluated. By taking a look into some various deterministic analyses, it has been found that the conflict between failure modes can be occurred, such that the stability of bearing capacity of mound decreased as the stability of sliding increased. Therefore, the multiple failure modes for the composite caisson breakwaters should be taken into account simultaneously even in the process of deterministically evaluating the design cross section of caisson. Meanwhile, the reliability analyses on multiple failure modes have been implemented to the cross section determined by the sliding failure mode. It has been shown that the system failure probabilities of the composite breakwater are very behaved differently according to the variation of incident waves. The failure probabilities of system tend also to increase as the crest freeboards of caisson are heightening. The similar behaviors are taken place in cases that the water depths above mound are deepening. Finally, the results of the first-order modal are quite coincided with those of the second-order modal in all conditions of numerical tests performed in this paper. However, the second-order modal have had higher accuracy than the first-order modal. This is mainly due to that some correlations between failure modes can be properly incorporated in the second-order modal. Nevertheless, the first-order modal can also be easily used only when one of failure probabilities among multiple failure modes is extremely larger than others.