• Economic and Environmental Geology
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• v.34 no.6
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• pp.539-553
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• 2001

Geochemical data of the Han river water, including four tributary water samples in the main Han river are presented in this paper. The concentration of dissolved ions in the North Han river water decreases in order of Ca>Na>K>Mg and HCO$_3$>NO$_3$>SO$_4$>Cl, which it mainly affected by the chemical weathering of granite and gneiss in the drainage basin. Meanwhile, the South Han river water shows a decreasing order of Ca>Mg>Na>K and HCO$_3$>SO$_4$>NO$_3$>Cl, which is controlled by the bed rock geology of carbornate rooks and the inflow of acid mine drainage from the metal and coal mines in the Taebaegsan and Hwanggangri areas. The main Han river waters are characterized by unusually high concentration of Na, Cl and SO$_4$ (Ca>Na>K>Mg and HCO$_3$>SO$_4$>CI>NO), indicating a significant anthropogenic pollution by human activities in the metropolitan Seoul city. The geochemical data of the Han river waters from 1981 through 1996 to 1999 records a significant increase in SO$_4$ and NO$_3$, which responsible for the increasing arid mane drainage and municipal anthropogenic pollution.

• Economic and Environmental Geology
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• v.35 no.2
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• pp.113-120
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• 2002

Oxygen and hydrogen isotopic compositions of stream water in the Han river basin are expressed by the equation of $\delta$D=6.6$\delta$$^{18}$ O-7.4, which is not satisfy the meteoric water line ($\delta$D=8$\delta$$^{18}$ O+10). It might be depended on the local climatic condition and the evaporation effect in the Han river basin. The $\delta$$^{18}$ O and $\delta$D values of stream water in the Han river basin range from -8.2 to -10$\textperthousand$ (avg. -9.1$\textperthousand$) and -60 to -96$\textperthousand$ (avg. -69$\textperthousand$), respectively. The stream water from the South Han river (8$\delta$$^{18}$ O= -8.9~ -10$\textperthousand$, avg.-9.3$\textperthousand$ $\delta$D: -66~ -96$\textperthousand$, avg.-69$\textperthousand$) is slightly more depleted in $^{18}$ O and D than those of North Han river ($\textperthousand$$^{18}$ O= -8.4~ -9.7$\textperthousand$, avg. -9.2$\textperthousand$, $\delta$D= -64~ -95$\textperthousand$, avg. -69$\textperthousand$). It reflects more altitude effect than the effect of latitude and Inflow of the $^{18}$ O eniched S $O_4$$^{2-}$ and HC $O_3$- from the carbonate rock and sulfide minerals in the Taebagsan and Hwanggangri mineralized zone. The Main stream water of the Han river having $\delta$D: -60~ -76$\textperthousand$ (avg.-68$\textperthousand$) and $\textperthousand$$^{18}$ O= -8.2~-10$\textperthousand$ (avg.9.0$\textperthousand$) is enriched in $^{18}$ O compared to the South and North Han river waters, which is caused by the evaporation effect. Binary simple mixing ratio of the Main Han river water between South and North Han river waters was obtained to be 6 : 4 by the isotopic data, suggesting a strong influence of South Han river water to the Main Han river water.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.3
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• pp.130-143
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• 1997

To investigate geochemical characteristics and the sources of the dissolved ion species in the river water in the Han river drainage basin, samples were collected at 60 sites from the Han river drainage basin. The data for. pH, conductivity, TDS (total dissolved solid), temperature, and concentrations of dissloved ions were obtained as follows : (1) The geochemical characteristics of the surface water in the South and North Han river drainage basins are mainly controlled by bed rock geology in the drainage basin and in the main stream of the Han river considerably affected by anthropogenic pollution. The South Han river water samples have high concentrations of $Ca^{2＋}$ (ave. 15.42 ppm), $Mg^{2＋}$ (ave. 2.74 ppm), HC $O_3$$^{[-10]}$ (ave. 51.9 ppm), which evidently indicates that the bed rock geology in a limestone area mainly controls the surface water chemistry. The concentration of S $O_4$$^{2-}$ is remarkably high (SHR10-2 : 129.9 ppm) because of acid mine drainage from the metal and coal mines in the upper reaches of the South Han river. (2) The South Han river and the North Han river join the Han river. in the Yangsuri, Kyounggido and flow through Seoul metropolitan city. The mixing ratio is about 60:40 at the meeting point (sample number HRl0). (3) The result of factor analysis suggests that the pollution factor accounts for about 79% and the bed rock type factor accounts for about 7% of the data variation. This means that the geochemical characteristics of the Han river water mainly controlled by anthropogenic pollution in the South Han river and main stream of the Han river drainage basin. (4) The chemical data for four tributaries such as the Wangsukcheon, the Tancheon, the Zunuangcheon, and the Anyangcheon show that the concentration of pollution elements such as N $O_2$, C $l^{－}$, P $O_4$$^{3-}$, S $O_4$$^{2-}$ and Mn are high due to municipal waste disposal.