• Title/Summary/Keyword: 표면 침투

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Study on Hydrogen Embrittlement for API 5L X65 Steel Using Small Punch Test II : Weld Metal (소형펀치 시험을 이용한 API 5L X65 강의 수소취화에 관한 연구 II : 용접부)

  • Jang, Sang-Yup;Yoon, Kee-Bong
    • Journal of Energy Engineering
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    • v.18 no.1
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    • pp.56-62
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    • 2009
  • With weld metal of X65 steel, hydrogen was charged by electro-chemical method and mechanical behavior such as strength was measured by the small punch test. The weld metal was more sensitive to hydrogen charging than the case of base metal. The small punch (SP) strength was decreased as the hydrogen contents increased. Magnitude of strength decrease was dependent on current density, temperature, charging time. Current density and charging time have significant effect on the mechanical properties but temperature of electrolyte has limited effect. Fractured surfaces of the tested specimens were observed by SEM (scanning electron microscope). In the hydrogen charged specimens cleavage fracture were observed, which is consistent with the SP test results. Since the testing procedure for studying hydrogen embrittlement proposed in this study has shown good reproducibility of test results, the proposed method can be assumed to be a reliable test procedure. Using the electrochemical charging and the small punch test, the change of SP strength for X65 weld metal due to hydrogen embritlement could be evaluated sensitively.

The effect of continuous application of the food waste composts on the paddy field environment (음식물류폐기물 활용 퇴비의 장기시용이 논 농업환경에 미치는 영향)

  • Kwon, Soon-Ik;So, Kyu-Ho;Hong, Seung-Gil;Kim, Gun-Yeob;Lee, Jeong-Taek;Seong, Ki-Seog;Kim, Kwon-Rae;Lee, Deog-Bae;Jung, Kwang-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.3
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    • pp.55-70
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    • 2009
  • The long-term effects and the soil environmental changes were examined to ensure the safety of food waste compost in agricultural use. Based on conventional nitrogen application rate of chemical fertilizer, Pig manure compost with $24g\;N\;kg^{-1}$, $8g\;P_2O_5\;kg^{-1}$, and $10.4g\;K_2O\;kg^{-1}$ and food waste compost with $20g\;N\;kg^{-1}$, $20.1g\;P_2O_5\;kg^{-1}$, and $6.5g\;K_2O\;kg^{-1}$ were applied to the paddy soil in $2{\times}2{\times}2m$ lysimeter in which paddy rice (Oryza sativa L. var Chucheong) were grown. The rice grown where food waste compost applied showed better growth responses than control, whereas less yield rate than chemical fertilizer applied. The contents of organic matter, nitrogen, and phosphorus after experiment were increased with compost applied. In addition, it improved soil aeration by the application of food waste compost, while little difference was observed in the quality of surface, infiltrated, and ground water compared to chemical fertilizer applied or control.

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Study of Adhesion Phenomena of Alkoxysilane-type Consolidants on Fresh Granites (알콕시 실란계 석재 강화제의 화강암 점착 특성 연구)

  • Kim, Eun-Kyung;Son, Seung-Hwan;Won, Jong-Ok;Kim, Jeong-Jin;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.23
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    • pp.1-10
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    • 2008
  • Consolidants based on tetraethoxysilane (TEOS) such as alkoxysilanes have been widely used for the consolidation of decaying stone heritages. Low-viscosity alkoxysilanes penetrate inside the decaying stone and polymerize within the porous structure of the decaying stone, significantly increasing the cohesion of the material. However, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force, which is typical for TEOS-based consolidants. We prepared new consolidants TEOS-based consolidants containing flexible (3-glycidoxypropyl)trimethoxysilane (GPTMS) and silica nanoparticles (or polyhedral oligomeric silsesquioxanes (POSS)) in order to reduce capillary force development during gel drying. Since the consolidants should have a good interaction with the component of the stone in order to connect the isolate grains of decaying stone, the adhesion interaction of the developed consolidants on the surface of the granite was macroscopically investigated by the ISO 2409 cross cutting test. The adhesion interaction decreased with the addition of silica nanoparticle and POSS while it increased with the addition of GPTMS in TEOS solution.

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The development of land use planning technique applying low impact development and verifying the effects of non-point pollution reduction : a case study of Sejong city 6 district (저영향개발(LID)을 적용한 토지이용계획 기법 개발 및 적용효과 분석 : 세종시 6생활권을 대상으로)

  • Kang, Ki-Hoon;Lee, Kyung-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.548-553
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    • 2017
  • The aim of this study was to develop a low impact development design technique that can be applied in the land use planning stage and verify quantitatively the effects of non-point pollution reduction. For this purpose, the low impact development design elements that can be applied in the land use planning stage were derived and applied to an actual site, and the non-point pollution reduction effect was analyzed using the LIDMOD2 program. The analysis showed that the permeability rate of the land use plan using low impact development decreased by 19.8% compared to the existing land use plan. In addition, annual surface runoff decreased by 19.0% and annual infiltration increased by 164.1%. In the case of non-point pollution, the annual loading, T-N, T-P, and BOD decreased by 18.7 ~ 22.8%. Therefore, compared to the existing land use plan, the land use plan using low impact development has a considerably large effect of reducing the non-point pollution without changing the floor area according to each application. Therefore, to maximize the reduction effect of non-point pollution, it will be necessary to establish a related plan by applying the low impact development technique from the land use planning stage to the existing LID facility-oriented plan.

A Study on Physical Properties of N-Acyl Taurates and its Suitability of Personal Care Cleaner (N-Acyl Taurates의 물성 및 인체세정제의 적합성 연구)

  • Park Ji Na;Bae Jae Hem;Lim Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.4 s.48
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    • pp.525-532
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    • 2004
  • N-acyl taurates are known as environmental-friendly and non-irritating to skin. In this study, the physicochemical properties of N-acyl taurates, which are amide-type anionic surfactants, were measured and also compared with sulfate-type anionic surfactants that show low biodegradability and are highly irritating to skin. The possibility of replacing the currently existing sulfate-type surfactants by N-acyl taurates was examined. Based on the experimental results, shampoos were formulated with these anionic surfactants and their stability and properties were measured. The possibility of application of amide-type surfactants to personal care cleaner was evaluated. Experimental results show that N-acyl taurates have various favorable aspects in making personal care cleanser: high viscosity, low surface tension, and low CMC values. These properties of N-acyl taurates generate nano-scale particles in emulsion, which is stable due to its high viscosity. This emulsion also has good cleaning ability with small amount of usage due to easy penetration into contaminants. Shampoo with N-methyl oleyl taurate showed high yield point and constant viscosity, and formed stable emulsion with nano- scale uniform particles. These results suggest that N-acyl taurates play an important role in making stable Interior structure in shampoo, and which improves the storage property.

Relationships between Airborne Droplet and Impression Diameters in Small Droplets (작은 분무입자(噴霧粒子)에 있어서 원형분무입자(原形噴霧粒子) 직경(直徑)과 살포(撒布)된 입자직경(粒子直徑)의 관계(關係))

  • Lee, Sang-Woo
    • Korean Journal of Agricultural Science
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    • v.6 no.2
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    • pp.192-197
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    • 1979
  • Spread factors were tried to determine the diameter of airborne droplet emitted: from the sprayer by the measurements of airborne droplet diameter emitted from the uniform size droplet producer and impression diameter on Kromekote card or Eucalypt's leaf in the different dilute concentration with Geigy Red Herbicide Dye from 0.5% to 2% by weight. The results abtained were as follows; The general form of the equation in the relationship between airborne droplet and impression diameter on Kromekote card or Eucalypt's leaf was an exponential equation as follows; $$Y=aX^b$$ which gave a linear relation on log-log graph paper. The spread factor seemed to be larger in the thin dilute concentration than in the thick dilute concentration. The spread factor was remarkably smaller on Eucalypt's leaf than on Kromekote card due to the penetration of liquid into the leaf and the stomata of the epidermis. The calculated equation of the mean depth of the droplet sprayed on Eucalypt's leaf was the same form as $Y=aX^b$, which implied that the spray liquid was distributed in surplus in accordance with the diameter of the droplet larger than the optimum size droplet to control insect and disease.

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Dynamic-stability Evaluation of Unsaturated Road Embankments with Different Water Contents (함수비에 따른 불포화 도로성토의 동적 안정성 평가)

  • Lee, Chung-Won;Higo, Yosuke;Oka, Fusao
    • Journal of the Korean Geotechnical Society
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    • v.30 no.6
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    • pp.5-21
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    • 2014
  • It has been pointed out that the collapses of unsaturated road embankments caused by earthquake are attributed to high water content caused by the seepage of the underground water and/or the rainfall infiltration. Hence, it is important to study influences of water content on the dynamic stability and deformation mode of unsaturated road embankments for development of a proper design scheme including an effective reinforcement to prevent severe damage. This study demonstrates dynamic centrifugal model tests with different water contents to investigate the effect of water content on deformation and failure behaviors of unsaturated road embankments. Based on the measurement of displacement, the pore water pressure and the acceleration during dynamic loading, dynamic behavior of the unsaturated road embankments with about optimum water content and the higher water content than the optimum one have been examined. In addition, an image analysis has revealed the displacement field and the distributions of strains in the road embankment, by which deformation mode of the road embankment with higher water content has been clarified. It has been confirmed that in the case of higher water content the settlement of the crown is large mainly owing to the volume compression underneath the crown, while the small confining pressure at the toe and near the slope surface induces large shear deformation with volume expansion.

Comparison of Heating Behavior of Various Susceptor-embedded Thermoplastic Polyurethane Adhesive Films via Induction Heating (다양한 발열체가 분산된 폴리우레탄 접착 필름의 유도가열 거동 비교)

  • Kwon, Yongsung;Bae, Duckhwan;Shon, MinYoung
    • Composites Research
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    • v.30 no.3
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    • pp.181-187
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    • 2017
  • The effect of nanoscopic and microscopic Fe, $Fe_3O_4$, and Ni particles and their shapes and substrate materials on the heating behavior of thermoplastic polyurethane (TPU) adhesive films was investigated via induction heating. The heat generation tendency of $Fe_3O_4$ particles was higher than that shown by Fe and Ni particles in the TPU adhesive films. When the Fe and Ni particle size was larger than the penetration skin depth, the initial heating rate and maximum temperature increased with an increase in the particle size. This is attributed to the eddy current heat loss. The heating behavior of the TPU films with Ni particles of different shapes was examined, and different hysteresis heat losses were observed depending on the particle shape. Consequently, the flake-shaped Ni particles showed the most favorable heat generation because of the largest hysteresis loss. The substrate materials also affected the heating behavior of the TPU adhesive films in an induction heating system, and the thermal conductivity of the substrate materials was determined to be the main factor affecting the heating behavior.

T 임파구와 세포성면역

  • 최철순
    • Journal of the korean veterinary medical association
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    • v.25 no.10
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    • pp.595-606
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    • 1989
  • 항원제시세포(APC)와 보조T세포 간의 협력작용에 의하여 활성화된 작동세포(NK세포, CTL, K세포, 대식세포, 과립구 등)의 종양세포, 이식장기 및 세포내기생세균에 감염된 각종 세포에 대한 세포독성작용은 생체방어를 위한 중요한 세포성면역기전이다. 지난 몇 년간 세포성면역기전에 관한 많은 연구에도 불구하고 T림파구매개성 세포독성작용의 면역생물학적기전은 확실히 밝혀있지 않다. 지금까지 알려진 중요한 연구내용을 요약하면 다음과 같다. 1. 세포독성작용을 나타내는 작동세포로는 NK세포, CTL, K세포, 대식세포/단핵구 및 과립구가 있다. 2. T세포의 세포표면항원분자군(CD)으로는 $CD_{2},\;CD_{3},\;CD_{4}[Ly_{3}T_{4}],\;CD_{5}[=Ly_{1}],\;CD_{7},\;CD_{8}[Ly_{2,3}]$가 있으며 $CD_{4}$는 보조Ttpvhdml 특이마커이고 $CD_{8}$는 세포독성 T세포 및 억압T세포의 특이마커이다. 주요 T세포수용체(TCR)는 $CD_{4}$ 또는 $CD_{8}$ 분자와 가까이 연합된 이향체($TCR-{\alpha}{\beta}/TCR-{\gamma}{\delta}$이며 보조 T세포 $CD_{4}$(마우스 $L_{3}T_{4}$)는 수용체와 연합되어 있는반면 억압 T세포 $CD_{8}(Ly+_{2,3})$는 항원수용체와 연합되어 있다. 3. T세포는 Ti-$CD_{3}$(항원/MHC) 복합체를 통한 '항원가교'에 의한 자극(항원인식)과 $CD_{2}$를 통한 비특이경로에 의하여 활성화(분화증식)된다. 비특이경로를 통한 활성경로에서 T세포($CD_{4}$$CD_{8}$)가 활성화되기 위하여는 보조T세포가 생산하는 IL-2을 요구하며 IL-2의 자극으로 분화증식된 $CD_{8}$는 세포독성능을 나타내지만 $CD_{4}^{+}$는 여전히 세포독성능을 나타내지 못한다. 4. 보조T세포는 class II MHC분자와 연합된 항원을 식별하는 반면 세포독성T세포는 class I MHC 분자와 연합된 항원을 식별한다. 5. 림파구 매개성 세포독성은 접촉(conjugati-on), 탈분극(depolarization), 용해계획(progra-mming), 용해(lysis) 및 재순환(recycling)의 단계를 거쳐 진행된다. 6. 표적세포살해매체로는 perforin / PFP / cy-tolysin, lymphopores, lymphotoxins, protone, cytolytic enzymes가 알려졌으며 세포독성작용은 이들 이외에도 여러 가지 매체를 통한 복합작용으로 추정된다. 7. CTL 매개성 표적세포의 주요 대사변화는 actomyocin ATPase의 증가, phosphocreatine과 ATPase의 소모, ATP 의존성 $Na^{+}/K^{+}$ 펌프작용의 중지, ATP 의존성 $Ca^{2+}$ 유출감소 및 세포내 축적이 관찰된다. 8. $Ca^{2+}$의 축적으로 세포막 교질 침투손상을 주어 수분의 유입을 증가시킴으로써 수포형성, 핵붕괴, 사립체팽화 및 정상세포 구조상실(Zeiosis)이 있다. 결론적으로 CTL 매개성 세포독성작용은 PFP, LT, TNF, 유사 TNF / LT 및 기타 매체를 통한 복합작용이며 세포살해기전은 지속적 대사소모와 정형적 세포구조(핵 및 세포질)의 파괴에 의한 것이다.

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Bending strength of alumina coated with bioglass and soda lime glass and the precipitation on the surface of coated alumina in PBS (생체 유리와 소다 유리침투에 따른 알루미나 세라믹의 굴곡 강도 및 PBS에서의 표면 생성물 연구)

  • Yuu, Jae-Yang
    • Journal of Technologic Dentistry
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    • v.30 no.2
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    • pp.39-45
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    • 2008
  • Titanium and its alloys are widely used as dental implants materials because of their excellent mechanical properties. However, the alumina and zirconia ceramics are preferred to use as the substitute of Ti implants because there is a problems in esthetics and biocompatibility in Ti implant. The the glass infiltrated alumina ceramics are studied to increase the toughness and biocompatibility. The 45S5 and soda-lime glass powder was mixed with ethanol at ratio of 1:1 and brushed on the surface of alumina. Then it was heat treated in the electric furnace at $1400^{\circ}C$ from 30 min. to 5 hours. The glass powder was controlled from 200 to $350{\mu}m$ using ball milling. After heat treatment, the glass infiltrated specimen was tested in universal testing machine to measure the bending strength. The surface microstructure of each specimen was observed with SEM. The biocompatibility of 45S5 and soda-lime glass coated alumina was investigated using PBS at $36.5^{\circ}C$ incubator. The specimen was immersed in PBS for 3, 5, 7, 10 days. After that, the surface morphology was investigated with SEM. As the results of experiment, the 45S5 bioglass infiltrated alumina show the increase of bending strength according to the increasing of heat treatment time from 30 min. to 5 hours at $1400^{\circ}C$ Finally the 1370N bending strength of alumina increased to 1958N at 5 hours heat treatment, which shows 1.4 times higher. In contrast to this, the soda lime glass infiltrated alumina ceramics shows the convex curve according to heat treatment time. Thus it shows maximum bending strength of 1820N at 1 hour heat treatment of $1400^{\circ}C$ It gives 1.3 times higher. However, the bending strength of soda lime glass infiltrated alumina is decreasing with increasing heat treatment time after 1 hour. The precipitation on the surface of 45S5 glass infiltrated alumina was revealed as a sodium phosphate ($Na_{6}P_{6}O_{24}6H_{2}O$) and the amount of precipitation is increasing with increasing of immersion time in PBS. In contrast to this, there is no precipitation are observed on the surface of soda lime glass infiltrated alumina. This implies that 45S5 glass infiltrated alumina brings more biocompatible when it is implanted in human body.

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