• Title/Summary/Keyword: 표면 침투

Search Result 529, Processing Time 0.029 seconds

An Experimental Study on the Resistance to Penetration of Harmful Ions in Surface Coatings Material Containing Organic Corrosion inhibitor (유기계 방청제를 혼입한 표면피복재의 유해이온 침투저항에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
    • /
    • v.17 no.2
    • /
    • pp.157-166
    • /
    • 2017
  • In general, carbonation and chlorine ions are the most harmful causes of deterioration of concrete structures. Recently, a method has been developed to control the corrosion of rebar in concrete containing chloride by impregnating a Surface coating material with a inhibitor. In this study, accelerated carbonation and differential thermogravimetric analysis (TG-DTA) and CASS tests were carried out to evaluate the characteristics of Surface coatings containing Organic Corrosion inhibitors which are excellent in corrosion inhibition and fix degradation causes $CO_2$ and $Cl^-$. As a result of the experiment, TG-DTA analysis and accelerated carbonation showed that $CO_2$ was directly reacted with amine derivative in concrete by the incorporation of Organic Corrosion inhibitor. In other words, $CO_2$ was immobilized and carbonation inhibition effect was confirmed. In addition, in the CASS test, the specimen coated with the Surface coating material containing the Organic Corrosion inhibitor with $Cl^-$ fixing property showed no corrosion until the 28th day and had excellent performance in preventing corrosion of a rebar by the chloride ion.

A Study on the Altitude Restrictions of Obstructions outside Airport Obstacle Limitation Surfaces of Korea (한국의 비행장 장애물 제한구역 밖의 장애물이 항공안전에 미치는 영향에 관한 연구)

  • Yang, Han-Mo;Kim, Byung-Jong;Kim, Do-Hyun
    • Journal of Korean Society of Transportation
    • /
    • v.23 no.6 s.84
    • /
    • pp.41-53
    • /
    • 2005
  • The effective utilization of an airport is considerably influenced by natural features and man-made structures inside and outside its boundary. These obstacles affect the airspace available for approaches and departures and the weather minima which dictates the necessary weather conditions for aircraft to be allowed to take-off or land. Certain areas of the airspace near airports must be regarded as the integral parts of the airport system. The availability of the required airspace is as important as are the runway and their associated strips to the safe and efficient use of the airport. For these reasons, ICAO and the member states have established the standards regarding the obstacle limitation surfaces and regulated the construction of the man-made structures in and beyond the surfaces. Existing objects that extend above a obstacle limitation surfaces should as for as practicable be removed except when, in the opinion of the appropriate authority, an objects is shielded an existing immovable objects, or after aeronautical study it is determined that the object would not adversely affect the safety or significantly affect the regularity of operations of airplanes. However, Korea's aviation law does not specified the outer horizontal surface in the obstacle limitation surfaces, while ICAO and most member states do. The absence of the outer horizontal surface regulation has created legal disputes between regulating agencies and private parties. The case study in this paper found that a skyscraper planned beyond Korea's obstacle limitation surfaces does affect the flight safety and the efficient use of an airport. Therefore, in areas beyond the obstacle limitation surfaces. those objects which extend to a height of 150m or more above ground elevation should be regarded as obstacle, unless a special aeronautical study indicates that they do not constitute a hazard to airplanes. We proposed low alternative regulatory schemes for resolving the issues raised in this paper, and we recommended to adopt ICAO's standards and recommended practices.

A Study on Rainfall-induced Erosion of Land Surface on Reinforced Slope Using Soil Improvement Material (지반 개량재에 의한 보강사면의 강우시 표면침식에 관한 연구)

  • Kim, You-Seong;Kim, Jae-Hong;Bhang, In-Hwang;Seo, Se-Gwan
    • Journal of the Korean Geotechnical Society
    • /
    • v.29 no.1
    • /
    • pp.49-59
    • /
    • 2013
  • Heavy rainfall intensity may cause shallow slope failures and debris flow by rill erosion and scour on land surface. The paper represents the difference between native soil (weathered soil) and reinforced soil, which is mixed by hardening agent with flyash as main material, for investigating experimental findings of rill erosion and erosion. Results obtained from artificial rainfall simulator show that erosion rate of reinforced soil mixed with hardening agent is reduced by 20% because an amount of eroded soil on slope surface is inversely proportional to the increase of soil strength. For example, rainfall of 45mm (at the elapsed time of 25mins in rainfall intensity of 110mm/hr) triggers rill erosion on native soil surface, but the rill erosion on reinforced soil surface does not even occur at 330mm rainfall (at the elapsed time of 3hrs in rainfall intensity of 110mm/hr). As a result of slope stability analysis, it was found that the construction method for reinforced soil surface would be more economical, easy and fast construction technology than conventional reinforcement method.

EFFECT OF BISCOVER ON THE MARGINAL MICROLEAKAGE OF COMPOSITE RESIN RESTORATION (복합레진 수복물의 변연 미세누출에 관한 BiscoverTM 전색제의 효과)

  • Cho, Young-Gon;Choi, Hee-Young
    • Restorative Dentistry and Endodontics
    • /
    • v.30 no.5
    • /
    • pp.355-362
    • /
    • 2005
  • The purpose of this study was to compare the effect on marginal leakage of a resin surface sealant (Biscover) applied before or after polymerization of composite resin to unsealed composite restorations. Thirty Class V cavities with the occlusal margin in enamel and cervical margin in dentin or cementum were prepared on the buccal surfaces of sound extracted molars and restored with a microfilled light-cured composite resin (Micronew). Restorations were randomly assigned into one of three equal groups (n = 10): a control group - no surface sealing, group 1 - applied Biscover after polymerization of the composite resin. and group 2 - applied Biscover before polymerization of the composite resin. Specimens were thermocycled, immersed in a $20\%$ methylene blue solution for 4 hoots, sectioned longitudinally, and analyzed for leakage at the occlusal and gingival margins. The results of this study were as follows 1. In sealed group, group 2 showed higher microleakage than group 1 at both occlusal and gingival margins. but there was no significant difference between two groups (p > 0.05). 2. Unsealed control group showed a little higher microleakage than sealed group at occlusal margins, and a little Higher or similar microleakage than sealed group at gingival margins (p > 0.05) 3. Control group and group 2 showed significantly less microleakage at the occlusal margins, but group 1 showed no significantly difference between microleakage at the occlusal and gingival margins.

The analysis for the HCl modification effect and formation of TiO2 on activated carbon fiber surface (활성탄소섬유 표면의 염산처리효과와 TiO2 형성에 관한 분석)

  • Oh, Won-Chun;Han, Sang-Bum;Bae, Jang-Soon
    • Analytical Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.279-288
    • /
    • 2007
  • We have studied a method for the preparation of $ACF/TiO_2$ composites involving the penetrationof titanium n-butoxide (TNB) solution into activated carbon fiber. It was focused on the characterization of $TiO_2$ formed in prorous carbon was which increased with surface functional groups by hydrochloric acid treatment. The conversion of TNB to $TiO_2$ for the acid treatment effect must be important for the preparationof $ACF/TiO_2$ composites. From the characterization of surface properties, both the BET surface area and the total pore volume decreased as the distribution of $TiO_2$ on the activated carbon fiber surfaces after acid treatments.The changes in XRD pattern showed the typical anatase type on $ACF/TiO_2$ composite for the sample named FT, FT1 and FT2 treated with 0.05, 0.1 and 0.5 M, respectively. However, XRD patern of FT3 treated with 0.5M showed mixed amatase-rutile structure. According to the results of SEM micrographs, the titanium complexe particles were irregularly distributed around carbon. And some large clusters were found when an amount of acid treatment increased. The EDX results of $ACF/TiO_2$ composites showed the presence of C, O and P with strong Ti peaks. Finally, the excellent photocatalytic activity of the $ACF/TiO_2$ composites between relative concentration($c/c_o$) of MB (methylene blue) and UV irradiation time could be attributed to the both effects between photocatalysis of the formation of titania complexes and adsorptivity of the activated carbon fiber.

Numerical Simulation for Evaluation the Feasibility of Using Sand and Gravel Contaminated by Heavy Metals for Dam Embankment Materials (중금속으로 오염된 사력재의 댐축조 재료 활용 가능성 평가를 위한 수치 모델링)

  • Suk, Hee-Jun;Seo, Min-Woo;Kim, Hyoung-Soo;Lee, Jeong-Min
    • Economic and Environmental Geology
    • /
    • v.40 no.2 s.183
    • /
    • pp.209-221
    • /
    • 2007
  • Numerical analysis was performed to investigate the effect of heavy metal contamination on neighboring environment in case a dam is constructed by using rockfill materials contaminated by heavy metals. The numerical simulation carried out in this research includes both subsurface flow and contaminant transport in the inside of the CFRD(Concrete Faced Rockfill Dam), using two commercial programs, SEEP2D and FEMWATER. The three representative cases of scenarios were chosen to consider a variety of cases occurring in a dam site; (1) Scenario 1 : no crack in the concrete face slab, (2) Scenario 2 : a crack In the upper part of face slab, and (3) Scenario 3 : a crack between plinth and face slab in the lower part of face slab. As a result of seepage analysis, the amount of seepage in scenario 2 was calculated as $14.31\sim14.924m^3/day$ per unit width, corresponding to the 1,000 times higher value than that in other scenarios. Also, in the simulation of contaminant transport by using FEMWATER, specified contaminant concentration of 13 ppb in main rockfill zone was set to consider continuous leakage from the rock materials. Through the analysis of contaminant transport, we found that elapsed times to take for the contaminant concentration of about 2 ppb to arrive at the end of a dam are as follows. Scenario 1 has the elapsed time of 55,000 years. In Scenario 2. it is 50 years. Finally, scenario 3 has 27,000 years. The rapid transport of the contaminant in scenario 2 was attributed to greater seepage flow by 500 times than other scenarios. Although, in case of upper crack in the face slab, it was identified that the contaminant might transport to the end of a dam within 100 years with about 2 ppb concentration, however, it happened that the contaminant was hardly transported out of the dam in other scenarios, which correspond to either no crack or a crack between plinth and face slab. In conclusion, the numerical analysis showed that the alternative usage of the contaminated sand and gravel as the dam embankment material can be one of the feasible methods with the assumption that the cracks in a face slab could be controlled adequately.

Flow Properties of Liquid Epoxy Compounds as a Function of Filler Fraction for the Underfill (Underfill용 액상 Epoxy Compound의 Filler 충진에 따른 Flow특성 연구)

  • 김원호;황영훈;배종우;정혜욱
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.7 no.2
    • /
    • pp.21-27
    • /
    • 2000
  • To develop the underfill materials which are required for the new process of semi-conductor industry, the properties of epoxy/anhydride/cobalt(II) catalyst system with two types of fused silica(1 $\mu\textrm{m}$, 8 $\mu\textrm{m}$) are studied as a function of filler fraction. According to the curing profile, the optimum catalyst amount was 1.0 wt% for full curing at the conditions of $160^{\circ}C$/l5 min., and we could conclude that the viscosity has superior effect on the real flaw through the relationship between surface tension and viscosity data. The underfills which were filled with 1 $\mu\textrm{m}$ fused silica did not show good flowability, but they should be useful by improving the viscosity for a future process which has small gaps. The underfills which were filled with 8 $\mu\textrm{m}$ fused silica showed good flowability when the filler contents were 55~60 vol%. The model which was referred by Matthew can predict the real flow length only when the underfill has high viscosity and low surface tension.

  • PDF

Performance of cement concrete pavement incorporating mineral admixtures (광물질혼화재를 적용한 시멘트콘크리트 포장의 성능 평가)

  • Lee, Seung-Tae;Lee, Da-Hyun;Lee, Jae-Jun
    • International Journal of Highway Engineering
    • /
    • v.12 no.3
    • /
    • pp.113-119
    • /
    • 2010
  • This study presents experimental findings on the performance of cement concrete pavement incorporating mineral admixtures such as ground granulated blastfurnace slag and silica fume. Flexural strength, compressive strength, charge passed, diffusion coefficient of chloride ions and initial surface absorption of cement concrete pavement incorporating mineral admixtures were periodically measured and the corresponding results were compared to those of plain concrete pavement. As a result, strength behaviors of concrete pavement were dependent on the types of mineral admixtures. However, it was true that incorporation of silica fume had a beneficial effect on compressive strength development. Furthermore, the application of mineral admixtures led to a lower diffusion coefficient of chloride ions compared to plain concrete pavement. Based on the experimental results, the present study would be helpful to design high-performance cement concrete pavement.

Thermal behavior of modified silicon surface by $CHF_3/C_2F_6$ reactive ion etching ($CHF_3/C_2F_6$ 반응성이온 건식식각에 의해 변형된 실리콘 표면의 열적 거동에 관한 연구)

  • Park, Hyung-Ho;Kwon, Kwang-Ho;Koak, Byong-Hwa;Lee, Joong-Whan;Lee, Soo-Min;Kwon, Oh-Joon;Kim, Bo-Woo;Seong, Yeong-Gwon
    • Korean Journal of Materials Research
    • /
    • v.2 no.1
    • /
    • pp.35-42
    • /
    • 1992
  • Thermal behavior of residue and damaged layer formed by reactive ion etching (RIE) in $CHF_3/C_2F_6$ were investigated using X-ray photoelectron spectroscopy(XPS) and secondary ion mass spec-trometry(SIMS) techniques. Decomposition of polymer residue film begins at $200^{\circ}C$ and above $400^{\circ}C$ carbon compound as graphite mainly forms by in-situ resistive heating. It reveals that thermal decomposition of residue can be completed by rapid thermal anneal treatment above $800^{\circ}C$ under nitrogen atmosphere and out-diffusion of carbon and fluorine of damaged layer is observed.

  • PDF

Effect of Consolidation using Artificial Porous Material for Stone Cultural Property (인공 다공질체를 이용한 석조문화재 강화제의 처리효과)

  • Lee, Jae-Man;Lee, Myeong-Seong;Kim, Jae-Hwan;Lee, Mi-Hye
    • Journal of Conservation Science
    • /
    • v.26 no.3
    • /
    • pp.325-334
    • /
    • 2010
  • In order to clarify the effect of consolidant, the artificial porous material with low intensity was manufactured using granite powder and Portland cement. We have prepared four kinds of alkoxysilane system consolidants, a acrylic resin and a epoxy resin and investigated about characteristics before and after consolidation. As a result of the research, Silres BS OH 100 was effective for density and surface hardness. SS-101 with hydrophobicity and Site SX-RO with hydrophilicity had the good durability over salts weathering. On the other hand, Syton HT-50 and Paraloid B72 were easily destructed by salt weathering because they were concentrated on surface area by the low penetration depth. Araldite 2020 was the most effective consolidant for improvement of physical properties.