• Title/Summary/Keyword: 표면저항

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Interfacial Control of Multi-functional CNT and ITO/PET Nanocomposites having Self-Sensing and Transparency (자체-감지능 및 광투과도를 지닌 CNT 및 ITO/PET 다기능성 나노복합소재의 계면 조절 연구)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Gu, Ga-Young;Park, Joung-Man
    • Composites Research
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    • v.24 no.1
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    • pp.45-50
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    • 2011
  • Transparent and conductive carbon nanotube on polyethylene terephthalate (PET) were prepared by dip-coating method for self-sensing multi-functional nanocomposites. The changes in the electrical and optical properties of CNT coating mainly depended on the number of dip-coating, concentration of CNT solution. Consequently, the surface resistance and transmittance of CNT coating were sensitively controlled by the processing parameters. Surface resistance of CNT coating was measured using four-point method, and surface resistance of coated CNT could be better calculated by using the dual configuration method. Optical transmittance of PET film with CNT coating was evaluated using UV spectrum. Surface properties of coated CNT investigated by wettability test via static and dynamic contact angle measurement were consistent with each other. As dip-coating number increased, surface resistance of coated CNT decreased seriously, whereas the transmittance exhibited little lower due to the thicker CNT networks layer. Interfacial microfailure properties were investigated for CNT and indium tin oxide (ITO) coatings on PET substrates by electrical resistance measurement under cyclic loading fatigue test. CNT with high aspect ratio exhibited no change in surface resistance up to 2000 cyclic loading, whereas ITO with brittle nature showed a linear increase of surface resistance up to 1000 cyclic loading and then exhibited the level-off due to reduced electrical contact points based on occurrence of many micro-cracks.

Effect of Fe content on the contact resistance of electroplated Au-Fe alloy layers (Au-Fe합금 도금층의 접촉저항에 미치는 Fe함량의 영향)

  • Park, Hyeon-Sun;Son, In-Jun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.350-350
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    • 2015
  • 본 연구는 Fe함량에 따른 Au-Fe합금 도금층의 접촉저항을 알아보는 것이 목적이다. 이를 위해 Fe함량을 다르게 하여 Au-Fe합금 도금층을 가진 시편을 제작하고 열처리를 실시한 후 접촉저항을 비교하였다. 그 결과 Fe함량이 증가할수록 접촉저항이 증가하는 것을 알 수 있었다.

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Corrosion resistance of gallium-doped zinc oxide film depending on the hydrogen content (수소가스 함유량에 따른 Gallium-doped Zinc Oxide(GZO) 박막의 내식성 평가)

  • Jo, Su-Ho;Choe, In-Gyu;Kim, Sang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.188-188
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    • 2016
  • GZO 박막은 상업적으로 사용되는 ITO를 경제적으로 대체할 수 있는 유망한 투명 전도 물질이며, 인체에 무해하고, 공급이 쉬우며, 화학적으로 안정하다. 특히, CIGS와 같은 광전변환 소자 전극에서는 부식 저항이 매우 중요한데, 습한 환경에서 견뎌낼 수 있다는 장점이 있다. GZO는 3가 갈륨이 2가 아연에 도핑된 n타입의 반도체 물질이다. 그리고 육각형의 황화아연 물질의 전기 전도도는 산소 결핍에 매우 의존한다. GZO의 수소는 산소 결핍 집중에 영향을 끼친다. 따라서 이 연구에서는 RF 마그네트론 스퍼터링 실험 동안 수소 함유량을 다양화 시키고, 면 저항, 광 투과도, 부식저항의 효과를 조사한다. 수소량이 증가할수록, 면 저항은 향상되어지고, 특정 지점을 넘으면 감소한다. 분극 실험에 의해 측정되어진 부식 저항은 박막의 미세조직과 결정립계의 특성에 더 의존되어진다. 훨씬 더 많은 수소를 함량한 비정질이 부식 저항성에 있어서 유효한 차이를 나타내지 못하는 동안 결정 내에서 많은 수소를 지닌 작은 결정의 결정립계는 낮은 분극저항, 즉 낮은 부식 저항성의 결과를 도출한다.

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Surface Resistance of Antistatic Agent Using Lithium-Fluoro Compound and Quaternary Ammonium Salt and Characteristics Evaluation of Antistatic Film (리튬 불소계 화합물과 4차 암모늄염을 사용한 대전방지제의 표면저항 및 대전방지필름의 특성 평가)

  • Soh, Soon-Young;Chun, Yong-Jin;Lee, Jae-Kyeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.575-581
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    • 2020
  • A colorless antistatic agent was prepared for use in antistatic films for liquid crystal displays (LCDs) requiring low surface resistance and high transmittance. Among various lithium-fluoro compounds and quaternary ammonium salts, antistatic materials were selected based on their electrical conductivity, and antistatic agents were prepared to measure the surface resistance. As a result, the material with high conductivity showed a relatively low surface resistance, i.e., relatively good antistatic performance. Based on the antistatic materials selected, the formulation ratio for producing the best antistatic agent was established through the experimental design method and the effects of each factor were analyzed. The higher the use of lithium- fluoro compounds as antistatic materials, the higher the ratio of oligomer use with multi-functional groups, and the smaller the surface resistance. The quaternary ammonium salts increased the antistatic performance of the lithium-fluoro compounds, but the effects of the amount used were not relatively large. After manufacturing the antistatic PET film, the properties of the antistatic film showed low surface resistance values (<109 Ω/sq.), high permeability (>92%), low haze (<0.5%), and high whiteness (L>95). In addition, the antistatic film reliability was found to be excellent by showing a stable surface-resistance change rate of less than 10%, even under high temperature and high humidity conditions.

Characteristics of Thin Film Electric Resistance Probe Prepared at Various Sputtering Condition (박막형 전기저항식 부식속도 측정 센서의 금속층 증착조건에 따른 전기화학적 특성 변화)

  • 방일환;원덕수;송홍석;장상엽;이성민;고영태;김지영
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.05a
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    • pp.95-95
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    • 1998
  • 현장에서 부식속도를 측정하는 방법의 하나인 전기저항 프로브(Electric Resistance Probe, ER probe)는 시편이 부식되는 양에 비례하여 저항이 증가하는 원리를 이용한 것으로 부식기구에 무관하게 직접적인 부식속도의 측정이 가능하다. 그러나, 와이어나 판형으로 기계 가공된 프로브로 제작되어 미량의 부식에는 저항변화폭이 작아 긴 측 정시간이 필요하고, 특히 국부 부식의 경우 부식이 상당히 진행되더라도 전체 저항변 화가 크지 않은 문제점이 있다. 박막형 전기저항프로브는 미량의 부식에서도 저항변화폭이 크게 나타나도록하기 위 하여 금속 박막을 스퍼터링으로 증착하여 동일 부식량에서 저항 변화율을 크게 향상 시킨 프로브이다. 이 프로브는 좁은 선폭(O.25-1mm)의 세선을 복수개 포함한 형상으로 프로브를 설계하여 핏팅이 발생하면 하나의 세선이 끊어지도록 하여 국부적인 부식이 일어날 경우에도 저항변화가 크게 나타나도록 고안되었다. 탄소강의 경우 일반적인 환경에서는 부식속도가 결정립의 크기, 가공경화의 정도등 에 민감하게 변화되지 않는 것으로 알려져 있으나, 박막으로 증착되었을 경우에는 별 크재료와는 전혀 다른 미세구조를 가지므로 벌크의 부식거동과는 다른 거동을 보일 수 있다. 이 연구에서는 증착조건을 달리하여 증착된 철 박막의 결정성, 비저항, 표면 상태, 조성등을 4 point 프로브, SEM, Auger spectroscopy등을 이용하여 조사하고 각각의 전위, 부식속도등과의 상관관계를 조사하였다. 증착된 박막의 비저항은 증착중 혼입된 산소의 양에 따라 매우 민감하게 변화하였다. 산소가 l0at%이상 함유된 철은 강의 알려진 비저항보다 수십배 높은 비저항을 보이며, 부식전위가 높아지고 실제 부식속도 또한 매우 낮게 나타났다. 박막의 부식거동은 미량 불순물에 의해서도 크게 변화하였는데 동일한 수준의 비저 항을 갖는 철 박막에서도 99.9% 순도의 철을 타켓으로 하여 증착된 막은 일반 저탄소 강을 타켓으로 하여 증착된 막보다 훨씬 낮은 부식속도를 보였다.

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Addition of nano particle to increase the cavitation resistance of urethane (나노입자 첨가를 통한 우레탄수지의 캐비테이션 저항 향상)

  • Lee, Iksoo;Kim, Nackjoo;Pak, Daewon
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.679-687
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    • 2014
  • In this study, a new paint which is able to resist the cavitation erosion is tried to be developed by using urethane added with nano particles such as multi-wall and single-wall carbon nano tube and spherical and fiber type graphite. The new paint synthesized was characterized with physical properties and resistivity to cavitation erosion($t_{50}$). Among nano particles, fiber type graphite($t_{50}$ 292min) showed high hardness and wear resistance compared with spherical type($t_{50}$ 182min). For carbon nano tube, single-wall type($t_{50}$ 286min) was higher than multi-wall type in wear resistance. Fiber-type graphite was the best nano-particle for paint with resistivity to cavitation erosion. In the application test of paint, the manually painted sample showed surface with smooth but the surface of sample prepared with spray was not smooth. During spray, dust was fixed on the surface.

Study of the Cavitation Erosion Mechanism and Erosion Resistance on the Dispersion Strengthened Stainless Steel by Solid Particle Collapse (고체입자충격에 의한 분산강화 스테인리스강의 침식메커니즘 및 침식저항성 고찰)

  • Han, Byeong-Seon;Hong, Seong-Mo;Lee, Min-Gu;Park, Jin-Ju;Lee, Sang-Hun;Lee, Chang-Gyu
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.29-29
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    • 2007
  • 본 연구에서는 분산강화 스테인리스강을 이용하여 케비테이션 발생 시 고체입자충격에 의한 재료의 침식메커니즘 및 침식저항성을 고찰하고자 하였다. 케비테이션 시간에 따른 침식저항성 측정결과, 기존재료에 비해 분산강화된 시편의 무게손실량이 낮았으며 침식잠복기가 짧고 침식속도가 낮아 전반적으로 우수한 저항성을 보였다. 이것은 침식표면의 손상메커니즘 관찰을 통해 확인할 수 있었다.

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Effect of Composite Re-bars Embedded in Concrete on Surface Electrical Resistivity of Concrete (콘크리트내 섬유복합체 보강근이 표면저항치에 미치는 영향)

  • Moon, Do Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.6
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    • pp.212-218
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    • 2011
  • The effect of composite reinforcing bars on surface electrical resistivity of concrete was investigated through experimental program. The resistivity was measured by Wenner method using an equipment with 4 probe. Ordinary steel, GFRP, and CFRP reinforcing bars produced domestically were used and a specimen with no reinforcement was tested for the comparison. This investigation is motivated from the fact that measured value of resistivity of concrete is significantly affected by details of steel reinforcements, such as location, depth and direction of the internal steel reinforcement. These results could be valuable data for evaluation of corrosion degree of concrete structures reinforced or strengthened by the composite reinforcing bars.

A Study on the Deposition of Tin Oxide Resistance Films through the Chemical Vapour Reaction Process (산화석 금속피막저항기에 관한 연구)

  • 정만영;박계영
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.4 no.1
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    • pp.3-12
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    • 1967
  • This study has been endeavored to deposit resistance films of tin oxide on the cylindrical Pyrex glass rods. In this report, at first an outline of the film formation is described and later some electrical properities of the resistance films manufactured through new method is discussed in detail. Because the new method which is called, "Chemical Vapour Reaction Process", is not only easy to get stable resistance films, but also doesn't need vacuum systtem, it seems to be a promising fundamental process to go into flow system mass production. Electrical properties of resistance films made by the new mathod are similar to or surpassing those by provious method (for example splay method). The top data thus obtained shows that surface resistivity is 25ohm/sq. with 12 ppm in temperature coefficient of resistor. resistor.

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Surface Resistance and Tensile Strength of Polyester Resin by Anti-static Agents (대전방지제에 의한 폴리에스테르 수지의 표면저항과 인장강도 특성)

  • Lee, Jeon-Kyu;Choi, Hwan-Oh;Kim, Eun-Bong;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.638-642
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    • 2010
  • In order to develope anti - static polyester resin which may be employed to dangerous circumstance with high organic vapor content, the effect of anti - static agents on the surface resistance and tensile strength of polyester resin were studied. Three organic anti - static agents and a conductive carbon black were adapted and used separately and together. The effects of anti - static agents, their contents, and synergic effect of anti - static agents were experimentally examined. Surface resistance and tensile strength of the polyester resin were decreased with the content of anti - static agents, and polyester resin with low surface resistance and relatively high tensile strength could be prepared by synergic effect of organic anti - static agent and carbon black.