• Title/Summary/Keyword: 헤테로 다중산

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Simple Heteropoly Acids as Water-Tolerant Catalysts in the Oxidation of Alcohols with 34% Hydrogen Peroxide, A Mechanistic Approach (34% 과산화 수소와 함께 알코올의 산화에서 수분-관용적인 촉매로서의 간단한 헤테로 다중산)

  • Tayebee, Reza
    • Journal of the Korean Chemical Society
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    • v.52 no.1
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    • pp.23-29
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    • 2008
  • Simple Keggin type tungsten and molybdenum heteropoly acids, H3PW12O40 and H3PMo12O40, were usedas water-tolerant catalysts for the oxidation of alcohols with 34% hydrogen peroxide in normal drinking water. Accordingto our findings, H3PW12O40 may be used as a simple, effective, and cheap catalyst for this type of transformation in nor-mal drinking water with excelent yields. Efects of diferent solvents at 25-80oC and changing concentration of catalystand substrate on the reaction progress were also studied.