• Clean Technology
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• v.18 no.1
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• pp.57-62
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• 2012

Aqueous poly (vinyl alcohol) (PVA) solution was modified by using hydrophobic vinyltriethoxysilane (VTEOS) and then adding different amounts of poly (acrylic acid) (PAA) to the resulting solution. Thermal and mechanical properties, contact angle, water vapor transmission rate (MVTR) and oxygen gas transmission rate ($O_2TR$) of the film samples fabricated by these solutions were investigated. The glass transition temperature (Tg) of the VTEOS-modified films was sightly increased and the value remained unchanged according to the amount of PAA. The tensile strength of the VTEOS-modified films was found to be 9.48~10.72 $kg/mm^2$ which showed no significant difference compared with that of PVA. The film prepared with VTEOS-modified PVA/PAA (= 90/10), of which the swelling and solubility were measured to be 198% and 0%, respectively, showed improved water-resistance. The MVTR and $O_2TR$ for the PET film (thickness 50 ${\mu}m$) coated with VTEOS-modified PVA/PAA (= 90/10) film (thickness 2.5 ${\mu}m$) were measured to be 11.04 $g/m^2/day$ and 3.1 $cc/m^2/day$, respectively.

• Proceedings of the Korean Society for Food Science of Animal Resources Conference
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• 2002.11a
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• pp.125-125
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• 2002

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.957-958
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• 2013

• Electrical & Electronic Materials
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• v.4 no.2
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• pp.132-142
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• 1991

본 연구에서는 유기절연재료의 재방사선 재료개발을 위한다는 측면에서 두께 15[.mu.m]의 이축 연신 폴리프로필렌 필름을 시료로 선정하여 Co$^{60}$-.gamma.으로 조사시켜 온도 25-55[.deg.C], 전계 10-250[MV/m]사이에서 방사선 조사량 변화에 따른 전기전도현상을 연구하였다. 조사된 시료의 전기전도는 온도에 크게 의존하여 전계의 증가와 더불어 각기 다른 전도기구 특성을 갖는 4개의 영역으로 구분되었는데 각 영역별로 조사선량 변화에 따른 하전입자들의 거동상황을 규명하고 기초적인 제 물성정수를 결정하였다.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1908-1910
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• 2001

본 논문은 마이크로머시닝 기술을 이용하여 lift-off 공정으로 패턴닝 한 후 TMAH (Tetramethylammonium Hydroxide) 용액으로 $5{\sim}100{\mu}m$ 두께의 실리콘 다이어프램을 제작하였다. Pt/Ti 박막을 HF 전해질의 mask 물질로 사용하여 HF 용액 내에서 전기화학적 방법으로 정전압을 인가, 다이어프램 영역에 다공질 실리콘을 성장시켜 관통하였다. 140$^{\circ}C$의 질소 분위기에서 $10{\sim}15{\mu}m$두께의 LDPE(Low Density Poly Ethylene) 필름을 물리적으로 다이어프램 영역에 코팅하고 $K_2CO_3$ 용액내에서 ${CO_3}^{2-}$ 이온의 barrier에 의한 전류의 감소를 전기화학적인 분석방법에 의하여 측정하였다. 일정 전압하에서 이온 농도에 기인하는 다공질 실리콘과 LDPE 표면에서 Barrier의 두께에 따른 저항의 증가를 전극으로 감지하여 농도-전류의 특성을 측정하고 이것을 기준으로 하여 미지농도의 $K_2CO_3$ 용액내의 ${CO_3}^{2-}$ 이온 농도를 측정하였다.

• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.138-147
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• 1992

Chemically-modified electrodes were fabricated and their electrocatalytic behaviors have been investigated. As a modifying layer, poly-[1-methyl-3-(pyrrol-1-ylmethyl) pyridinium] was electropolymerized onto Pt electrodes under constant current. The thickness of the polymer film was controlled by means of total charge consumed during the electropolymerization. SEM was used to measure the thickness. There was a linear relationship between the passed charge and the film thickness. Ferro/ferricyanide, used as an electron mediator in this study, was rapidly ion-exchanged into the polymer layer with its concentration of 1.2~1.3M. It was found that electrooxidation of ascorbic acid is catalyzed by incorporated ferri/ferrocyanide couple. Kinetic parameters for electrooxidation were determined by RDE experiments. The results indicate that the present system corresponds to ER+S case based on the Saveant theory. Improving methods have been proposed to be R+S case which is ideal for electrocatalysis.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.27 no.6
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• pp.289-294
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• 2017

Films fabricated using atomic layer 2-dimensional nanosheets exhibit various physical properties depending on the size of the nanosheet. This is because the physical properties of the film depend on the interfacial properties between the sheets. Therefore, the synthesis of large-sized nanosheets is very important because it can reduce the dependency of the film on the interfacial properties. In this study, we succeeded in fabricating $TiO_x$ nanosheets with atomic layer thickness over micrometer size by using single-crystallized starting material and its chemical exfoliation. In addition, it was revealed that the mechanical agitation speed (the stirring speed of a magnetic bar) during the exfoliation step using the organic material is closely related to the nanosheet size and the colloidal concentration of the nanosheets.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.336.1-336.1
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• 2014

대표적인 TCO 물질인 ITO는 디스플레이 패널이나 태양 전지 등과 같은 소자에 널리 사용되고 있다. 최근에는 대량생산 및 대면적화, 그리고 유연 디스플레이 응용을 위해 롤투롤 스퍼터링(roll to roll sputtering) 공정을 이용하여 플라스틱 기판에 ITO박막을 증착하여 ITO 필름을 제작하고 있다. 롤투롤 방식으로 ITO 필름의 제작 시 공정 변수에 따라 ITO 박막의 전기적 광학적 물성 변화가 매우 크기 때문에, 공정 변수에 따른 ITO 박막의 전기적, 광학적 특성 변화에 대한 연구의 필요성이 매우 높아지고 있다. 따라서 본 연구에서는 롤투롤 스퍼터링 방법으로 PET 기판 위에 다양한 조건으로 ITO 박막을 증착하여 공정변수에 따른 ITO 박막의 물성을 조사 하였다. 이를 위해 ITO (In/Sn=95/5 wt.%) 타겟을 사용하여 DC 파워와 산소 분압비, 열처리 온도 등을 변화시켜 낮은 면저항과 높은 광투과도를 가지는 최적의 ITO 증착 조건을 찾은 후 ITO 박막을 PET 기판 위에 두께 별로 증착 하였다. ITO 박막의 두께와 열처리 온도에 따른 전기적 특성은 면저항 측정기와 홀 측정 장치를 이용하여 분석하였고, 분광광도계와 탁도 측정기를 이용하여 광학적 특성을 관찰하였다. 또한, GIXD를 이용하여 이들 박막의 구조와 결정성에 대한 조사를 수행하였다. 이 결과들로부터 산소 분압비에 따른 ITO/PET 박막의 저항 특성 변화와 ITO 박막의 두께와 열처리 온도에 따른 구조적, 전기적, 광학적 특성을 조사하여, 롤투롤 스퍼터링법에서 공정 조건에 따른 ITO/PET 필름의 물성변화를 보고하고자 한다.

• Journal of the Korean Society of Radiology
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• v.3 no.2
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• pp.11-16
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• 2009

Mercury Iodide as good sensitivity at radiation and has an easy peculiarity that operates at low voltage for other photoconductors(a-Se, a-Si, Ge, etc) Based on this characteristic, we studied about an efficiency of the digital x-ray detector in acccordance with the thickness of photoconductor. To solve the problem that is difficult to make a large area film using PVD(Physical Vapor Deposition)method, we used a PIB(Particle In Binder)method. To make a binder paste, we used a PVB(Polyvinylbutyral) as a binder and a DGME(Diethylene Glycol Monobutyl Ether), DGMEA(Diethylene Glycol Monobutyl Ether Acetate) as a solvent. Using this binder paste, we made a polycrystal mercury iodide film that has an each thickness. To evaluate the electrical properties of this films, we measured a darkcurrent, sensitivity and SNR(Signal to Noise Ratio). Mercury iodide film of the 200um thickness has good electrical properties as a result of the measurement. From this result there is a good chance that replace the existing a-Se(Amnorphous seleinum; a-se) with the mercury iodide.

• Journal of Bio-Environment Control
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• v.5 no.1
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• pp.23-33
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• 1996

This study was performed to induce a quality improvement and standardization of materials used for greenhouse. For this purpose, physical and mechanical properties of agricultural films for greenhouse were measured by kinds and thickness of the films. The properties are composed of impact, tensile, tear propagation strength and light transmittance. The results were summarized as follows. 1. At the impact test result of the falling dart, the thicker the film, the greater the impact strength of soft film. The impact weight at 50 percents is from 158g to 213g and the strength of low density polyethylene(LDPE) film is higher than the rest of any other films. 2. Seeing the leveling of the impact rupture, maximum impact weight which was ruptured very little ranges from 62g to 192g. The impact strength of 0.1mm films was higher than that of 0.05mm as from 1.8 to 3.2 times. 3. Tensile weight covers from 0.95kg to 2.22kg in the test materials, and the weight of lengthwise film is larger than that of width. LDPE film has high value of tensile weight. Elongation range is from 345 to 102 percent and lengthwise elongation is greater than width as much as from 1.4 to 2.7 times. 4. Tea. propagation strength ranges from 80.5kg/cm to 121.7kg/cm, and unlike which of LDPE film has high value, EVA film has low value in the films tested. The width strength is higher than the lengthwise. 5. The light transmittance of the soft film is about 78-92 percent in the range of ultraviolet ray, but has high value in the visible ray range.