• Elastomers and Composites
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• v.45 no.3
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• pp.170-187
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• 2010

Much interest on the thermoplastic elastomers (TPEs) has recently been attracted in commercial fields as well as scientific and applied researches. The TPEs have their own characteristic area especially in relation with block copolymers as well as many other polymeric materials, since they show interesting features displayed by the conventional vulcanized rubber, and at the same time, by the thermoplastics. In addition, they are characterized by a set of interesting properties inherent to block and graft copolymers, variety of blends and vulcanized materials. The importance of TPE as organic materials can be evaluated by the number of published reports (papers, patents, technical reports, etc). The input of the concept 'thermoplastic elastomer' to SciFinderScholar yields 18,508 results between 1939 and July 10, 2010, and the number increased exponentially after the mid of 1990. For the suitable introduction of the TPE, historic, scientific, technical and commercial considerations should be taken into account. This review article starts with a brief discussion on historical considerations, followed by a introduction of the main preparations and analytical techniques utilized in chemical, structural, and morphological studies. The properties, processing tools, the position among organic materials, and applications of TPEs are also briefly reviewed. Finally, the most probable trends of their future development are discussed in a short final remarks.

• Journal of the Korean Chemical Society
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• v.54 no.2
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• pp.198-207
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• 2010

The construction and performance characteristics of doxepin hydrochloride selective electrodes were developed. Three types of electrodes: plastic membrane I, coated wire II, and coated graphite rod III were constructed based on the incorporation of doxepin hydrochloride with ammonium reineckate. The influence of membrane composition, kind of plasticizer, pH of the test solution, soaking time, and foreign ions on the electrodes was investigated. The electrodes showed a Nernstain response with a mean slope of 57.41 ${\pm}$ 0.5, 56.22 ${\pm}$ 0.2 and 52.88 ${\pm}$ 0.7 mV at $25^{\circ}C$ for electrode I, II and III respectively, over Doxepin hydrochloride concentration range from $1{\times}10^{-2}-1{\times}10^{-6}M$, $5{\tims}10^{-2}-1{\times}10^{-6}M$ and $1{\times}10^{-3}-5{\times}10^{-6}M$, and with a detection limit $5.0{\times}10^{-7}M$, $6.3{\times}10^{-7}M$ and $2.5{\times}10^{-6}M$ for electrode I, II and III respectively. The constructed electrodes gave average selective precise and usable within the pH range 3 - 7. Interferences from common cations, alkaloids, sugars, amino acids and drug excipients were reported. The results obtained by the proposed electrodes were also applied successfully to the determination of the drug in pharmaceutical preparations and biological fluids.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.742-748
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• 2005

Transparent conductive indium-tin oxide (ITO) films are widely used as transparent electrodes for flat panel displays. Many of the ITO films for practical use have been prepared by magnetron sputtering, chemical vapor deposition, electron beam evaporation, etc. An oxide target composed of 10 wt% $SnO_2$ and 90 wt% $In_2O_3$ has been deposited onto polycyclic olefin polymer (POP) substrate by electron beam evaporation. POP has a higher glass transition temperature ($Tg=330^{\circ}C$) than other conventional polymers. In this study, the effects of substrate temperature and the $O_2$ introduction flow rate were investigated in terms of physical, electrical and optical properties of deposited ITO films. We investigated the effects of processing variables such as substrate temperature and the oxygen introduction flow rate. The best electrical and optical properties of deposited ITO films obtained from this study were electrical resistivity value of ${\rho}=1.78{\times}10^{-3}{\Omega}{\cdot}cm$ and optical transmittance of about 85% at 8 sccm (Standard Cubic Centimeter per Minute) $O_2$ introduction flow rate, $5{\AA}/sec$ deposition rate, $1000{\AA}$ deposited ITO thickness and $200^{\circ}C$ substrate temperature.

• Journal of Radiation Protection and Research
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• v.7 no.1
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• pp.17-22
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• 1982

Measurement of the radon concentration close to the ground surface can be used in search of environmental radiation for human safety, exploration for uranium, premonitory signals from earthquakes. We can detect radons in soil gas by alpha particle track method using the plastic track detectors, cellulose nitrate (LR115-Type 2 and CA80-15, Kodak $Path\'{e}$) and CR-39. For present works, radon cups having these detectors were made in our laboratory and their conversion factor was determined. A typical conversion factor was $1tr/cm^2{\cdot}30days=1.2{\times}10^{-2}pCi/l$. In the radon cups, some of $CaSO_4$ were used as desiccant for reducing the moisture effects on plastic track detectors. With these radon cups, underground radon concentrations of Kyungpook area were measured. Average radon concentration in Daegu from Jan. 1981 to Feb. 1982 was 39.7pCi/l. From Aug. 1981 to Feb. 1982, average radon concentrations of Daegu, Angang, Kyungju, Pohang, Chungha, and Andong were 31.8pCi/l, 124.5pCi/l, 127.0pCi/l, 79.1pCi/l, 144.4pCi/l, and 70.9pCi/l, respectively. The results were compared with the environmental radiation measured by TLD method.

• Polymer(Korea)
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• v.36 no.1
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• pp.59-64
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• 2012

The impact strength of material is considered the most important design factor for small and light products. Impact strength is a unique material property, thus the impact strength should not depend upon the geometry of specimen. However it varies according to specimen thickness, notching method, and notch shape. In this study, the variations of impact strength have been investigated according to thickness, notch shape, and notching method of specimen. Engineering plastics such as PC, ABS and POM have been used in this study. Experimental results showed impact strength increased as thickness decreasesd. PC showed the highest increment of impact strength when the thickness was thin. Fractured section of PC showed brittle fracture behavior when the specimen was thick. However it showed ductile fracture behavior when it was thin. The impact strength of in-mold notched specimen showed higher than that of milling notched specimen. PC showed the highest notch sensitivity among the materials used in this experiment.

• Korean Journal of Optics and Photonics
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• v.12 no.2
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• pp.135-142
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• 2001

Recently, plastic optical fiber draws a lot of attention as a new transmission medium for local area network (LAN) and home network applications. As PMMA based GI-POF (Graded Index Plastic Optical Fiber) has very low loss at about 500 nm and 650 nm wavelengths, it is very important to have a compact ultra short optical pulse source at these wavelength windows. In this paper, we have investigated detailed characteristics of gain switched laser system by using a commercially available low cost RF devices and an InGaAlP Fabry Perot semiconductor laser operating at 650 nm wavelength. The shortest optical 'pulse obtained was 33 psec with 1 GHz repetition rate. Depending on the DC bias current and the modulation frequency, the FWHM and the pulse energy of the gain switched pulses show 33.3-82.8 psec and 0.97-9.69 pI respectively. Also, the spectral bandwidths for CW and gain switched operations are 0.44 nm and 1.50 nm. We believe that these results are quite useful for high bit rate optical transmission applications with PMMA based plastic optical fibers in addition to estimate properties of ultra fast optical components and electro-optic devices. vices.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.25 no.1
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• pp.11-16
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• 2019

This study analyzed various packaging materials and types for frozen foods and the effects of packaging materials on temperature changes during frozen process. Pouches with different film thickness were prepared and placed in an IQF freezer, then the temperature inside pouches measured using a deep thermometer. The most common types of primary packaging for frozen foods in the market was plastic pouches with polyethylene or polyamide/polyethylene multilayer materials. The temperature change inside of packaging was delayed with film thickness increased. As the size of packaged food increased, the temperature change inside the food was slowed down. In addition, the pouches with air inside took more time to reach $-30^{\circ}C$ compared to pouches with less air during frozen process. This study provides information on packaging materials and types for frozen foods and preliminary data of temperature change by different types of packaging.

• Resources Recycling
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• v.30 no.3
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• pp.70-81
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• 2021

This study evaluated the recyclability of waste plastics in used coffee capsules disposed of as municipal waste. For recycling, a new material separation process was developed to remove the coffee grounds through primary crushing, washing, sieving, and secondary crushing, followed by corona discharge electrostatic separation. Furthermore, for the under 10 mm size fraction samples, the aluminum removal and the plastic recovery were 95.4% and 98.3%, respectively, under optimal conditions. In addition, for the 15 mm fraction samples, the aluminum removal and the plastic recovery were 91.3% and 97.2%, respectively. To evaluate the recyclability of the separated waste plastics, the samples were pelleted, and their material properties were analyzed. No hazardous substances were detected, and the results were similar to those for homo-PP. Therefore, it was confirmed tha t sufficient functiona lity existed a s recycled PP. However, owing to the da rk color of the pellets, limited applications to black or dark products are expected.

• Journal of IKEEE
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• v.26 no.3
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• pp.510-514
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• 2022

In this paper, we propose the development of high-sensitivity low-end radiation measuring sensor module. The proposed measurement sensor module is a scintillator + photomultiplier(SiPM) sensor optimization structure design, amplification and filter and control circuit design for sensor driver, control circuit design including short-distance communication, sensor mechanism design and manufacturing, and GUI development applied to prototypes consists of, etc. The scintillator + photomultiplier(SiPM) sensor optimization structure design is designed by checking the characteristics of the scintillator and the photomultiplier (SiPM) for the sensor structure design. Amplification, filter and control circuit design for sensor driver is designed to process fine scintillation signal generated by radiation with a scintillator using SiPM. Control circuit design including short-distance communication is designed to enable data transmission through MCU design to support short-range wireless communication function and wired communication support. The sensor mechanism design and manufacture is designed so that the glare generated by wrapping a reflective paper (mirroring) on the outside of the plastic scintillator is reflected to increase the efficiency in order to transmit the fine scintillation signal generated from the plastic scintillator to the photomultiplier(SiPM). The GUI development applied to the prototype expresses the date and time at the top according to each screen and allows the measurement unit and time, seconds, alarm level, communication status, battery capacity, etc. to be expressed. In order to evaluate the performance of the proposed system, the results of experiments conducted by an authorized testing institute showed that the radiation dose measurement range was 30 𝜇Sv/h ~ 10 mSv/h, so the results are the same as the highest level among products sold commercially at domestic and foreign. In addition, it was confirmed that the measurement uncertainty of ±7.4% was measured, and normal operation was performed under the international standard ±15%.

• Journal of Navigation and Port Research
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• v.46 no.4
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• pp.331-337
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• 2022

In 2021, the Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection (GESAMP), a U.N. advisory research institute, cited container loss as one of six sources of marine litters in shipping. The sinking of the X-P ress Pearl in May 2021 caused a catastrophic environmental pollution accident in which the loaded containers were moved to the shore, and the plastic pellets were loaded inside covered the coast of Sri Lanka. With this history, the International Maritime Organization (IMO) will discuss prevention and follow-up measures for container loss during ship voyages, as an agenda at the 8th Sub Committee on Carriage of Cargoes and Containers meeting in September 2022. To establish Korea's response direction at the IMO meeting, this study identified major causes of container loss accidents, and considered the response through analysis based on the accident investigation report and related professional data. As a result, it was found that the major cause of container loss during voyages was the enlargement of container ships, bad weather, and poor loading of containers. In particular, the need to prepare countermeasures for the deterioration of the operational safety of large container ships due to bad weather was identified. Additionally, integrated monitoring of the implementation of international conventions is required, for the safe sea transportation of container cargo. In particular, in terms of preservation of the marine environment, it is necessary to supplement the system for the recovery of lost containers. Finally, it was found that it is necessary to establish systems that can complement each other in the shipbuilding and shipping industries, in terms of shipbuilding as well as ship operation, to fundamentally prevent container loss accidents at sea. It is judged that it is difficult to resolve the various factors of container loss at sea during voyages, by responding from an individual perspective.