• Title/Summary/Keyword: 표면 윤활

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Si 함유 다이아몬드상 카본 필름의 환경 변화에 따른 마찰거동 연구

  • 박세준;이광렬;공호성;양승호
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.126-126
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    • 2000
  • 다이아몬드상 카본(DLC) 필름은 경도가 높고, 마찰계수가 낮다는 장점을 가지고 있기 때문에 내마모성 코팅이나 윤활성코팅에 응용을 위한 연구가 활발히 진행중이다. 하지만 마찰계수가 주변환경에 매우 큰 영향을 받는다는 단점이 있다. 이러한 단점은 DLC필름의 응용에 대한 저해 요인이 되며, 이 점을 보완하기 위해서 DLC 필름에 Si을 첨가하는 연구들이 진행되고 있다. 본 실험에서는 r.f-PACVD 법을 이용하여 Si이 첨가된 DLC 필름의 주위 환경 변화에 따른 마찰특성의 변화를 연구하였다. 사용한 반응 가스는 벤젠(C6H)과 희석된 Silane(SiH4 : H2 = 10 : 90)이며, 희석된 Silane과 벤젠의 첨가비율을 조절하여 필름내 Si의 함량을 조절하였고, 증착시 바이아스의 전압은 -400V로 하였다. 마찰테스트는 Ball-on-Disk type의 조건에서 대기, 건조공기, 진공의 세가지 분위기에서 마찰테스트를 실행하였다. 실험결과 마찰계수는 건조공기, 대기, 진공의 순으로 증가하였고, 필름내에 포함되어 있는 Si의 양이 증가할수록 마찰계수는 낮고 안정한 값을 나타내었다. Tribochemiacal 분석과, ball과 track의 전자현미경 사진 분석 결과, 진공에 비해서 건조공기와 대기중에서 마찰계수가 낮은 것은 DLC 필름내에 마모 track 중심부에 Si-C-O 계의 화합물이 형성되어, 이 화합물이 마찰계면에 존재하여 마찰계수를 낮추었음을 확인하였다. 그리고 대기중에서 실험한 경우, 습기의 존재로 인해 마모입자가 볼의 표면에서 엉김으로써 건조공기의 상태에서 보다 높은 마찰저항을 갖게 됨으로 인하여 마찰계수가 높아짐을 알 수 있었다.a)는 as-deposit 상태이며, 그림 1(b)는 45$0^{\circ}C$, 60min 열처리한 plan-view TEM 사진이다.dical의 영향을 조사하였으며 oxygen radical의 rf power에 따른 변화는 OES(Optical emission spectroscopy)를 사용하였다. 너무 적은 oxygen ion beam flux나 oxygen radical은 film의 전도도 및 투과도를 저하시켰고 반면 너무 과도한 flux의 증가 시는 전도도는 감소하였고 투과도는 증가하는 경향을 보였다. 기판에 도달하는 oxygen ion flux는 faraday cup을 이용하여 측정하였으며 증착된 ITO film은 XPS, UV-spectrometer, 4-point probe를 이용하여 분석하였다. 때문으로 생각되어진다. 또한, 성장 온도가 낮아짐에 따라 AlGaN의 성장을 저해하기 때문으로 판단된다. 성장 온도 변화에 따라 성장된 V의 구조적 특성 및 표면 거칠기 변화를 관찰하여 AlGaN의 성장 거동을 논의하겠다.034, 0.005 정도로 다시 감소하였다. 박막의 유전율은 약 35 정도의 값을 나타내었으며 X-선 회절 data로부터 분석한 박막의 변형은 증온도에 따라 7.2%에서 0.04%로 감소하였고 이 이경향은 유전손실은 감소경향과 일치하였다.는 현저하게 향상되었다. 그 원인은 SB power의 인가에 의해 활성화된 precursor 분자들이 큰 에너지를 가지고 기판에 유입되어 치밀한 박막이 형성되었기 때문으로 사료된다.을수 있었다.보았다.다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품

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Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part 1) (저분자 유기실리콘 계면활성제의 개발 동향 (제1보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.66-82
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    • 2017
  • Organosilicone-based surfactants consist of hydrophobic organosilicone groups coupled to hydrophilic polar groups. Organosilicone surfactants have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, trisiloxane surfactants, having low molecular weight organosilicone as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of trisiloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review covers the synthetic schemes of reactive trisiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive trisiloxanes to hydrophilic groups, and the synthetic schemes of the main trisiloxane surfactants including polyether-, carbohydrate-, gemini-, bolaform-, double trisiloxane-type surfactants.

A case study on the bolt failure of the moving parts of a marine diesel engine (선박용 디젤기관의 운동부 볼트 손상사례에 대한 연구)

  • Kim, Jong-Ho;Lee, Jae-Hyun
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.1
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    • pp.118-124
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    • 2017
  • To investigate and analyze the cause of the failure of the connecting rod bolt and the crank pin bearing bolt of the diesel engine of this study, the following results were obtained through site surveying, the investigation of literature referring to similar failures, testing and inspection of the fracture surface, and the experience of the researchers. The fractured crank pin bearing bolt of the diesel engine is estimated to be damaged later than the connecting rod bolt. From the shape of fracture surface, it is evident that the failed connecting rod bolt is fractured by fatigue failure due to abnormally repeated loads (e.g. loosening of the connecting bolt, etc.), and is not failed by brittle fractures due to the impact load. The surface of the U-nut on the fractured connecting rod bolt has been worsening due to the improper use of lubricant (agent for prevention of thread fixing) and no usage of separating the each connecting rod on each cylinder. Moreover, there is the possibility that those poor surface conditions of the fractured connecting rod bolt have affected the failure of the connecting rod bolt of the main engine. And it could be assumed that the mechanical characteristic and manufacturing process of the failed connecting rod bolt and crank pin bearing bolt, which were made by a domestic company, conform to the design requirements for those bolts.

Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part II) (저분자 유기실리콘 계면활성제의 개발 동향 (제2보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.461-477
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    • 2017
  • Organosilicone-based surfactants, consisting of hydrophobic organosilicone groups coupled to hydrophilic polar groups, have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, organosiloxane surfactants, having low molecular weight siloxane as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of low molecular weight siloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review includes the synthetic schemes of reactive tetrasiloxanes and disiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive tetrasiloxanes or disiloxanes to hydrophilic groups, and the main synthetic schemes of the tetra- and di-siloxane surfactants having polyether-, carbohydrate-, gemini-, bola-type surfactant structures.

Air Fluid Analysis between Porous PE-Plate and Glass in Air-Floating FPD Conveyor System (공기부상 FPD 이송장치에서 다공질판과 글래스 사이의 공기유동 해석)

  • Lho, Tae-Jung;Shon, Tae-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.4
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    • pp.878-885
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    • 2008
  • The FPDs(Flat Panel Displays) such as LCD(Liquid Crystal Display) and PDP(Plasma Display Panel) and OLED(Organic Light Emitting Diode), recently, have been substituted for CRT(Cathode Ray Tube) displays because they have a convex surface, small volume, light weight and lower electric power consumption. The productivity of FPDs is greatly dependent on the area of thin glass panel with 0.6 - 0.8mm thickness because FPDs are manufactured by cutting a large-scaled thin glass panel with patterns to the required product dimensions. So FPD's industries are trying to increase the area of thin glass panel. For example, the thin glass panel size of the 8th generation is 2,200mm in width, 2,600mm in length and 0.7mm in thickness. The air flows both in the thin glass panel and in the porous PE-plate surface were modeled and analyzed, from which a working condition was estimated. The thin glass panel on the porous PE-plate surface with self-lubricating characteristics was investigated and compared with that on the square duct floating bar surface with many holes of 1mm diameter when the thin glass panel contacts the floating bar surface due to malfunction of electric power supply.

Study on the Durability of Composite Tilting Pad Journal Bearing for Turbo Compressor System under Oil-cut Situation (터보 컴프레셔용 복합재료 틸팅 패드 저널 베어링의 오일 공급 중단 상황에서의 내구성 연구)

  • Choe, Kang-Yeong;Jung, Min-Hye;You, Jun-Il;Song, Seung-A;Kim, Seong-Su
    • Composites Research
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    • v.29 no.3
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    • pp.111-116
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    • 2016
  • The tilting pad journal bearing for the turbo compressor application has a role to support high speed and heavy loading rotor. White metal has been widely used for the bearing material but the conventional bearing is immediately suspended and induces serious serious damage to the rotor under the unexpected oil cut situation or the insufficient oil film formation. The carbon fiber reinforced composite having high specific stiffness, specific strength and excellent tribological characteristics can solve these seizure problems. In this work, the study on the durability of high thermal resistance carbon fiber/epoxy composite tilting pad journal bearing under oil cut situation was conducted. The material properties of the composite materials including tensile, compressive and interlaminar properties were measured at room and high temperature of oil cut situation. To investigate the possibility of failure of composite tilting pad journal bearing under oil cut situation, the stress distribution of the composite bearing was analyzed via finite element analysis and the Tsai-Wu Failure index was calculated. To verify the failure analysis results, the oil cut tests for the composite tilting pad journal bearing were conducted using industrial test bench.

Research Trend of Soft Magnetic Composite Materials with High Energy Efficiency (고에너지효율 연자성 복합 분말 소재의 연구개발 동향)

  • Kim, Hwi-Jun
    • Journal of the Korean Magnetics Society
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    • v.21 no.2
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    • pp.77-82
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    • 2011
  • The use of soft magnetic materials have been increasing in the various industrial fields according to the increasing demand for high performance, automatic, miniaturing equipments in the recent our life. In this study, we investigated the effect of factors on the core loss and magnetic properties of electrical steel and soft magnetic composites. Furthermore, we reviewed the major efforts to reduce the core loss and improve the soft magnetic properties in the two main soft magnetic materials. Domain purification which results from reduced density of defects in cleaner electrical steels is combined with large grains to reduce hysteresis loss. The reduced thickness and the high electrical conductivity reduce the eddy current component of loss. Furthermore, the coating applied to the surface of electrical steel and texture control lead to improve high permeability and low core loss. There is an increasing interest in soft magnetic composite materials because of the demand for miniaturization of cores for power electronic applications. The SMC materials have a broad range of potential applications due to the possibility of true 3-D electromagnetic design and higher frequency operation. Grain size, sintering temperature, and the degree of porosity need to be carefully controlled in order to optimize structure-sensitive properties such as maximum permeability and low coercive force. The insulating coating on the powder particles in SMCs eliminates particle-to-particle eddy current paths hence minimizing eddy current losses, but it reduces the permeability and to a small extent the saturation magnetization. The combination of new chemical composition with optimum powder manufacturing processes will be able to result in improving the magnetic properties in soft magnetic composite materials, too.

Study on Analysis of Transfer Torque and Improvement of Transfer Torque in Non-Contact Permanent Magnet Gear (비접촉 영구자석 기어의 전달토크 분석 및 전달토크 향상에 대한 연구)

  • Park, Gyu-Sang;Kim, Chan-Ho;Kim, Yong-Jae
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.181-188
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    • 2015
  • The non-contact permanent magnet gear has advantages of high efficiency and improved reliability. It has other advantages of no mechanical friction loss, very little noise and vibration, and no need for lubricant. With these advantages, the non-contact permanent magnet gear that solves the physical contact problem of the mechanical gear has drawn attention. Due to this unique non-contact characteristic, the non-contact permanent magnet gear which is capable of non-contact torque transmission has replaced mechanical gear. The mechanical gears which is in many fields of the modern industry, is used mostly for power transmitting mechanical devices. However, it also has the problem of a low torque density, which requires improvement. In this paper, a novel pole piece shape is proposed in order to improve the problem of low torque density of the non-contact permanent magnet gear. The experiment data required for predicting the relationships among them are obtained using finiteelement Operating method based on two-dimensional (2-D) numerical analysis. Therefore, this paper derived an optimal model for thenon-contact permanent magnet gear with the novel pole piece using the Box-Behnken design, and the validity of the optimal design of the proposed pole piece shape through variance analysis and regression analysis demonstrated. In this paper, we performed the thransfer torque analysis in order to improve the torque density and power density, we have performed on optimal design of proposed pole piece shape using box-behnken.

A Study on the Corrosion Prevention of the Integral Series Generator for Military Vehicles (군용차량용 엔진일체형 직렬 발전기 부식 방지에 관한 연구)

  • Kang, Tae-Woo;Kim, Seong-Gon;Shin, Cheol-Ho;Lee, Kye-Sub
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.74-79
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    • 2019
  • The military vehicle produces electric power through an engine-integrated serial hybrid generator that is connected to the engine and does not have a separate generator installation space. However, depending on the mechanical characteristics of the connection between the generator and the engine, iron oxide for internal rusting and lubrication grew scattered. The iron oxide is adhered to the starter to deteriorate the starting performance, and there is a problem that the noise of the leg due to wear of the gear is increased. To solve this problem, the connection spline material and the surface treatment of the engine were improved and the shape was changed to a grease sealing type to prevent the generation of iron oxide inside. As the shape of the generator connector composing the shafting system was changed, the integrity of the structure was confirmed through the torsional endurance test. In addition, through the actual vehicle load test, it was verified that no corrosion occurred during the target life span without internal corrosion. It was confirmed that the anti-scattering structure of the grease effectively suppresses the generation of iron oxide, thereby reducing the noise generated from the generator. In this paper, we propose a fundamental solution to the degradation of the starter and the noise generation by preventing the back corrosion caused by the serial hybrid generator installed between the engine and the transmission.

Influence of tungsten carbide/carbon coating of implant-abutment screw on screw loosening (임플랜트 지대주 나사의 텅스텐 카바이드/탄소 코팅이나사풀림에 미치는 영향)

  • Park, Jae-Kyoung;Jeong, Chang-Mo;Jeon, Young-Chan;Yoon, Ji-Hoon
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.2
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    • pp.137-147
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    • 2008
  • Statement of problem: Dental implant procedure has been recognized as a very effective treatment to rehabilitate fully or partially edentulous patients. However, mechanical failures such as screw loosening, screw fracture have been still reported frequently. Purpose: The purpose of this study was to evaluate the influence of tungsten carbide/carbon coating, which has superior hardness and frictional wear resistance, on implant-abutment screw loosening of three different joint connections after one million cyclic loading. Material and methods: The values of detorque before and after loading were measured in three different joint connections (Osstem Implant, Korea), one external butt joint, US II implant system and two internal cones, SS II and GS II system. The values of detorque before loading was analyzed by one-way ANOVA, and two-way ANOVA and Scheffe' test were performed for the value of detorque after loading. Results: 1. The values of initial detorque of tungsten carbide/carbon coated Ti alloy screw were smaller those of Ti alloy screw (P<.01), and there were no differences among implant systems in each screw (P>.05). 2. In comparison of loss rate of detorque value after cyclic loading, US II system was greater than SS II and GS II system but there was no difference between SS II and GS II system (P<.01). 3. Loss rates of detorque value after cyclic loading decreased consistently at tungsten carbide/carbon coated Ti alloy screw comparing with Ti alloy screw in all implant systems (P<.01), and there were no differences among three systems in reduction of loss rates by using tungsten carbide/carbon coated Ti alloy screw (P>.05). Conclusion: Tungsten carbide/carbon coating to increase preload with reduction of friction resistance was a effective way to decrease screw loosening by functional loading.