• Title/Summary/Keyword: 표면 안정화

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Carbonation Treatment of EAF Slag for Using Aggregate of Concrete (EAF-Slag의 콘크리트용(用) 골재(骨材)로의 활용(活用)을 위한 탄산화(炭酸化) 처리(處理) 연구(硏究))

  • Yoo, Kwang-Suk;Ahn, Ji-Whan;Lee, Kyung-Hoon
    • Resources Recycling
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    • v.18 no.3
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    • pp.36-41
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    • 2009
  • The objectives of this study are focusing on the issue with efficiently recycling for EAF slag as construction material such as an aggregate of concrete. This study can be classified mainly into two categories: the first section is the carbonation treatment of Electric Arc Furnace(EAF)-slag for obtaining soundness as using aggregate of concrete. And the second section is the application of carbonated EAF-slag on the mortar test to evaluate the stability and mechanical property, which is compressive strength, according to the replacement of EAF-slag on the mortar. It was known that pH of EAF-Slagle according to carbonation time decreases drastically to 7 within several sec of carbonation, and a calcite is formed on the surface of EAF slag. The formation of calcite during the carbonation process of EAF slag lead to fill at pore in the texture of EAF-Slag surface, and than the porosity of EAF-slag decreases with carbonation process. In the mortar test, compressive strength, according to the replacement of EAF-Slag to sand on the mortar, the compressive strength of mortar increased as the 50% replacement ratio of EAF slag for sand was above 10% higher than that of reference mortar according to 50% replacement of EAF slag.

Effects of Plasma on the Surface of Protein Chip Plates (단백질 칩 기판의 플라즈마 효과)

  • Hyun, J.W.;Kim, N.Y.
    • Journal of the Korean Vacuum Society
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    • v.17 no.6
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    • pp.549-554
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    • 2008
  • Nickel Chloride coated protein chip plates were developed by using a spin coating method after $H_2$ plasma treatment. The adsorption ability of histidine tagged protein was investigated at various times of plasma treatment. The properties of the nickel chloride and protein on the surface of the slides were assayed using particle size analysis and the extent of the protein adsorption was determined by using a bio imaging analyzer system. The results show that the ability of protein adsorption decreased as increasing the time of $H_2$ plasma treatment. The mechanism on the ability of protein adsorption at the plate surface is discussed on results and discussions. The results also suggest that the surface stabilization of protein chip plates treated by plasma technology may be applicable in biosensor markets.

Characteristics of Ti Platinization for Fabrication Sn-modified Platinized Ti Electrode (Sn-modified Platinized Ti 전극 제조를 위한 Ti의 백금 도금 특성)

  • Kim, Kwang-Wook;Kim, Seong-Min;Lee, Eil-Hee
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.124-132
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    • 2007
  • This work investigated a fabrication way of stable platinized Ti electrode and evaluated the electrochemical characteristics of the Sn-modified platinized Ti electrode in nitrate solution. A Pt electro-plating way to form some open special clearances within the Pt coating layer on etched Ti substrate was very important to remove effectively the residual contaminate due to plating solution out of the fabricated electrode surface and to maximize the actual electrode surface area contacting solution. Both boiling and electro-cleaning processes of the fabricated electrode was essential to obtain a stable platinized-Pt electrode with reproducible and stable surface property which was necessary for the correct evaluation of Sn coverage on the electrode. The electro-cleaning caused a morphology change of the platinized Ti electrode surface with some downy hair-like polyps formed during the deposition disappearing, which made the electrode stable. The Sn-modified platinized Ti electrode in this work showed the best electro-activity for nitrate reduction, when it was fabricated through the Pt electro-plating of about 30 minutes.

A Study on the Temperature Characteristics and Flame Stabilization of Surface Combustor using the Metal Fiber (메탈화이버를 이용한 표면연소기의 화염안정화 및 온도특성에 관한 연구)

  • Lee, Jin-Seok;Lee, Young-Hoo;Yun, Bong-Seok;Lee, Do-Hyung
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.92-97
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    • 2002
  • By changing the excess air ratio which affects strongly to the combustion characteristics, the flame stability range in the metal fiber burner were found and the range of the blue flame male and radiant mode were distinguished by direct photography. The results in our experiments for the flame stability zone were from a=1.4($354 KW/m^2$) to a=2.06($240 KW/m^2$), and then the blue flame mode zone was form a=1.87($266 KW/m^2$) to a=2.06($240 KW/m^2$) and the radiant mode one was form a=1.4($354 KW/m^2$) to a =1.78($278 KW/m^2$). And the flame was not fired when a is less than the lean condition a=2.45($202 KW/m^2$).

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Reduction of perchlorate in aqueous solution using zero valence iron stabilized with alginate bead (알지네이트 비드를 이용하여 안정화한 0가 철의 수용액 상에서의 과염소산 이온의 환원 분해 특성)

  • Joo, Tae-Kyeong;Lee, Jong-Chol;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.23 no.6
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    • pp.560-565
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    • 2010
  • Perchlorate ion ($ClO_4^-$) has been widely used as oxidizing agent in military weapon system such as rocket and missile fuel propellant. So it has been challenging to remove the pollutant of perchlorate ion. nanoscale zero valence iron (nZVI) particles are widely employing reduction catalyst for decomposition of perchlorate ion. nZVI particles has increasingly been utilized in groundwater purification and waste water treatment. But it have strong tendency of aggregation, rapid sedimentation and limited mobility. In this study, we focused on reduction of perchlorate ion using nZVI particles immobilized in alginate polymer bead for stabilization. The stabilized nZVI particles displayed much greater surface area, and much faster reaction rates of reduction of perchlorate ion. In this study, an efficient way to immobilize nZVI particles in a support material, alginate bead, was developed by using $Ca^{2+}$ as the cross-linking cations. The efficiency and reusability of the immobilized Fe-alginate beads on the reduction of perchlorate was tested at various temperature conditions.

Real-time impact location monitoring using the stabilized Bragg grating sensor system (안정화된 광섬유 브래그 격자 센서 시스템을 이용한 실시간 충격위치검출에 관한 연구)

  • Bang, Hyung-Joon;Hong, Chang-Sun;Kim, Chun-Gon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.7
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    • pp.37-42
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    • 2004
  • In order to monitor the impact locations in smart structures, multipoint ultrasonic sensors are to be employed. In this study, a multiplexing demodulator with wide dynamic range was proposed to detect the impact locations using FBG sensors, and a stabilization controlling system was also developed for the maintenance of maximum sensitivity of sensors. Two FBG sensors were attached on the bottom side of the aluminum beam specimen and low velocity impact tests were performed to detect the one-dimensional impact locations. As a result, multiplexed in-line FBG sensors could detect the moment of impact precisely, and found the impact locations with the average location error below 0.58mm.

Effect of Stabilization Conditions on the Microstructure and Electrochemical Properties of Melt-blown Graphite Fibers Prepared from NMP (NMP로부터 제조된 Melt-blown흑연섬유의 안정화조건에 따른 미세구조와 전기화학적 특성)

  • Kim Chan;Yang Kap Seung;Ko Jang Myoun;Park Sang Hee;Park Ho Chul;Kim Young-Min
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.104-108
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    • 2001
  • Naphthalene derived mesophase pitch WP) was spun into short fibers by using melt-blown technology. The pitch fibers oxidative stabilization were carried out heating rates of $2^{\circ}C/min,\;5^{\circ}C/min\;and\; 10^{\circ}/min$. The heating rate was a key factor to maximate the capacity of the Li-ion secondary battery through controlling the morphology of the graphitized fiber. The diameters of the melt-blown fibers prepared were in the range of $4{\mu}m\~16{\mu}m$ with functions of air jet speed, air temperature and the temperature of the nozzle. The graphitized fibers of $10{\mu}m$ diameters showed various morphological structure with heating rate of the stabilization. Radial, radial-random and skin-core cross-sectional structure of the fibers were observed at the respective heating rate of $2^{\circ}C/min\;5^{\circ}C/min\;and\;10^{\circ}C/min$. Most crystalline structure of graphite was obtained from the fiber stabilized at heating rate of $10^{\circ}C/min$ exhibiting the best anode performance with 400 mAh/g of capacitance and $96.8\%$ of charge/discharge efficiency.

Stabilizing Properties of SiOF Film with Low Dielectric Constant by $N_2O$ Plasma Annealing ($N_2O$ 플라즈마 열처리에 의한 저유전율 SiOF 박막의 물성 안정화)

  • Kim, Yoon-Hae;Lee, Seok-Kiu;Kim, Sun-Oo;Kim, Hyeong-Joon
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.317-322
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    • 1998
  • The stabilization of low dielectric constant SiOF films prepared by conventional PECVD using TEOS and $C_2F_6$ was evaluated by the $N_2O$-plasma post-deposition annealing. Properties of SiOF film became unstable when it was air-exposed or heat-treated. Water absorption of SiOF films was increased as F content was increased due to the for¬mation of F -Si- F bonds. Also F content of SiOF films decreased after heat treatment. $N_2O$-plasma post-deposition annealing was proved to be effective on stabilizing SiOF films. which was mainly due to the formation of thin SiON layer near the top surface of films. However. the value of dielectric constant was greatly increased again when $N_2O$-plasma post-deposition annealing was done for a long time. To stabilize the SiOF films without an increase of dielec¬tric constant by $N_2O$- plasma post-deposition annealing. the annealing time should be kept the minimum value. to which stabilizing effects against air environment and heat treatment were preserved.

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Experimental Study of Desalting Methods Using Ethyl Alcohol for Archaeological Cast Iron Objects (에틸알코올 용매를 이용한 주조철제유물의 탈염 실험 연구)

  • Lee, Hye Youn;Cho, Ju Hye
    • Journal of Conservation Science
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    • v.31 no.2
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    • pp.95-104
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    • 2015
  • Excavated archaeological cast iron objects in improper storage are quickly corroded and disintegrated into block and powder finally. Hence desalination treatment which is a way of removing internal corrosive factors, especially chloride ion, is an important process. But desalination is often omitted or objects are dehydrated by alcohol because the destruction of objects could occur during desalting. Although current desalting methods mostly use an aqueous alkali solution, $OH^-$ ions of water could accelerate corrosion and broaden internal cracks cause of high surface tension. Therefore this study experimented desalting using ethyl alcohol, which is low surface tension, to investigate an effect of desalination. As a result, desalting using ethyl alcohol showed the similar or more effective results of desalting using water. In addition, as aspects of desalting safety, ethyl alcohol desalting method was smaller destruction of objects and extraction of Fe from the objects than the aqueous alkali solution. However, this study explored the possibility of desalting methods using organic solvent in fieldwork, so the results would provide basic date for making the safe and effective desalting method for archaeological cast iron objects through further experiments.

Studies on Photoprotection of Walnut Veneer Exposed to UV Light (자외선 노출에 의한 Walnut 베니어의 광 변색 방지 연구)

  • Park, Se-Yeong;Hong, Chang-Young;Kim, Seon-Hong;Choi, June-Ho;Lee, Hyo-Jin;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.3
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    • pp.221-230
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    • 2018
  • The purpose of this study was to evaluate the effect of several chemical treatments to prevent photodegradation of wood veneer by external UV (Ultraviolet) light. Of woods, walnut veneer is selected as a raw material for this study since it is known as a luxurious wood with dark color giving an esthetic effect. Alcohol-benzene, hydrogen peroxide ($H_2O_2$) and sodium hypochlorite (NaClO) solution were used for investigate the effect on color stabilization. Despite the removal of the extractive compounds, which is known as a discoloration component, a significant color change of walnut wood veneer was observed. Meanwhile, the veneers treated by 20 and 30% $H_2O_2$ solution at $75^{\circ}C$ for 1 h also showed the no positive effect of color stability exposed to UV light although they have a bleaching effect on wood veneer. Besides, it was difficult to maintain the original color of walnut veneer due to the elution of the extractive compounds. On the other hands, the veneer treated by NaClO solution indicated the good performance on color stability despite of the intensive UV light test. However, when the concentration exceeds 3%, surface roughness and fiber damage occurred simultaneously. Therefore, the walnut species should be treated with proper concentration when sodium hypochlorite is applied to the veneer.