• Title/Summary/Keyword: 플라스틱 결함

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A Study on the Collection and Analysis of Tire and Road Wear Particles(TRWPs) as Fine Dust Generated on the Roadside (도로변에서 발생되는 미세먼지로써 타이어와 도로 마모입자 채집과 분석 연구)

  • Kang, Tae-Woo;Kim, Hyeok-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.293-299
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    • 2022
  • Recently, various stakeholder are interested in microplastic to cause pollution of the marine's ecosystem and effort to conduct study of product's life cycle to reduce pollution of marine's ecosystem. The micorplastic refer to materials of the nano- to micro- sized units and it can be classified into primary and secondary. The primary microplastic mean the manufactured for use in the specific field such as the microbead of the cosmetic or cleanser. also, secondary mean the unintentionally generated during use of the product such as the textile crumb by the doing the laundry. Tire and Road Wear Particles(TRWPs) are also defined as secondary microplastic. Typically, TRWPs are created by friction between the tread compound's rubber of the tire and the surface of the road du ring the driving cars. Most of the generated TRWPs exist on the roadside and some of them were carried to marine by the rainwater. In this study, we perform the quantitative analysis of the TRWPs existed in fine dust at the roadside. So, we collected the dust from the roadside in Chungcheongnam-do's C site with a movement of 1,300 cars per the hour. The collected samples were separated according to size and density. And shape analysis was performed using the Scanning Electron Microscope(SEM). We were possible to discover a lot of TRWPs at the fine dust of the 100 ± 20 ㎛. And we analysis it u sing the Thermo Gravimetric Analysis(TGA) and Gas Chromatography/Mass Spectrometer(GC/MS) for the quantitative components from the tire. As a result, it was confirmed that TRWPs generated from the roadside fine dust were included the 0.21 %, and the tire and road components in the generated TRWPs consisted of the 3:7 ratio.

A Study on the Physical Properties of a Compound Using the Crosslinking of Vinylized-mesoporous Silica and Regenerated Polyethylene (비닐화 실란이 도입된 메조포러스 실리카와 재생 폴리에틸렌의 가교결합을 이용한 컴파운드의 물성 연구)

  • Tae-Yoon Kim;Hyun-Ho Park;Chang-Seop Lee
    • Journal of the Korean Chemical Society
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    • v.67 no.6
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    • pp.420-428
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    • 2023
  • Crosslinking was introduced into vinylized-mesoporous silica and recycled polyethylene. By introducing a vinyl group into the mesoporous silica, it becomes a material capable of inducing cross-linking with non-polar polyethylene. By synthesizing vinylized-mesoporous silica and inducing crosslinking with recycled polyethylene, a recycled polyethylene composite with improved physical properties than existing recycled polyethylene was synthesized. In addition, even when a small amount is added according to the grade of recycled polyethylene using vinylized-mesoporous silica, the crosslinking reaction proceeds and all physical properties are improved. Four types of vinylized-mesoporous silica were synthesized, and the shape, microstructure, and functional groups were analyzed by TEM, BET, FT-IR, and XRD. Using vinylized-mesoporous silica, three types of compounds were blended by crosslinking reaction with recycled polyethylene. In order to confirm the presence or absence of crosslinking, analysis was performed using XPS and FT-IR, and physical properties such as tensile strength, elongation, flexural strength, and flexural modulus were confirmed using a universal testing machine. As a result, by applying vinylized-mesoporous silica to recycled polyethylene in various grades, the weak physical properties of existing recycled polyethylene were overcome. By applying the vinylized-mesoporous silica, recycled polyethylene composite material that overcomes the weak physical properties to the normal polyethylene, it shows the optimal physical property index that can be used commercially. Therefore, it is expected that it can potentially increase the use of recycled polyethylene and recycle resources.

The study of thermal change by chemoport in radiofrequency hyperthermia (고주파 온열치료시 케모포트의 열적 변화 연구)

  • Lee, seung hoon;Lee, sun young;Gim, yang soo;Kwak, Keun tak;Yang, myung sik;Cha, seok yong
    • The Journal of Korean Society for Radiation Therapy
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    • v.27 no.2
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    • pp.97-106
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    • 2015
  • Purpose : This study evaluate the thermal changes caused by use of the chemoport for drug administration and blood sampling during radiofrequency hyperthermia. Materials and Methods : 20cm size of the electrode radio frequency hyperthermia (EHY-2000, Oncotherm KFT, Hungary) was used. The materials of the chemoport in our hospital from currently being used therapy are plastics, metal-containing epoxy and titanium that were made of the diameter 20 cm, height 20 cm insertion of the self-made cylindrical Agar phantom to measure the temperature. Thermoscope(TM-100, Oncotherm Kft, Hungary) and Sim4Life (Ver2.0, Zurich, Switzerland) was compared to the actual measured temperature. Each of the electrode measurement position is the central axis and the central axis side 1.5 cm, 0 cm(surface), 0.5 cm, 1.8 cm, 2.8 cm in depth was respectively measured. The measured temperature is $24.5{\sim}25.5^{\circ}C$, humidity is 30% ~ 32%. In five-minute intervals to measure the output power of 100W, 60 min. Results : In the electrode central axis 2.8 cm depth, the maximum temperature of the case with the unused of the chemoport, plastic, epoxy and titanium were respectively $39.51^{\circ}C$, $39.11^{\circ}C$, $38.81^{\circ}C$, $40.64^{\circ}C$, simulated experimental data were $42.20^{\circ}C$, $41.50^{\circ}C$, $40.70^{\circ}C$, $42.50^{\circ}C$. And in the central axis electrode side 1.5 cm depth 2.8 cm, mesured data were $39.37^{\circ}C$, $39.32^{\circ}C$, $39.20^{\circ}C$, $39.46^{\circ}C$, the simulated experimental data were $42.00^{\circ}C$, $41.80^{\circ}C$, $41.20^{\circ}C$, $42.30^{\circ}C$. Conclusion : The thermal variations were caused by radiofrequency electromagnetic field surrounding the chemoport showed lower than in the case of unused in non-conductive plastic material and epoxy material, the titanum chemoport that made of conductor materials showed a slight differences. This is due to the metal contents in the chemoport and the geometry of the chemoport. And because it uses a low radio frequency bandwidth of the used equipment. That is, although use of the chemoport in this study do not significantly affect the surrounding tissue. That is, because the thermal change is insignificant, it is suggested that the hazard of the chemoport used in this study doesn't need to be considered.

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Applications of Functional Tray Form Packaging to Extend the Freshness of High-Quality 'Fuji' Apples (특 등급 품질 후지사과 선도유지를 위한 플라스틱 용기 포장 효과 연구)

  • Chung, Dae-Sung;Lee, Youn-Suk
    • Food Science and Preservation
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    • v.16 no.6
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    • pp.817-823
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    • 2009
  • We investigated the effects of storage temperature and packaging treatment on the freshness of high-quality 'Fuji' apples to improve consumer confidence in the maintenance of high fruit quality during distribution. A 0.35 mm-deep PET tray form-sealed with a 0.05 mm LDPE film lid was developed and tested with the aim of optimizing gas composition within the package headspace to utilize potential modified atmosphere (MA) storage to maintain the freshness of apples. Weight loss, color difference, firmness, respiration rate, gas concentrations in packages, acidity, solid soluble content, and fruit decay rate were measured during storage at $5^{\circ}C$ and $25^{\circ}C$. The results showed that respiration rate, weight loss, color difference, and firmness were lower and overall quality better during storage at $5^{\circ}C$ compared with $25^{\circ}C$. Also, the fruits packed in the functional tray form showed a low level of quality changes compared with the control (no packaging). The accumulated gasconcentrations in the headspace of the packages decreased from 21% to 12% $O_2$ and increased from 0% to 5% $CO_2$ (v/v) on day 7, and after remained at those levels thereafter. Soluble solid contents and total acidities of the packaged fruits were in the range of $11\;-\;14^{\circ}Brix$ and 0.2 0.3% during storage. Decay rates in the control and packaged fruits were more than 20% and less than 10% at 3 weeks, respectively. Based on the standard acceptable level (less than 10%) of total weight loss, it could be estimated that the shelf life of top-quality fruits packed in functional trays was 3 weeks at $5^{\circ}C$ and 16 weeks at $25^{\circ}C$, whereas the shelf life of the control fruit was 1 week and 12 weeks, respectively. For the top-quality fruit "Fuji" apples, the best results were obtained with a functional tray form for packaging treatment and a storage temperature of $5^{\circ}C$.

Deepest Dormancy Period in Strawberry 'Reiko' and Time for Starting Insulation in Semi-forcing With Lighting in Daegu Area ('여홍' 딸기의 대구지방 휴면최심기와 반촉성 보온개시기)

  • Lee, Woo-Sung;Mun, Jong-Hak;Kim, Seung-Ki;Lee, Ha-Yoon
    • Horticultural Science & Technology
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    • v.19 no.4
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    • pp.488-494
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    • 2001
  • Seedlings of strawberry, 'Reiko' were planted in plastic pots of 24 cm in diameter in the middle of September in 1995, 1996, and 1997. Ten plants were transferred to greenhouse with artificial illumination at 5-day interval from late September to late January. The deepest dormancy of 'Reiko' in Daegu area was found to be on November 5, October 25, and October 31 in 1995, 1996, and 1997, respectively. The time for moving plants to make the plants grow in semi-dormant state in the greenhouse occurred between Nov. 10 and Nov. 20 in both 1995 and 1996, and between Nov. 10 and Nov. 30 in 1997. The time passing approximately 100-200 cumulative hours of exposure to below $5^{\circ}C$ canopy temperature from the peak dormancy, which is required for breaking dormancy of 'Reiko', was between November 16 and 25 in 1996, and November 24 and December 5 in 1997. 'Reiko' yielded high every year when seedlings were moved into greenhouse during the period of October to November. The plants gave good response to forcing culture under lighting. The right time for moving plants into greenhouse in semi-forcing culture appeared to be the time passing 50-150 cumulative hours of exposure to below $5^{\circ}C$ canopy temperature from the peak dormancy.

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Effect of microwave power on aging dynamics of solution-processed InGaZnO thin-film transistors

  • Kim, Gyeong-Jun;Jo, Won-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.256-256
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    • 2016
  • 기존의 디스플레이 기슬은 마스크를 통해 특정 부분에만 유기재료를 증착시키는 방법을 사용하였으나, 기판의 크기가 커짐에 따라 공정조건에 제약이 발생하였다. 이를 해결하기 위해 최근 용액 공정에 대한 연구가 활발히 진행되고 있다. 용액 공정은 기존 진공 증착 방식과 비교하였을 때 상온, 대기압에서 증착이 가능하며 경제적이고, 대면적 균일 증착에 유리하다는 장점이 있다. 반면, 용액 공정으로 제작한 소자는 시간이 지남에 따라 점차 전기적 특성이 변하는 aging effect를 보인다. Aging effect는 용액에 포함된 C기와 OH기 기반의 불순물의 영향으로 시간의 경과에 따라서 문턱전압, subthreshold swing 및 mobility 등의 전기적 특성이 변하는 현상으로 고품질의 박막을 형성하기 위해서는 고온의 열처리가 필요하다. 지금까지 고품질 박막 형성을 위한 열처리는 퍼니스 (furnace) 장비에서 주로 이루어졌는데, 시간이 오래 걸리고, 상대적으로 고온 공정이기 때문에 유리, 종이, 플라스틱과 같은 다양한 기판에 적용하기 어렵다는 단점이 있다. 따라서, 본 연구에서는 $100^{\circ}C$ 이하의 저온에서도 열처리가 가능한 microwave irradiation (MWI) 방법을 이용하여 solution-processed InGaZnO TFT를 제작하였고, 기존의 열처리 방식인 furnace로 열처리한 TFT 소자와 aging effect를 비교하였다. 먼저, solution-processed IGZO TFT를 제작하기 위해 p type Si 기판을 열산화시켜서 100 nm의 SiO2 게이트 산화막을 성장시켰고, 스핀코팅 방법으로 a-IGZO 채널층을 형성하였다. 증착후 열처리를 위하여 1000 W의 마이크로웨이브 출력으로 15분간 MWI를 실시하여 a-IGZO TFT를 제작하였고, 비교를 위하여 furnace N2 gas 분위기에서 $600^{\circ}C$로 30분간 열처리한 TFT를 준비하였다. 제작된 직후의 TFT 특성을 평가한 결과, MWI 열처리한 소자가 퍼니스 열처리한 소자보다 높은 이동도, 낮은 subthreshold swing (SS)과 히스테리시스 전압을 가지는 것을 확인하였다. 한편, aging effect를 평가하기 위하여 제작 후에 30일 동안의 특성변화를 측정한 결과, MWI 열처리 소자는 30일 동안 문턱치 전압(VTH)의 변화량 ${\Delta}VTH=3.18[V]$ 변화되었지만, furnace 열처리 소자는 ${\Delta}VTH=8.56[V]$로 큰 변화가 있었다. 다음으로 SS의 변화량은 MWI 열처리 소자가 ${\Delta}SS=106.85[mV/dec]$인 반면에 퍼니스 열처리 소자는 ${\Delta}SS=299.2[mV/dec]$이었다. 그리고 전하 트래핑에 의해서 발생하는 게이트 히스테리시스 전압의 변화량은 MWI 열처리 소자에서 ${\Delta}V=0.5[V]$이었지만, 퍼니스 열처리 소자에서 ${\Delta}V=5.8[V]$의 큰 수치를 보였다. 결과적으로 MWI 열처리 방식이 퍼니스 열처리 방식보다 소자의 성능이 우수할 뿐만 아니라 aging effect가 개선된 것을 확인할 수 있었고 차세대 디스플레이 공정에 있어서 전기적, 화학적 특성을 개선하는데 기여할 것으로 기대된다.

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Synthesis of Cubic and Rod Shapes CaCO3 by Hydrothermal Method (수열합성법을 이용한 큐빅과 로드형의 탄산칼슘 합성)

  • Kang, Kuk-Hyoun;Jeon, Sang-Chul;Hyun, Mi-Ho;Lee, Dong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.6
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    • pp.255-261
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    • 2016
  • $CaCO_3$ was applied in various industries including rubber, plastics, paint, paper, food additives, and acid neutralizer, etc., owing to its excellent physical and chemical characteristics as well as various appearances of crystals and many reserves. In particular, research on controlling the structure and shape of $CaCO_3$ has attracted considerable attention recently, because the whiteness and physical characteristics of $CaCO_3$ depend on the size and shapes of the particles. In this study, $CaCO_3$ was synthesized using $CaCl_2$ and $(NH4)_2CO_3$, which has multi-shapes and structures, using a self-assembly method with a hydrothermal method. The structure and morphology of the $CaCO_3$ could be controlled by adjusting the pH and precursor concentration. In particular, the pH adjustment appeared to be a critical factor for the morphology and crystal form. In addition, the calcite and cubic shape were obtained at pH 7, while the mixed calcite, aragonite structure, and rod shapes appeared at pH 7 and over. Through an analysis of the particle formation process, the formation of the calcium carbonate particles was confirmed. The physicochemical properties of the synthesized $CaCO_3$ were analyzed by SEM, XRD, EDS, FTIR, and TG/DTA.

Relationship between Drought-Tolerance and Physiological Parameters in Korean Barley Genotypes (보리 품종의 한발저항성과 생리적 지표와의 상관)

  • 이변우;부금동;백남천;김정곤
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.516-526
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    • 2003
  • Thirty-six barley varieties including Korean modern and local varieties were tested for drought-tolerance in the field of plastic rain shelter, Drought treatment was initiated at initial tillering stage (March 27, 2002) by withholding irrigation and lasted until harvest. Soil water potential maintained at around -0.05㎫ in the control plot and varied from -0.05㎫ (at the initial stage of drought treatment) to -0.29㎫ in the drought treatment plot. At forty days after drought treatment, relative water content (RWC), osmotic potential (OP), osmotic adjustment (OA), and $^{13}\textrm{C}$ discrimination ($\Delta$) were measured and then plants were sampled for leaf area index (LAI) and dry weight (DW). Barley was harvested at maturity for determining DW, grain yield, 1000 grains weight and number of spikelet. The tested varieties revealed wide spectrum of drought tolerance. Dongbori-1, Chalbori, Changyeongjaerae, Samdobori and Weolseong 87-31 showed strong drought-tolerance while Songhagbori and Suwonmaeg360 showed weak drought-tolerance. The drought injury indexes (drought/control ratio) of DW and yield revealed significant positive correlation with leaf RWC in drought treatment plot and $\Delta$ in the control plot, but obvious negative correlation with leaf OP and OA under drought condition. In addition, all the drought indexes of OP, $\Delta$ and RWC showed obvious positive correlation with the drought injury indexes of DW, 1000 grain weight and yield. Thus, OP and RWC under drought condition and $\Delta$ under well-watered condition would be used as the evaluation criteria for drought- tolerance of barley genotypes. However, further investigation is needed for the relationship between $\Delta$ and drought-tolerance as the other reports were not consistent with our result.

Evaluation of Heating Performance and Analysis of Heating Loads in Single Span Plastic Greenhouses with an Electrical or Hot-Air Heating (전기히터식 난방, 온풍난방시스템을 채용한 단동 플라스틱 하우스의 열부하 해석 및 난방성능 평가)

  • 허종철;임종환;서효덕;최동호
    • Journal of Bio-Environment Control
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    • v.8 no.2
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    • pp.136-146
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    • 1999
  • A series of experiments were carried out in winter to investigate the indoor thermal environment in greenhouses with different kinds of heating systems, and characterize the energy consumption, heat transport and thermal energy efficiency of each system. By the Quantitative calculation of heat losses which transmit through the covers of greenhouse, the fundamental data of energy-saving of the particular heating system were obtained. And from the analysis of air temperature differences between indoor and outside, it was possible to select more effective energy-saving and comfortable heating system in greenhouses. The electric heater was more stable in thermal environment and cheaper in cost, since it could be used during the surplus time of electric power from 10:00 p.M. to 8:00 A.M. But the low air temperature in greenhouses besides these times resulted in a chilling problem of the crops. The heating system by hot air had the advantage to show nearly uniform temperature difference by the height above the ground. But the system had the disadvantage to require more energy consumption than the electric heating system.

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Correlation between tonal events and their acoustic duration (한국어 성조 이벤트와 음향적 길이)

  • 이숙향
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1998.06c
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    • pp.383-386
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    • 1998
  • 한국어의 운율구조는 발화문장(utterance), 억양구(intonational phrase), 악센트구(accentual phrase), 음운적 어절(phonological word), 음절(syllable) 순의 계층적 구조를 가지고 있다. 본 연구에서는 운율구조의 각 층에서 성조 이벤트가 얹혀지는 음절이나 또는 각 층의 운율단위말의 음절의 음향적 길이를 측정함으로써 첫째, 운율단위말의 음절의 음향적 길이 또한 계층적 순위를 보이는지 둘째, 성조 이벤트(tonal event)와 음향적 길이 사이에 높은 상관관계를 보이는지 보고자 한다. 즉, 두 가지 측면에서 길이비교가 수행되었는데 하나는 언어 보편적 현상으로 알려진 구말 장음화 현상으로써 각 층 운율적 단위의 마지막 음절의 모음 길이 비교이며 다른 하나는 억양구초 고성조가 실현되는 음절의 모음과 어절 내 모음, 그리고 고성조가 실현되는 억양구말 음절의 모음간의 길이 비교이다. 남녀 각각 200문장의 각 분절음과 운율분석을 한 후 길이에 대한 일원분산분석 실시 결과 억양구말은 악센트구말 보다 길었으나 악센트구말은 어절말과 차이를 보이지 않거나 남자 화자의 경우 오히려 짧게 나타났다. 그리고 남자화자의 경우 악센트구초 고성자가 얹혀지는 음절의 길이는 어절 내 어절말 음절을 제외한 그 외 음절과 화자에 따라 큰 차이를 보이지 않거나 그보다 조금 짧게 실현되는 것으로 나타났다. 위의 결과는 첫째, 단위말 음절 모음의 장음화는 운율적 구조의 층위에 일대일 대응을 보이지 않는 것으로 해석되며 둘째, 성조 이벤트와 그것이 실현되는 분절음의 음향적 길이와는 큰 상관관계를 보이지 않는 것으로 해석될 수 있겠다. 그러나 이러한 일반화에 대한 충분한 근거 제공을 위해서는 해당음절의 모음 길이 뿐만 아니라 초성자음의 길이간의 비교와 음절자체의 길이 비교 또한 필요한 것이며 모음길이에 대한 선행자음의 분절음적 영향 고려가 수반되어야 할 것으로 보인다. 다음 내용을 정리해 보고자 한다.리해 보고자 한다.rc$ 구입할 때 중점적으로 살펴보는 사항은 신선도와 순수재래종 여부, 위생상태였다. 한편 소비자가 언제나 구입할 수 없다는 의견이 85.2%나 되어 원활한 공급과 시장조성이 아직 정착되지 않고 있었다. $\bigcirc$ 현재 유통되고 있는 재래종닭은 소비자 대부분이 잡종으로 인식하고 있었으며, 재래종과 일반육계와의 구별은 깃털색, 피부색, 정강이색등 외관상으로 구별하고 있었다. 체중에 대한 반응은 너무 작다는 의견이었고, 식품으로의 인식도는 비교적 고급식품으로 인식하고 있다. $\bigcirc$ 재래종닭고기의 브랜드화에 대한 견해는 젊고 소득이 높은 계층에서 브랜드화의 필요성을 강조하고 있다. $\bigcirc$ 재래종달걀의 소비형태는 대부분의 소비자가 좋아하였으나 아직 먹어보지 못한 응답자가 많았다. 재래종달걀의 맛에 대해서는 고소하고 독특하여 차별성을 느끼고 있었다. $\bigcirc$ 재래종달걀의 구입장소는 계란판매점(축협.농협), 슈퍼, 백화점, 재래닭 사육 농장등 다양하였으며 포장단위는 10개를 가장 선호하였고, 포장재료는 종이, 플라스틱, 짚의 순으로 좋아하였다. $\bigcirc$ 달걀의 가격은 200원정도를 적정하다고 하였으며, 크기는 (평균 52g)는 가장 적당하다고 인식하고 있으며, 난각색은 대부분의 응답자가 갈색을 선호하였다. $\bigcirc$ 재래종달걀의 구입시 애로사항은 믿을수 없고, 구입장소를 몰라서, 값이 싸다 등이었고, 앞으로 신뢰할 수 있고 위생적인 생산 및 유통체계가 확립될 경우 더 많이 소비하겠다는 의견이었다. $\bigcirc$ 재래닭 판매업소(식당)의 판매형태는 66.7%인 대부분의 업소가 잡종과 개량종 유색닭을 판매하고 있었으며, 1개 업소에서 1일 판

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