• 청정기술
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• 제19권1호
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• pp.13-21
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• 2013

다른 분율의 Cs이 포함된 Pt/$Cs_xH_{3-x}PW_{12}O_{40}$ 촉매를 제조하여 셀룰로우스의 폴리올로의 수소화분해반응를 수행하였다. 촉매의 비표면적과 Pt의 분산도는 Pt/$Cs_xH_{3-x}PW_{12}O_{40}$ 촉매의 Cs 함량이 증가함에 따라 증가하였다. 그러나 Pt/$Cs_xH_{3-x}PW_{12}O_{40}$ 촉매의 Cs의 함량이 변함에도 불구하고 비슷한 폴리올 수득률을 보였다. Pt/$Cs_xH_{3-x}PW_{12}O_{40}$ 촉매의 반응 활성은 Ni/W/SBA-15와 두 가지의 복합촉매(Pt/AC+$H_3PW_{12}O_{40}$과 Pt/AC+$Cs_{3.0}PW_{12}O_{40}$)와 비슷하였다. 이 반응을 진행하는 동안 Pt/$Cs_xH_{3-x}PW_{12}O_{40}$ 촉매로부터 헤테로폴리 음이온이 침출되는 것을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제22권1호
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• pp.1-12
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• 2011

To improve the mechanical properties, such as durabilities and antioxidative characteristics, the covalently cross-linked (CL-) SPEEK (sulfonated polyether ether ketone)/Cs-substituted HPA (heteropoly acid) organic-inorganic composite membranes (CL-SPEEK/Cs-HPAs), have been intensively investigated. The composite membrane were prepared by blending cesium-substituted HPAs (Cs-HPAs), including tungstophosphoric acid (TPA), molybdophosphoric acid (MoPA), and tungstosilicic acid (TSiA) with cross-linking agent content of 0.01 mL. And composite electrolytes composed of Cs-HPAs, prepared by immersion (imm.) and titration (titr.) methods to increase the stability of HPAs in water, were applied to polymer electrolyte membrane electrolysis (PEME). As a result, the proton conductivity of Cs-substituted composite membranes increased rapidly over $60^{\circ}C$ but mechanical properties, such as tensile strength, decreased in accordance with added Cs content. The bleeding-out of Cs-TPA membranes by titration method (50 vol.% Cs) decreased steadily to 2.15%. In the oxidative stability test by Fenton solution, the durability of membranes with Cs-HPA significantly increased. In case of CL-SPEEK/ Cs-TPA membrane, duration time increased more than 1200 hours. It is expected that even though CL-SPEEK/Cs-MoPA membrane shows the high proton conductivity, electrocatalytic activity and cell voltage of 1.80 V for water electrolysis, the CL-SPEEK/Cs-TPA (imm.) is more suitable as an alternative membrane in real system with the satisfactory proton conductivity, mechanical properties, anti-oxidative stability and cell voltage of 1.89 V.