• Title/Summary/Keyword: 형광스펙트럼

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Fabrication and Characteristics of High Brightness White Emission Electroluminescent Device (고휘도 백색방출 전계발광소자의 제작 및 특성)

  • Bae, Seung-Choon;Kim, Jeong-Hwan;Park, Sung-Kun;Kwun, Sung-Yul;Kim, Woo-Hyun;Kim, Ki-Wan
    • Journal of Sensor Science and Technology
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    • v.8 no.1
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    • pp.10-15
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    • 1999
  • White emission thin film electroluminescent device was fabricated using ZnS for phosphor layer and BST ferroelectric thin film for insulating layer. For fabrication conditions of BST thin film, stoichiometry of target was $Ba_{0.5}Sr_{0.5}TiO_3$, substrate temperature was $400^{\circ}C$, working pressure was 30 mTorr, and A:$O_2$ ratio was 9:1. At this time, dielectric constant was 209 at 1kHz frequency. For phosphor layer ZnS:Mn, ZnS:Tb, and ZnS:Ag were used. Mixing rates of activators were respectively 0.8, 0.8, and 1 wt%. Total thickness of phosphor tapers was 500 nm, thickness of lower insulating layer was 200 nm, and thickness of upper insulating layer was 400 nm. In this conditions, luminescence threshold voltage of thin film electroluminescent device was $95\;V_{rms}$, maximum brightness was $3,000\;cd/m^2$ at $150\;V_{rms}$. Luminescence spectrum peak was observed at region of blue(450 nm), green(550 nm), and red(600 nm).

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Variations of imaging depth and chloroplast emission spectrum of Arabidopsis thaliana with excitation wavelength in two-photon microscopy (이광자현미경 여기 광 파장에 따른 Arabidopsis thaliana 촬영 깊이 및 엽록체 형광 스펙트럼의 변화)

  • Joo, Yongjoon;Son, Si Hyung;Kim, Ki Hean
    • Journal of the Korean Society of Visualization
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    • v.12 no.3
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    • pp.9-14
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    • 2014
  • Two-photon microscopy (TPM) has been used in plant research as a high-resolution high-depth 3D imaging modality. However, TPM is known to induce photo-damage to the plant in case of long time exposure, and optimal excitation wavelength for plant imaging has not been investigated. Longer excitation wavelength may be appropriate for in vivo two-photon imaging of Arabidopsis thaliana leaves, and effects of longer excitation wavelength were investigated in terms of imaging depth, emission spectrum. Changes of emission spectrum as a function of exposure time at longer excitation wavelength were measured for in vivo longitudinal imaging. Imaging depth was not changed much probably because photon scattering at the cell wall was a limiting factor. Chloroplast emission spectrum showed its intensity peak shift by 20 nm with transition of excitation wavelength from 849 nm or below to 850 nm or higher. Emission spectrum showed different change patterns with excitation wavelengths in longitudinal imaging. Longer excitation wavelengths appeared to interact with chloroplasts differently in comparison with 780 nm excitation wavelength, and may be good for in vivo imaging.

혼합된 호스트 발광층을 가진 청색 유기 발광 소자의 발광효율 향상

  • Jo, Jin-Taek;Kim, Dae-Hun;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.499-499
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    • 2013
  • 유기 발광 소자는 낮은 구동전압, 낮은 소비전력, 높은 명암비, 넓은 시야각 및 빠른 응답속도의 장점을 가지고 있기 때문에 전색 디스플레이에서 각광을 받고 있다. 고효율의 청색 유기 발광 소자를 제작하기 위해서 다양한 구조를 제작하고 있지만, 적색 및 녹색 유기 발광 소자에 비해 낮은 효율, 색 순도의 저하 및 짧은 수명으로 인한 문제점을 갖고 있기 때문에 이를 해결하기 위한 연구가 필요하다. 본 연구에서는 발광층내에 호스트 물질로 1.3-Bis(carbazol-9-yl) benzene (mCP)와 2-t-butyl-9,10-di-2-naphthylanthracene (TBADN)을 혼합하였고, 형광 도펀트인 4,40-Bis[4-(diphenylamino)styryl]biphenyl (BDAVBi) 또는 인광 도펀트인 bis(3,5-difluoro-2-(2-pyridyl) phenyl-(2-carboxypyridyl)iridium III (FIrpic)을 혼합한 발광층을 사용한 유기 발광 소자를 제작하여 전기적인 특성과 발광 효율을 관찰하였다. 유기 발광 소자의 정공 수송층 N,N,'-bis-(1-naphthyl)-N,N'-diphenyl1-1'-biphenyl-4,4'-diamine (NPB)와 정공 저지층 3-Benzidino-6-(4-chlorophenyl) pyridazine (BCP) 사이에 호스트 mCP와 도펀트 TBADN:BDAVBi를 혼합한 발광층의 혼합비율을 최적화 할 때 구동전압이 낮고, 발광효율이 증가됨을 확인하였다. 호스트 mCP에 도펀트를 혼합한 발광층에서는 호스트로 mCP 또는 TBADN만 사용하였을 때보다 전계발광 스펙트럼의 최대치가 청색 영역에서 나타남을 확인하였다. Commission Internationale de l'Eclairage (CIE) 측정을 통해, 호스트 mCP와 도펀트 TBADN : BDAVBi의 최적화된 혼합비에서 전압의 변동에 따른 CIE 값이 매우 안정적임을 확인하였다.

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2 파장 백색 OLED의 형광층 두께와 발광 특성

  • Jang, Ji-Geun;An, Jong-Myeong;Sin, Sang-Bae;Jang, Ho-Jeong;Ryu, Sang-Uk
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2007.06a
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    • pp.34-38
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    • 2007
  • 청, 황 2-파장 발광층의 구성에서 청색층으로 GDI602를, 황색층으로 GD1602:Rubrene(10%)를 사용하여 2-파장 백색 유기발광다이오드(WOLED)를 제작하고 이들의 특성을 분석하였다. 실험에서는 GDI602:Rubrene (10%)-황색층의 두께를 $220\{AA}$으로 일정하게 두고, GDI602-청색층의 두께를 달리하여 소자들을 제작하였다. 제작된 소자들의 발광 스펙트럼 특성으로는 GDI602 층의 두께에 따라 중심파장의 위치는 거의 일정하나 2-파장 사이의 상대적 세기가 변화되었으며, GDI602 층의 두께가 얇아질수록 황색파장의 상대적 세기가 강해지는 것을 볼 수 있었다. GDI602 층이 $60{\AA}$인 소자는 11V, $70{\AA}$인 소자는 9V, $80{\AA}$인 소자는 8V, $90{\AA}$인 소자는 7V 에서 순수 백색광(x=0.33, y=0.33)에 가까운 발광 특성을 나타내었다. 또한 GDI602 층의 두께에 따른 효율과 휘도는 백색발광 조건에서 각각 0.51m/W와 $3650cd/m^2(60{\AA})$, 0.61m/W와 $1050cd/m^2(70{\AA})$, 0.91m/W와 $490cd/m^2(80){\AA}$, 1.61m/W와 $250cd/m^2(90){\AA}$을 나타내었다.

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Preparation and Characterization of Zinc Oxide Prepared by Spray Pyrolysis Method (열분무법으로 제조된 산화아연의 제법과 확인(I))

  • Jin, Eui;Kim, Young Soon
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.638-645
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    • 1998
  • By using the spray pyrolysis method, zinc oxide(ZnO) was produced from zinc acetate, the surface morphology of the prepared films was investigated by using scanning electron microscopy. The thickness of ZnO thin film was increased up to 460$^{\circ}C$ and it was 833 nm. The maximum wavelength of absorption was obtained at 365 nm, and the maximum peak of fluorescence at 475 nm and 505 nm. ZnO film have been characterized by XPS, XRD, and SEM. XRD results show that all the films are preferred orientation along the (002) plane which is depend on the substrate temperature. The optimal temperature to produce ZnO was determined at around 460$^{\circ}C$ from measurements of XPS, XRD and photocurrent. It was also shown that the homogeneous particles had the higher photocurrent.

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Characteristics of Er-Doped Fiber Laser on Resonator Reflectivities and Pump Power (공진기 반사율과 펌프 파워에 따른 어븀 광섬유 레이저의 특성)

  • 박서연;이학규;김경헌;이동한
    • Korean Journal of Optics and Photonics
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    • v.5 no.2
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    • pp.286-290
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    • 1994
  • Lasing characteristics of an Er-doped fiber laser have been investigated at various conditions of resonator reflectivities and pump powers. Variation of the laser wavelength with various mirror reflectivities has been compared with the theoretical analysis based on absorption, gain spectra, and resonator parameters. The maximum slope efficiency of 38% was obtained with the resonator's mirror reflectivities of 100% and 4% on both sides, and the threshold powers were varied from 7.8 mW to 5.6 mW, and lasing wavelengths were varied $1.532\mum to 1.563\mum and 1.558 \mum to 1.570 \mum$ for 6 and 15.8 mlong Er-doped fiber, respectively, as the resonator reflectivities were changed from 0.0016 to 0.9.to 0.9.

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Excited State Absorption and Nonradiative Transition from the Lowest 5d State of $Ce^{3+}:YAlO_3$ ($Ce^{3+}:YAlO_3$ 단결정의 5d 상태 흡수 및 비발광 천이)

  • 김지병;임기수;이건준;김동호;한재민
    • Korean Journal of Optics and Photonics
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    • v.6 no.1
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    • pp.33-38
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    • 1995
  • We have measured the excited state absorption in $Ce:YAlO_{3}$, crystals for the first time and assigned it for a 5d$\rightarrow$conduction band transition. Two broad absorption bands were observed at 555 nm and 465 nm fowllowing the 308 nm XeCl laser excitation and their cross sections and oscillator strengths were calculated. We have also measured the fluorescence lifetimes in between 300 K and 700 K to study the nonradiative relaxation from the lowest 5d state of $Ce^{3+}$ ions and explained ESA and the transition process from the state in terms of a configurational coordinate.dinate.

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The Effect of Color Reproduction Properties at TFT-LCD Using High Color Reproduction CCFL (고색재현성 CCFL을 사용한 LCD에서의 색재현성 개선에 관한 평가)

  • Han, Jeong-Min;Bae, Kyung-Woon;Kim, Yun-Ho;Lim, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.165-168
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    • 2003
  • 최근 TV 대응 LCD 제품의 본격적인 양산과 더불어 LCD TV 의 색재현성에 대한 해결과제가 큰 문제로 대두되고 있으며, CRT 급 색재현성의 확보는 LCD TV 의 고급화를 위한 또 하나의 개발 방향이 되고 있다. 그러나, CF(Color Filter)만을 이용한 색재현성의 개선은 근본적으로 한계를 가지고 있으며, 패널 투과율의 저하로 이어져 또다시 고휘도 사양의 BL(Back Light)에 대한 요구가 발생하고 있다. 따라서 본 연구에서는 CF(Color Filter)만에 의한 색재현성의 개선이 아닌 BL 광원 자체의 스펙트럼 최적화를 통해서 CRT 급 색재현성의 확보를 통한 고부가가치 상품개발의 가능성을 제시하고자 하였다. 구체적으로, 램프형광체의 RED 와 Green-Blue 영역에서의 Intensity 향상을 통해서 기존의 CCFL(Cold Cathode Fluorescent Lamp)과는 다른 특성을 광원에 부가하여, 기본의 LCD 패널을 그대로 이용한 경우에도 색재현성을 약 11% 개선하였다.

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Photochemical Changes of Malonaldehyde by the Presence of Aflatoxins in Model Systems (Aflatoxin 존재하에서의 수용액중 Malonadehyde 의 광화학적 변화)

  • Kwon,, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.1 no.1
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    • pp.45-50
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    • 1969
  • On the basis of UV spectral changes and TBA reaction, malonaldehyde (MA) in aqueous solution receives considerable photochemical modification by UV light of short wavelengths around $260m{\mu}$. When aflatoxin is added in the solution, UV light of long wavelengths around $360m{\mu}$ induces such changes quite rapidly and although the rate of change is rather slow, it is also true even with ordinary laboratory illumination(fluorescent). The modification is irreversible in nature and the role of aflatoxin in this reaction is identified as a photosensitizer. The mechanism involved in this modification is apparently due to the parallel dimerization of MA molecules, but not by head to tail combination of the molecules.

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Adaptive Marquardt Algorithm based on Mobile environment (모바일 환경에 적합한 적응형 마쿼트 알고리즘 제시)

  • Lee, Jongsu;Hwang, Eunhan;Song, Sangseob
    • Smart Media Journal
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    • v.3 no.2
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    • pp.9-13
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    • 2014
  • The Levenberg-Marquardt (LM) algorithm is the most widely used fitting algorithm. It outperforms simple gradient descent and other conjugate gradient methods in a wide variety of problems. Based on the work of paper[1], we propose a modified Levenberg-Marquardt algorithm for better performance of mobile system. The LM parameter at the $k_{th}$ iteration is chosen ${\mu}=A{\bullet}{\parallel}f(x){\parallel}{\bullet}I$ where f is the residual function, and J is the Jacobi of f. In this paper, we show this method is more efficient than traditional method under the situation that the system iteration is limited.