• Journal of Korean Society of Environmental Engineers
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• v.30 no.11
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• pp.1139-1145
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• 2008

The objectives of this research are to investigate the mechanism of coagulation affecting UF and find out the optimum conditions of the combined of coagulation with UF membrane filtration for NOM removal. During the mixing period, substantial changes in particle size distribution occurred under rapid and slow mixing condition due to the simultaneous formation of microflocs and NOM precipitates. Therefore, combined pretreatment using coagulation (both rapid mixing and slow mixing) improved dissolved removal efficiency. Also, for combined coagulation to membrane process, flux reduction rate showed lower than only UF process. The rate of flux decline for the hydrophobic membrane was considerably greater than for the hydrophilic membrane. Applying coagulation process before membrane filtration showed not only reducing membrane fouling, but also improving the removal of dissolved organic materials that might otherwise not be removed by the membrane.

• Clean Technology
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• v.7 no.1
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• pp.35-42
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• 2001

This study was performed to evaluate the effect of zeolite addition on biofloc in aictvated sludge process. Two units were compared each other, in which one was operated as control unit (CU) and the other was managed by adding zeolite into aeration basin to sustain 4,000 mg/l (ZU). It was observed that flocs of both units were enduringly increased in medium size by extending SRT (Solid Retention Time), although their effect size of ZU was smaller than theirs of CU. Zeolite application excessively improved sludge settling property and ZU presented sludge settling velocity of 3.4 to 11 m/h regardless of SRT variation. The sludge volume index (SVI) was in the range of 50 and 108 ml/g. Conversely, the sludge settling velocity of CU seriously depended on SRT increase, and sludge sedimentation was not achieved at a 40 days of SRT due to Sphaerotilus appeared predominantly in reactor.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.551-555
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• 2015

본 연구는 수체 내 오염물질을 직접적으로 처리할 수 있는 친자연형 소재와 생물을 통한 처리의 다양한 기술 및 공법 중 식생을 이용한 수질의 정화효율에 대해 조사 하였다. 사용된 식생은 환경부 '하천식물자료집'을 바탕으로 수질정화능력이 있고 다년생으로 안정적인 생육특성을 갖는 식생으로 노랑꽃창포, 부들, 수크령, 질경이택사, 창포를 선정하여 약 13 L 크기의 원통형 반응조내에서 실험을 진행하였다. 선별된 식생들은 물가에 서식하는 식물로 15 cm 마사토를 식재 기반으로 하여 반침수 조건으로 실험을 진행하였다. 유입수는 경기도 용인시 기흥구에 위치한 기흥저수지 샘플과 경기도 화성시에 위치한 황구지천 샘플 혼합액 7 L를 주입하여 유입수 대비 유출수의 COD, T-N, T-P에 대한 저감 효율을 검토하였다. 노랑꽃 창포와 창포의 경우 침수된 부분에 플럭이 발생하여 투명도가 낮은 것으로 확인되었고, 수크령과 질경이택사의 경우 노랑꽃 창포와 창포에 비해 플럭의 발생은 적었지만 투명도는 비교적 높은 것으로 확인되었다. 특히 부들은 다른 식생에 비해 성장이 왕성한 것을 관찰할 수 있었으며, 수체의 탁도 또한 매우 낮아 투명한 것으로 확인되었다. 실험 종료 시점에는 창포의 경우 수체 내에서 잎 자체가 분해되어 식재기반 상부가 검정색으로 혐기화 된 것으로 나타났고, 부들의 경우 플럭이 약간 형성되었으나 투명도가 좋고 성장이 왕성한 특징을 나타내었다. 부들의 경우 COD, T-P의 평균 제거효율이 각각 47.1%, 46.0%로 조사되었고, 노랑꽃창포의 경우 T-N의 평균 제거효율이 63.9%로 선별 된 식생 중 가장 높게 조사되었다. 따라서 수질정화를 위한 공법으로는 부들과 노랑꽃창포가 적용 가능할 것으로 판단된다.

• Korean Chemical Engineering Research
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• v.44 no.2
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• pp.207-215
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• 2006

The characteristic floc growth of Al-based coagulants was investigated in the aspect of mixing intensity and visualization of generated flocs during coagulation and flocculation processes. Zeta potential of turbid particles in the artificial water nearly approached to zero at pH 8-9, in which TDS and conductivity were minimized. The removal rate of turbidity and phosphate was maximized at the optimal mixing intensity of rapid and slow mixing stages. After the rapid mixing stage of coagulation process, small particles ($3-5{\mu}m$) were abruptly generated, and higher mixing intensity made more numbers of flocs. With the progress of slow mixing stage, the number of small particles were decreased with the simultaneous increase of intermediate particles ($7-21{\mu}m$). The number of large particles (>$23{\mu}m$) were maximized at the lowest rapid mixing intensity of $95.1sec^{-1}$, whereas small particles (<$5{\mu}m$) were maximized at the highest rapid mixing intensity of $760.7sec^{-1}$.

• Clean Technology
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• v.7 no.1
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• pp.75-80
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• 2001

In this study, hexavalent chromium (Cr(VI)) plating wastewater in strong acidic condition was treated by reduction and alkalization. Ferrous sulfate ($FeSO_4$), known to reduce Cr(VI) to Cr(III) rapidly at acidic pH, was used as a reductant of Cr(VI). The optimum reduction condition of Cr(VI) was observed at iron to chromium dose ratio of 3:1 by mole concentration. The precipitation of Cr(III) as $Cr(OH)_3$, was achieved by the pH adjustment in the limestone aeration bed. The precipitates were removed less than the upper limit of chromium for effluent at pH over 5.0. The continuous removal of Cr(VI) was performed using the process consisting of reduction vessel, limestone aeration bed, and sedimentation tank coupled with metal screen membrane. As pH was maintained around 5.0 in the limestone aeration bed, insoluble chromic hydroxide flocs was formed continuously. Most chromic hydroxide flocs were filtered by the metal screen membrane with 1450 mesh size, and the treated water to meet the upper limits of chromium for effluent (Cr Conc. 0.25~0.90 mg/l) was obtained in 30 minutes. Periodic backwashing decreased the fouling on the membrane rapidly.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.245-245
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• 2019

점착성 유사는 유사가 가지는 점착력에 의해 응집현상을 겪으며 그 크기와 밀도가 변화한다. 유사의 크기와 밀도는 침강속도에 직접적인 영향을 주며 침강속도는 변화는 유사의 거동에 매우 중요한 작용을 한다. 따라서 점착성 유사의 크기 특성을 파악하는 것은 필수적이다. 본 연구는 유사가 가지는 입도분포를 파악하기 위해 통계학적 접근법을 적용하여 분석하였다. 점착성 유사의 입자가 가지는 입도 분포를 구체화한 결과를 유사의 입도 분포를 위한 수치 모의 연구에 적용하여 모의 결과를 향상시키고 유사 문제의 분석에 용이하도록 하려 한다. 통계학적인 방법 중 적합도 검정을 이용하여 실제 점착성 유사의 입도가 어떠한 분포를 모사하는지 분석하였다. 수집된 입도 분포 자료에 적합도 검정 방법 중 Kolmogorov-Sminorv(K-S) 검정을 이용하였으며 유의수준 5%를 통과할 경우 이론 분포가 점착성 유사의 입도 분포를 잘 모사하는 것으로 판단하였다. 점착성 유사의 입도 분포를 수집하고 그 자료를 바탕으로 적합도 검정을 실시한 결과 많은 연구에서 점착성 유사의 입도 분포로 가정하고 있는 Log-normal 분포가 유의수준 5%를 기준으로 적합도 검정을 통과한 경우는 많지 않았다. 본 연구에서 검정한 결과로는 기존에 이용되는 Log-normal 분포는 위치 매개변수를 추가하여 3 매개변수 분포를 사용할 경우에만 점착성 유사의 입도 분포를 모사한다고 판단된다. 향후에는 점착성 유사의 입도 분포를 모사하고 사용함에 있어 Log-normal 분포를 무조건적으로 이용하는 것은 지양하고 점착성 유사가 가지는 특성을 파악하여 어떠한 입도 분포 형태를 나타낼지 미리 예측하여 이론 분포를 가정한다면 수치모형을 통해 점착성 유사의 입도 분포를 모사할 때 그 정확도가 크게 증가할 것으로 판단된다. 또한 점착성 유사의 입도 분포로서 제시한 GEV 분포와 Gamma 분포, Log-normal 분포를 FM 모형에 결합하여 입도 분포를 모의한 후 그 결과를 실제 현장에서 측정된 입도 분포와 비교하는 과정을 통해 실제 어떠한 분포가 가장 적합하게 모의하는지도 검증할 필요성이 있다고 판단된다. 또한 점착성 유사의 입도를 모사하는 분포를 새로 개발하여 사용한다면 점착성 유사의 이동과 특성을 연구할 때 가장 중요한 크기 특성에 대한 많은 정보를 제공할 수 있으며 유사와 관련된 문제를 용이하게 분석할 것으로 판단된다.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.581-589
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• 2005

Recently, membrane processes have been replacing the conventional processes for waste water treatment to produce better quality of effluent and to meet more stringent regulations because of water shortage. However, using membrane processes for water treatment has confronted with fouling and difficulty in treating dissolved organic pollutants. In this study, membrane process equipped with crossflow microfiltration is combined with coagulation process using alum and PAC to improve permeability and treatment efficiency. The effects of coagulant dosage and optimum membrane operating conditions were investigated from measurement of permeate flow, cumulative volume, total resistance, particle size, dissolved organic pollutant, dissolved aluminium and quality of effluent. Characteristic of PAC coagulation was compared with that of alum coagulation. PAC coagulation reduced membrane fouling because of forming larger particle size and increased permeate velocity and cumulative volume. Less dissolved organic pollutants and dissolved aluminum made decreasing-rate of permeate velocity being lowered. At using $0.2\;{\mu}m$ membrane, cake filtration observed. At using $0.45\;{\mu}m$ membrane, there was floc breakage due to shear stress occurred born circulating operation. It made floc size smaller than membrane pore size, which subsequently to decrease permeate velocity and to increase total resistance. The optimum coagulation dosage was $300{\pm}50\;mg/L$ for both alum and PAC. PAC coagulation was more efficiently used with $0.2\;{\mu}m$ membrane, and the highest permeate flux was in using $0.45\;{\mu}m$membrane. The greatest efficiency of treatment was as follows; turbidity 99.8%, SS 99.9%, $BOD_5$ 94.4%, $COD_{Cr}$ 95.4%, T-N 54.3%, T-P 99.8%.

• Clean Technology
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• v.18 no.4
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• pp.404-409
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• 2012

In this study, the effects of mixing intensity and coagulant dosages on the characteristics of floc growth for phosphorus removal were investigated. The experiments were conducted under Al/P molar ratio of 1.0, 1.5 and 2.0; rapid mixing intensity with G value of 100, 300, and 500 $s^{-1}$. The characteristics of floc growth were measured by flocculation index (FSI) and the removal efficiencies of phosphorus by using different size filters. The removal efficiencies of soluble phosphorus increased as Al/P molar ratio and rapid mixing intensity increased. However, the highest removal efficiencies of T-P were observed at G value of 300 $s^{-1}$. When Al/P molar ratio was lower than 1.0, the value of FSI at G value of 500 $s^{-1}$ was the largest. However, when Al/P ratio was larger than 1.0, the value of FSI at G value 300 $s^{-1}$ was the largest. Effects of mixing intensity and Al/P molar ratio on coagulation for phosphorus removal of synthetic and real wastewater effluent were observed to be similar.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.3
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• pp.234-240
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• 2010

The effectiveness of adding powdered zeolite and granular activated carbon (GAC) before starvation into biological reactor for recovering its performances was investigated. Two types of carrier addition in Sequencing Batch Reactor (SBR) system for non-saline and saline wastewater were evaluated after starvation periods. During the experiment, settleablity (SVI), floc size, fractal dimension, $COD_{Mn}$, T-N, T-P removal efficiencies and recovery time were monitored. When the wastewater feeding was resumed after starvation period for 5days, the SVI increased at the beginning of resumption and then decreased with time in both types. And the larger the floc size and fractal dimension of floc, the more increased removal efficiency for $COD_{Mn}$, T-N and T-P was also. Its performance recovery was strongly correlated with floc size and fractal dimension of activated sludge. After resuming the wastewater feeding, the SVI, floc size, fractal dimension, $COD_{Mn}$, T-N, T-P removal efficiency of SBR with carrier improved and reached its initial value faster compared to those of SBR without carrier.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.12
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• pp.7438-7442
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• 2014

An assessment of flocculation was performed by measuring the distribution of the floc size during sedimentation in water works. The size and number of flocs have a greater effect on an evaluation of the efficiency of flocculation rather than the turbidity. The data was collected in situ using particle image velocimetry and image analysis. The measurements were carried out at a water depth of 1m. The removal efficiency of the total organic compounds, UV absorbance and turbidity depended on the size and floc size distribution in flocculation as the G value. The G value of 50 sec-1, 30 sec-1 and 10 sec-1 showed the highest degree of efficiency in the case of an inlet water turbidity of 5 NTU, and the highest degree of efficiency was observed at a G value of 65 sec-1, 40 sec-1 and 10 sec-1 when the inlet water turbidity was 263 NTU. The number of flocs with a distribution of above $1,200{\mu}m$ was 14. The dynamics between two important growth mechanisms were investigated as the energy input changed. This is a certain method that makes use of the size and number of flocs as an efficiency assessment.