• Title/Summary/Keyword: 표면변색

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Oxidation Behavior of STS Series at High -Temperature/Stagnation/Oxidizer-Rich Environment (고온/정체/산화제 과잉 환경에서 STS 계열의 산화 거동)

  • Shin, Donghae;Lee, Seongmin;Lee, Hijune;Ko, Youngsung;Kim, Seonjin;So, Younseok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.843-848
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    • 2017
  • Metal exposed to high temperature/high pressure/oxidizer-rich environment may cause rapid oxidation(ignition and combustion). In this study, a DC power supply test system that controls the temperature of specimen by supplying power to the specimen was constructed and after simulating the high temperature/stagnation/oxidizer-rich environment, the metal oxidation and ignition of STS series metal materials were evaluated. As a result, we was confirmed that the deformation (discoloration) of the selected material, the change in the surface roughness and the peeling of the metal surface were observed, and that the weight and the specimen thickness were changed. The most oxidized specimen was STS 304 and the less oxidized specimen was XM-19.

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저온 플라즈마를 이용한 바이오 메디컬 분야에의 응용

  • Park, Gan-Yeong;Kim, Gon-Jun;Lee, Hyeon-U;Yun, Ji-In;Sim, Jae-Yun;Kim, Gyeong-Tae;Kim, Gyu-Cheon;Lee, Jae-Gu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.41-41
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    • 2010
  • 상온에 준하는 저온의 플라즈마를 발생시키는 장치들이 개발되면서, 저온 플라즈마와 생체조직간의 상호작용에 대한 연구가 큰 관심을 끌고 있다. 플라즈마에서 발생되는 다량의 이온과 활성종, 그리고 UV 등이 박테리아나 세포들과 작용함으로 해서 암세포 사멸, 치아 미백, 박테리아 살균/멸균, 지혈등의 효과들이 나타나고 있으며, 이러한 효과들을 극대화할 수 있는 장치 개발과 플라즈마와 생체조직간의 상호작용 메카니즘을 규명하는 것이 중요한 이슈가 되고 있다. 나노 금입자를 암세포의 막단백질인 FAK의 항체와 결합시킨 중합체를 만들어서, 암세포 표면에 나노 금입자붙이고, 플라즈마를 조사했을 때, 나노 금입자가 부착되지 않았을 경우에 비해서, 5배이상 사멸률이 증가하였다.[1] 변색된 치아에 미백제의 주성분인 과산화수소를 도포하고, 10분간 플라즈마를 조사하게 되면, 과산화수소만 도포했을 때에 비해, 치아 표면의 색이 3배이상 밝아지는 것을 관찰할 수 있었다. 과산화수소를 플라즈마에 노출시켰을 때, 활성종인 OH의 생성이 2배이상 증가하였고, 플라즈마에 의한 OH 생성의 촉진이 치아 미백효과가 증대되는 주된 요인인 것으로 추측된다.[2] 플라즈마에서 발생되는 O, $O_3$와 같은 활성종들은 살균력이 뛰어나기 때문에, 저온 플라즈마를 의료기구의 소독/멸균에 응용할 가능성이 아주 크다. 대장균이나 구강 세균이 플라즈마 처리로 5분이내에 멸균되는 것을 확인하였고, 핸드피스와 같은 의료기구를 오염시켜서 멸균 테스트를 수행하고 있다.

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A comparative study on consolidants for bronze objects conservation (청동유물 보존처리에 사용되는 강화처리제의 특성 비교)

  • Cho, Hyun-Kyung;Cho, Nam-Chul
    • Analytical Science and Technology
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    • v.22 no.3
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    • pp.263-271
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    • 2009
  • The purpose of metal artifacts conservation is recovering the original state of objects and preventing it from further corrosion. Four different consolidants are selected that are widely used for bronze objects conservation. This study found out the characteristics of thin film by various experiments and analysis for the bronze plates coated using each solutions. After a series of analysis, resin B and V showed good coating properties. However, the evaluation point suited to this purpose are adhesive strength, stability against yellowing and corrosion resistance. Therefore, resin B of four different consolidants could expect to get the most suitable consolidation effect for consolidation purpose.

Deterioration Diagnosis and Petrogenesis for Rock Properties of the Stone Lantern in the Gwanchoksa Temple, Nonsan, Korea (논산 관촉사 석등의 훼손도 진단 및 기원암의 성인적 해석)

  • Lee, Myeong Seong;Yi, Jeong Eun;Pyo, Su Hee;Song, Chi Young;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.17 s.17
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    • pp.5-18
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    • 2005
  • Rock materials of the Stone Lantern in the Gwanchoksa temple was composed of dark grey granodiorite. This Stone Lantern is partly structural distortion as S-shape, especially, rocks of the upper supports and under the roof materials were highly deterioration due to the surface exfoliation, and strong secondary contaminations owing to the discoloration by oxidation of inserted iron plates between the rock properties, and white grey to dark black contaminants along the rain path way. Rock surface of the Stone Lantern occurred as partly green patches because of coated by algae, lichen and moss. This biological problems are need for cleaning and treatments. The Stone Lantern have to be considered to conservation method that can reduce weathering factors with long-term monitoring about environmental change for structural stability, surface degradation and mechanical weathering. Materials of the Stone Lantern and basement rocks of the area are consisted of same petrogenetic granodiotite based on occurrences, petrological and geochemical characteristics.

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A Study of Stone Cultural Heritage on Filler Status and Clinical Trials of Conservation Treatment in Cracks - Focusing on the Change in Surface of the Filler by Mixing the Talc - (석조문화재 균열부 보존처리 충전제의 현황과 임상실험 고찰 - 활석을 혼합 한 충전제의 표면변화를 중심으로 -)

  • Lee, Tae Jong;Oh, Hyeon Jung;Kim, Sa Dug;Lee, Jang Jon
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.383-393
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    • 2014
  • It is used for the epoxy resin, a mixture of various fillers conservation of cracks of the stone cultural heritage. Such as conservation treatment is need to for long-term conservation. However, field research and experiments on the conservation treatment results when included 54 cases of talc filler was confirmed that the damage, such as discoloration and cracks. The field research is talc was used to determine whether the reports and conservator interviews conducted, microscopy, ICP analysis of the samples collected from the field site. Experiments is color difference measurement and Ultrasonic measurement were arried out, and artificial weathering tests to investigate the effect of talc. As a result, lower the property of matter of the samples containing the talc. Therefore, we propose that the selection process is not allowed to use talc as the filler of stone powder filler cracks is conservation treatment.

Influence of Vacuum Cooling on Browning, PPO activity and Free Amino Acid of Shiitake Mushroom (진공 예냉처리가 포장 저장중 표고버섯의 품질에 미치는 영향)

  • Kim, Byeong-Sam;Kim, Oui-Woung;Chung, Jin-Woung;Kim, Dong-Chul;Nahmgung, Bae
    • Applied Biological Chemistry
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    • v.38 no.4
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    • pp.345-352
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    • 1995
  • The influence of vacuum cooling and modified atmospheric packaging was investigated about browning degree, polyphenoloxidase(PPO) activity and free amino acid of shiitake mushroom. During storage, surface browning was inhibited by precooling. PPO activities of shiitake mushroom was increased during storage. Especially, PPO activity was rapidly increased as surface browning was proceeded. And PVC-wrapped mushroom was lower than carton box-packed mushroom in the changes of surface browning and PPO activity. Total free amino acid contents of shiitake mushroom was 2,510 mg% at harvest, but free amino acid content of shiitake mushroom decreased consistantly during storage. Precooled mushroom had more free amino acid content than non-precooled and their contents were fluctuated by storage temperature, packaging methods and storage periods.

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Symptom of Leaf Injury and Varietal Difference to Ozone in Rice and Soybean Plant (벼와 콩의 오존 피해증상과 품종간 차이)

  • Lee, Jong-Ta;Sohn, Jae-Keun
    • Korean Journal of Environmental Agriculture
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    • v.19 no.2
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    • pp.154-159
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    • 2000
  • This study was carried out to elucidate the symptom of leaf injury to ozone and to determine varietal difference to ozone injury in rice and soybean plant. Ozone was produced by electrostatic discharge in oxygen and was monitored by UV absorption ozone analyzer. The rice leaves were spotted red and rolling leaf edge, discolored to reddish brown or yellowish white in response to ozone, and the leaves that were severely stressed were withered from the tip of leaf. The soybean ones were also discolored to lemon yellow, yellow or dark brown. The leaf injury in both rice and soybean was clearly appeared at the reverse side of leaf and in lower leaves. Milyang 23 and Nonganbyeo among rice cultivars tested were resistant to ozone, but Chucheongbyeo was resistant to it. The ratio of leaf injury was increased and chlorophyll content was decreased as the extension of ozone exposure from 2 to 8 hours in rice. Keunolkong and Danyeopkong among soybean cultivars tested showed resistant reaction to ozone, but Kwangankong and Muhankong were susceptible to it. It was observed that the soybean plants grown for 45 days after seeding were severely damaged by ozone than those of other growth stages.

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Nondestructive Deterioration Diagnosis for Wooden Ksitigarbha Triad Statues of Shinhungsa Temple in Sokcho, Korea (속초 신흥사 목조지장보살삼존상의 비파괴 손상도 진단)

  • Han, Na Ra;Lee, Chan Hee;Yi, Jeong Eun
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.93-102
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    • 2013
  • The wooden Ksitigarbha Triad Statues (Treasure No. 1749) of Shinhungsa temple in Sokcho are enshrined in the inside of the Myeonbujeon Hall. The Statues are highly damaged physical weathering which are crack and exfoliation. Also, the Statues were deteriorated by chemical and biological weathering. This study carried out nondestructive method as deterioration map, ultrasonic measurement, X-ray and endoscopy survey for deterioration evaluation and conservation plan. As a result, Ksitigarbha Statue coated by dust and various pollutants. And gold-gilt of Statue's surface has peeled off. Head part of Mudokguiwang Statue was discolored from water leak in Myeongbujeon Hall. Domyeongjonja Statue is highly damaged by insects. Result of endoscopy, there were bee hives in the inside of the Statue. Therefore, we suggest that these Statues have need to do conservation treatment on the basis of diagnostic results.

Conservation Treatment, Deterioration Assessment and Petrography of the Hongjimun Ogansumun (Five-arched Floodgates) in Seoul (서울 홍지문 오간수문의 암석기재적 분석과 손상도 평가 및 보존처리)

  • Lee, Myeong Seong;Kim, Jiyoung;Lee, Chan Hee;Kim, Yeong Taek;Han, Byoung Il
    • Journal of Conservation Science
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    • v.29 no.1
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    • pp.1-14
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    • 2013
  • The Hongjimun Ogansumun (Five-arched floodgates) is composed mainly of biotite granite, pink feldspar granite and granodiorite that are very similar with granitic rocks around the Seoul. Main damage in the floodgates was gray, yellow and predominantly white discoloration on the surface of stone blocks. All floodgates showed more discoloration in the wall than ceiling, and there were growing stalactite on the ceiling. Scientific analyses determined that the white discoloring substrates were mainly calcite. Therefore, conservation treatment was carried out to remove the substrates by using dry cleaning, high pressure cleaning and chemicals. The floodgates have been restored to good state, but it is still significantly necessary to install drainage on the top of the gates.

Characteristic of Inorganic Contaminants and Conservation Treatment Materials for the Three-Storied Stone Pagoda of Bulguksa Temple in Gyeongju (경주 불국사 삼층석탑(석가탑)의 무기오염물과 보수물질 특성)

  • Lee, Gemma;Kim, Sa Duk;Park, Sungchul;Kim, Derk Moon
    • Journal of Conservation Science
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    • v.34 no.5
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    • pp.421-431
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    • 2018
  • Analyses of the three-storied stone pagoda at the Bulguksa temple in Gyeongju were carried out in order to identify the cause for material characteristics of inorganic contaminants and conservation treatment materials. Results indicated that foreign soil or weathering soil caused yellow discoloration of the pagoda, reddish-brown contaminants were formed by goethite (FeOOH), an iron oxide mineral, and black pollutants were formed by manganese (Mn) oxide, leading to discoloration of the rock. Among the restoration materials used in the past, cement mortar could cause whitening by reacting with the external environment. The results were used as basic standards to evaluate the material characteristics of the surface contaminants and identify a set of effective conservation treatments. Nevertheless, continuous monitoring is required, as there is a high possibility of regeneration of pollutants in the future because of the continuous exposure of the pagoda to the external environment.