• Journal of the Korean Chemical Society
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• v.33 no.6
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• pp.588-595
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• 1989

Log K, ${\Delta}$H and ${\Delta}$S for the complexation of $La^{3+},\;Ce^{3+}$ and $Eu^{3+}$with various multidentate ligand containing crown ether, diaza crown ether and diamine ether have been determined in methanol and acetonitril solutions at $25^{\circ}C$ by solution calorimetric titration method. The greater stability constant of $La^{3+}$-15C5 than those of 18C6 diaza [2.2] in methanol are discussed in terms of the size of metal ion and the ligand cavity and of metal ion solvation. The stabilities of $Ce^{3+}$ and $La^{3+}$ ion complexes with a various multidentate ligand in acetonitril are in the order of (diamine ether)<18C6<15C5$Ce^{3+}$, $La^{3+}$ and $Eu^{3+}$-diaza [2.2] complexes in acetonitril are increased with the following order: $Eu^{3+}$ < $La^{3+}$ < $Ce^{3+}$, that is increasing order of the optimum size and of the charge density of metal ion.

• Communications of Mathematical Education
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• v.29 no.1
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• pp.111-130
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• 2015

The purpose of the study was to investigate the differences between two groups of students according to information recognition styles such as visual learners and linguistic learners. Two instructional methods, algeblocks and factorization formula, were utilized to introduce the factorization. Four students were participated for the study, and two of them were visual learners and the other two were linguistic learners based on learning style test. Interviews and the diagnostic tests were implemented before the instructions which were lasted for 6 sessions. After the instructions all the participants were interviewed and the researchers also interviewed them 5 days later. The results of the study were the followings: 1. All the participants regardless of their learning style revealed that algeblocks were helpful in understanding the factorization. 2. Visual learners were more likely using algeblocks, while the linguistic learners were more enthusiastic and proficient in using formula to solve the problems. 3. Five days later, two types of learning style students revealed different tendencies. Visual learners mainly used algeblocks, and linguistic learners were not enthusiastic about using algeblocks and one of them did not use them at all. 4. Five days later, two visual learners could not remember the formula, but linguistic learners could remember the formula in somewhat different level.

• Journal of Korean Society of Transportation
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• v.21 no.2
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• pp.95-105
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• 2003

Because the basic assumptions of deterministic user equilibrium assignment that all network users have perfect information of network condition and determine their routes without errors are known to be unrealistic, several stochastic assignment models have been proposed to relax this assumption. However. it is not easy to solve such stochastic assignment models due to the probability distribution they assume. Also. in order to avoid all path enumeration they restrict the number of feasible path set, thereby they can not preciously explain the travel behavior when the travel cost is varied in a network loading step. Another problem of the stochastic assignment models is stemmed from that they use heuristic approach in attaining optimal moving size, due to the difficulty for evaluation of their objective function. This paper presents a logit-based stochastic assignment model and its solution algorithm to cope with the problems above. We also provide a stochastic user equilibrium condition of the model. The model is based on path where all feasible paths are enumerated in advance. This kind of method needs a more computing demand for running the model compared to the link-based one. However, there are same advantages. It could describe the travel behavior more exactly, and too much computing time does not require than we expect, because we calculate the path set only one time in initial step Two numerical examples are also given in order to assess the model and to compare it with other methods.

• Proceedings of the Korea Water Resources Association Conference
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• 1990.07a
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• pp.49-52
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• 1990

강우강도가 큰 집중호우가 지표면에 도달하게 되면 강우량중 상당 부분이 수문학적 손실성분인 침수, 증발산, 차단 및 저류등으로 시간에 따라 분포된다. 이 가운데 지표면에 분포된 식생계 및 낙엽등에 의한 차단(canopy interception effect)과, 지표가 포화시의 증발산(wetted environmental evapotranspiration) 및 각종 저류, 즉 지표면 저류(depression storage), 지표토양층에의 저류(retention storage) 성분 등을 들 수 있으며 이들 각 손실성분은 직접유출로 나타나는 초과우량의 발생시간을 지체시켜 주는 역할을 하나 차단성분 및 저류성분은 시간이 경과함에 따라 결국은 증발산 또는 침투성분으로 흡수된다. 따라서 침투성분은 초과우량 추정에 매우 큰 영향을 줄 뿐 아니라 지표면 아래의 흙의 변형을 야기시키며, 중간유출 및 지하수유출에 기여 한다. 대부분의 호우사상은 강우초기에 강우강도가 지표 흙의 침수계수(hydraulic conductivity)보다 작기 때문에 모두 각 손실성분에 의해 손실되며, 강우강도가 점차 커져 침수능을 초과하면 지표면에 순간적으로 물이 고이게 되는데 이것을 지표심수(surface ponding)라하고, 강우시작부터 이 때까지가 침수시간(ponding time)이 된다. 이 지표침수가 나타나는 순간이 곧 직접유출 시작 시간으로 볼 수 있을 뿐 아니라, 침수시간은 지표면의 물수지면에서 볼 때 초기손실량 및 침수율 결정에 중요한 인자가 된다. 본 연구에서는 각 손실 성분별로 유역의 제반 특성을 고려하여 구한 매개변수로부터 시간에 대한 손실율을 결정하여 산지 하천유역에 발생하는 부정강우사상(unsteady rainfall)의 초과우량을 추정하는 모델을 유도하였다. 대상유역으로는 현재 건설부에서 수행하고 있는 국제수문개발계획(IHP) 대표시험유역 가운데 평창강 수계내의 장평유역으로서, 본 유역은 자기 우량계 및 자기 수위계가 운용되고 있고, 인접 대관령 측후소로부터 기상자료를 획득, 이용할 수 있는 비교적 분석에 양호한 조건을 지닌 유역이다. 모델의 유도 과정은 대상유역 식생계로 피복된 산지유역임으로, 식생차단 저류효과를 고려해서 지표면의 흙에 도달되는 순강우주상도를 얻고 이로부터 침수시간 및 침투율을 결정해서 초과우량을 산정하는 모델을 유도하였다. 강우 지속시간내 즉, 유역이 완전 포화시의 증발산율의 결정은 Morton 모델로부터, 침수시간 및 침투율 결정은 Green-Ampt 방정식을 부정강우사상에 적용할 수 있도록 수정된 모델을 사용하였으며, 분석에 이용된 호우는 1986 ~ 1987년도 발생된 호우사상 가운데 강우강도 및 총 강우량이 비교적 큰 7개 강우사상을 선정하였다. 각 호우사상별로 손실율울 지표면에서 물수지개념을 이용하여 계산하고 산술지상에 구성시킨 결과는 다음 그림과 같다. 이 그림에서 굵은 실선으로 나타낸 곡선(B. L. R)은 각 손실을 곡선을 시간축에 따라 산술평균한 대표손실율곡선이다. 이 대표손실율곡선은 역지수함수형으로서 곡선식의 유도는 회기분석을 이용하였다. 초과우량 주상도를 얻기 위하여 이 대표손실을 곡선을 관측 강우주상도에 적용시켜 본 결과 식생계에 의한 차단 저류율은 약 6mm/hr 정도인 것으로 나타났으며, 이로 인한 침수시간 지체효과는 1~3시간 정도로서 비교적 그 영향이 큼을 알았다. 또한 각 호우사상별 침수시간 계산 결과 그 변동이 큰 것으로 나타났는데 이는 초기 강우강도에 민감하기 때문인 것으로 판단되낟. 한편 유역 포화시의 증발산율은 우기의 기상자료를 이용하여 구한 결과 0.05 - 0.10 mm/hr 의 범위로서 이로 인한 강우손실량은 큰 의미가 없음을 알았다.

• Journal of Educational Research in Mathematics
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• v.22 no.3
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• pp.371-386
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• 2012

This research assumes two facts; One is that the mathematics curriculum reform of Korea in 2007 would have been better if it had been a revise instead of deletion and the other is that every school curriculum should be of help for the sound enhancement of all 6 types of logical concepts that appears in the Piaget's theory of cognitive development. What our mathematics curriculum has introduced as a correlation is not the one of the 6 logical concepts that Piaget had thought in his theory of cognitive development. In order to see the reason of that difference, we check the difference of jargons among the academic denominations, such as Pedagogy, Psychology and Statistics through their college textbooks. Because we suppose that the mismatch of 'Piaget's vs Curriculum's correlation' is due to the mis-communication among scholars of different academic denominations. With what we learned via the above analytical study leaned on an abduction and to get some idea on them for the potential future construction of school Statistics curriculum when it should be returned, which we believe so, we observe two foreign highschool mathematics textbooks briefly. As a result of the study, we found that the concept of correlation in Pedagogy contain all kinds of relation while it was stingy in Statistics. Here we report a main result; A careful discretion among similar concepts of correlation, such as linear relationship(correlation), stochastic change along conditions(dependence), central comparison(other relation) are needed for the potential future curriculum. And if new curriculum contains the linear correlation then we strongly recommend to involve the regression line to connect it with the linear function chapter.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.12
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• pp.714-722
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• 2017

The TPLMs is a system to manage the total amount of pollutants discharged from the watershed in order to achieve the target water quality of the river. In this process, the pollutant load can be classified into generation, discharge and delivery load. When using equation 2, the discharge coefficient should be 1. In case of using equation 3, it is considered that the discharge coefficient defined in the Technical Guideline should be applied. The delivery load is calculated as the product of the discharge load and the delivery ratio, and the delivery ratio is defined as the rate at which the pollutant discharged from the watershed reaches a specific point in the stream. In this study, the delivery ratio estimation method proposed by Hwang (2016) was applied to the Yonggang watershed in the Nakdong river. And the input data of QUALKO2 model was generated by using the estimated delivery ratio (equation 3) and the validation study was conducted by comparing with DRave (equation 2). As a result of the study, it is possible to use both the equation 2 and the equation 3, but it is necessary to change the methodology according to the application of the discharge coefficient.

• Journal of the Korean Chemical Society
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• v.46 no.4
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• pp.363-377
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• 2002

The purpose of this study was to improve the problems of the voltaic cell described in the science textbooks of secondary schools. For this purpose, the contents of science textbooks which are related to the voltaic cell were analyzed and the problems which were not explained clearly by theorems were tried to be explained by experiments, and lastly sug-gestions were made toward the improvements regarding the voltaic cell in the science textbooks. The findings are that there are problems on the ways of ensuring whether the voltaic cell operates properly as a chemical battery, on the explanation of why the hydrogen bubbles form at the zinc electrode, on the cell potential, on the unification of the electrode terminology used, and on the mention of the current. Solutions to the problems except the cell potential were suggested. According to the experiment, the theoretical potential was calculated by considering the potentials of redox reactions at the two electrodes of the cell and by taking into account the characteristics of the electrodes such as the work function, ionization energy, stan-dard reduction potential, and electronegativity.The cell potential of the voltaic cell is explained by several factors. In the improved version of the textbook's introduction section to the voltaic cell, it is necessary to describe the voltaic cell his-torically.For the conceptual section, it should be explained in terms of the Daniel cell.

• Journal of Digital Convergence
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• v.10 no.11
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• pp.565-577
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• 2012

Various factors affecting teachers' self-confidence exist in math class using technology such as graphic calculators. For example, internal factors such as teachers' attitude and external factors such as school administrators or colleague's support can be considered. Pedagogical Technology Knowledge(PTK) is the very important factor which determines teacher's self-confidence in educational technology, and the development of PTK is composed of teacher's perception on the technology and its application and instrumentation. This study investigated 19 pre-service and current middle and high school teachers in the respect of their change of self-confidence, attitude, expertise on pedagogical technology, and quality of math class. These are anlayzed with the concept of instrumentation and instrumentalization through various experiences like graphic calculator, GPS and AutoGraph. The result indicated that constraints or obstacles did not affect much if teachers' attitude and self-confidence were strong. Particularly teachers' firm will to learn about technology and their confidence on its value are the critical factors in using technology for mathematics class.

• Journal of KIISE:Computing Practices and Letters
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• v.11 no.3
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• pp.209-215
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• 2005

Conventional ORDBMS vendors provide extension mechanisms for adding user-defined types and functions to their own DBMSs. Here, the extension mechanisms are implemented using a high-level interface. We call this technique loose-coupling. The advantage of loose-coupling is that it is easy to implement. However, it is not preferable for implementing new data types and operations in large databases when high Performance is required. In this paper, we propose to use the notion of tight-coupling to satisfy this requirement. In tight-coupling, new data types and operations are integrated into the core of the DBMS engine. Thus, they are supported in a consistent manner with high performance. This tight-coupling architecture is being used to incorporate information retrieval(IR) features and spatial database features into the Odysseus/IR ORDBMS that has been under development at KAIST/AITrc. In this paper, we introduce Odysseus/IR and explain its tightly-coupled IR features (U.S. patented). We then demonstrate a web search engine that is capable of managing 20 million web pages in a non-parallel configuration using Odysseus/IR.

• Proceedings of the Korea Society for Simulation Conference
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• 1993.10a
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• pp.11-11
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• 1993

도메인에 대한 전문 지식 획득(Acquisition of expert knowlegde)은 지식 제공자인 인간 전문가에 의존한다. 도메인이 복잡해 질수록 인간 전문가로부터 관련된 모든 지식을 획득하기란 어렵다. 이런 지식 획득의 어려움을 부분 흑은 완전 자동화된 지식 획득 시스템을 통해 해결하려는 많은 연구가 있어 왔다. 그러나 지식 획득을 위한 여러 시도들은 지식 제공자의 촛점이 도메인이 아닌 표현 구조나 도구- representation environment -에 보다 치우치게 하여, 잘못된 지식을 획득하게 하거나 주요지식이 생략되는 경우를 보이기도 한다. 또한 정적인 관계(relationship)에 의해서만 지식(Static Knowledge)을 생성하므로 시간흐름에 따라변화하는 지식을 나타내기는 어렵다. 본 연구에서는 시뮬레이션을 통한 자동 지식 획득(Simulation Based automatic Knowledge Acquisition) 방법을 제시한다. 이 방법은 1) 도메인에 관한 초기 인과관계 정보를 입력 받고, 2) 입력된 정보를 일정한 프레임에 따라 구조화 시켜 경험 베이스를 구성하고 이를 탐색하여 도메인과 관련된 확장된 정보를 얻은 후, 3) 위의1),2)를 통해 얻어진 정보를 분석하여 주어지는 입력에 대해 다양한 출력을 낼 수 있는 시뮬레이션 모델을 생성한다. 이 모델은 다음 단계의 지식 생성을 위한 수단(resource)이 되며, 구간값과 같은 불확실한 정보를 포함할 수 있는 구조이다. 마지막으로 4) 생성된 모델을 시뮬레이션하여 결과로 생성된 지식을 획득한다. 위의 과정에서, 지식획득을 위한 수단인 시뮬레이션 모델이 지식 제공자의 개입 없이 자동 생성됨에 따라, 지식 제공자는 도메인 관련 지식 그 자체에 집중할 수 있으며, 생성된 모델을 시뮬레이션한 결과에 의해 지식을 생성함으로써 동적인 지식이 얻어질 수 있다. DEVS 모델에 대한 타당성 검사 방법을 고찰하고 그 문제점에 대하여 자세히 설명한다. DEVS 모델의 타당성 검사에 이용하는 SPN 모델에 대한 개념과 DEVS 모델과 행위적으로 동등한 SNP 모델로 변환을 위한 관점을 제조명하다. 동일한 관점에서 두 모델의 상태표현이 같도록 DEVS 모델이 SPN 모델로 표현됨을 보이는 변환이론을 제시하고 변환이론을 바탕으로 모델 변환과정을 제시한다. 모델 변환이론과 변환고정을 기본으로 타당성 검사를 위한 새로운 동질함수(homogeneous function)를 정의하고 이와 함께 SPN 모델의 특성을 이용하여 DEVS 모델에 대한 타당성 검사 방법을 새롭게 제안한다. 에탄올투여로 증가된 유리기 해독계 효소인 GSH-Px활성을 큰 폭으로 감소시키고 에탄올투여로 감소된 비효소적 항산화작용을 나타내는 GSH함량을 다량 증가시킴으로서 지질과산화물에 대한 방어력이 증가되어 나타난 결과로 여겨지며, 또한 혈청중의 ALT, ALP 및 LDH활성을 유의성있게 감소시키므로서 감잎 phenolic compounds가 에탄올에 의한 간세포 손상에 대한 해독 및 보호작용이 있는 것으로 사료된다.반적으로 홍삼 제조시 내공의 발생은 제조공정에서 나타나는 경우가 많으며, 내백의 경우는 홍삼으로 가공되면서 발생하는 경우가 있고, 인삼이 성장될 때 부분적인 영양상태의 불충분이나 기후 등에 따른 영향을 받을 수 있기 때문에 앞으로 이에 대한 많은 연구가 이루어져야할 것으로 판단된다.태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minimal $X^{0}$ elements)로 가정한다. 즉, [+wh] 의미의 겹의문사는 동일한 구성요 소를 지닌 병렬적 합성어([$[W1]_{XO-}$ $[W1]_{XO}$ ]$