• 전기의세계
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• v.28 no.8
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• pp.25-28
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• 1979

일반석유제품에 비해 특이한 사용목적및 특성을 갖는 전기절연유는 유입전기기의 절연및 냉각용으로 장기간에 걸쳐 사용되어 왔다. 최근에 이르러서는 전기기기의 고전압화, 대용량화 추세에 따라 절연유에 대한 요구특성도 더욱 가혹하게 되었으며 이 요구특성을 만족시키기 위하여 부단한 연구와 노력이 뒤따라 현시점에서는 특고압및 초고압 전기기기의 수요에도 대응하게 되었다. 한편, 선진외국에서는 광유계 절연유와는 별도로 합성절연유의 개발이 활발히 진행되고 있는 실정이다. 본란에서는 현재 주종을 이루고 있는 광유계 전기절연유가 갖는 특성및 취급상 유의점을 기술하고저한다.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.2
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• pp.162-166
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• 1998

Synthetic fluid, class 7 group 2, as an insulating and cooling material is selected as. specimen, arid it is studied for the physical and electrical properties. Also, Benzotriazole(following as BT A) known as a suppressant of streaming electrification is added to it, and the change of physical and electrical properties by addition of BT A is investigated. From the spectrum of FT-IR, it is confirmed that the absorption peak in wavenumbers $3400{\sim}3450[cm^{-1}]$ is small or disappears when BTA is added. AC breakdown strength and volume resistivity of each specimen are investigated. It is considered that the effective content of BTA is about 10[ppm] for the suppression of electrification in this experiment.

• Applied Chemistry for Engineering
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• v.25 no.3
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• pp.254-261
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• 2014

The transformer is a static electrical device that transfers energy by inductive coupling. Then, heat is occurred at coils, inner transformer was filled with insulating oils for cooling and insulation. Although mineral oil as insulating oil has been widely used, it does not meet health and current environmental laws because it is not biodegradable. Therefore, in this study, the diglycerol ester was synthesized with diglycerol and fatty acids (oleic acid and caprylic acid) over various catalysts for insulating oil having biodegradability, high flash points and low pour points. The sulfated zirconia ($SO_4{^{2-}}/ZrO_2$) catalyst prepared at different calcination temperature shows the highest conversion of fatty acids at $600^{\circ}C$ due to crystallinity and high density of acid sites per surface area. When the molar ratio of oleic acid and caprylic acid is 1:3, the diglycerol ester shows superior insulation properties that are the flash point of $306^{\circ}C$ and pour point of $-50^{\circ}C$. The insulation properties of synthesized diglycerol ester shows the pour point of $-50^{\circ}C$ and the flash point of over $300^{\circ}C$. Therefore, diglycerol ester is superior to the vegetable oils in insulation properties.