• Title/Summary/Keyword: 표면강화제

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Study for Recovery Silicon and Tempered Glass from Waste PV Modules (태양전지(太陽電池) 폐(廢) 모듈로부터 실리콘 및 강화(彈化)유리 회수(回收)에 관(關)한 연구(硏究))

  • Kang, Suk-Min;Yoo, Sung-Yeol;Lee, Jin-A;Boo, Bong-Hyun;Ryu, Ho-Jin
    • Resources Recycling
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    • v.20 no.2
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    • pp.45-53
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    • 2011
  • We devised a procedure for the recovery of silicon and tempered glass from waste photovoltaic (PV) modules using optimized conditions. The tempered glass was recovered without any damage using organic solvents. The surface material is removed by applying an acid solution on the surface of the PV cell. Through our proposed method, we offer a much more efficient approach for recycling solar cells with a surfactant than the conventional method. This process, we obtained pure silicon with a yield of 90% by chemical treatment with the surfactant at room temperature for 18 min. The silicon yield was characterized using an inductively coupled plasma-atomic emission spectrometer.

Conservation Treatment and Material Analysis of Amber Relics Found in the Huryeongtong of Geumsansa Temple (금산사 후령통(候鈴筒) 내 발견 호박유물의 과학적 분석과 보존처리)

  • Ham, Chul-hee;Kang, So-yeong
    • Korean Journal of Heritage: History & Science
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    • v.46 no.4
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    • pp.78-89
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    • 2013
  • For safe conservation treatment of damaged accessory relics that were unearthed, the quality of the material should be accurately identified through a nondestructive analysis and failure analysis. This study provides the basic conservational scientific data regarding material analyses and conservation treatment that were conducted for 11 relics, including amber and agate that were discovered during the repair of Geumsansa Temple's Hall of Maitreya Buddha and Left Attendant Buddhas in June 2008. An ultraviolet analysis, SEM-EDS analysis and FT-IR microscope analysis revealed that the physical and chemical characteristics of the 11 relics are the same as those of amber. It is inferred that the cracks and exfoliation of the surface of most amber relics is attributable to darkening of the color due to C=C bond oxidation. It is also assumed that cracks and exfoliation occurred from the weathered layer on the amber surface. As such, it is appropriate to engage in conservation treatment of the damaged amber relics by using $Paraloid^{(R)}$ B67 reinforcing agent that is diluted in nonpolar solvent. The greatest care is needed for future handling of organic artifacts.

Size control of Au nanoparticles by pH and effect of surface enhanced raman spectroscopy (SERS) (pH에 의한 골드나노입자의 사이즈 조절과 표면라만증강의 효과)

  • Lee, Young Wook;Shin, Tae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.379-382
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    • 2019
  • Synthesis of gold nanoparticles (NPs) made an aqueous environment via the reduction of HAuCl4 by ascorbic acid (AC) with the surfactant of polyvinylpyrrolidone (PVP). Highly monodisperse gold particles with size ranges from 4 to 20 nm were prepared in high-yield by pH control. The synthesized gold nanoparticles were analyzed for structural and optical properties using transmission electron microscopy (TEM) and UV-vis spectroscopy. In this study, we could reveal that the prepared nanoparticles exhibited efficient surface-enhanced Raman scattering (SERS) properties, and their SERS activities depends on size.

Effects of Sizing Treatment of Carbon Fibers on Mechanical Interfacial Properties of Nylon 6 Matrix Composites (탄소섬유의 사이징처리가 탄소섬유/나일론6 복합재료의 기계적 계면 특성에 미치는 영향)

  • Park, Soo-Jin;Choi, Woong-Ki;Kim, Byung-Joo;Min, Byung-Gak;Bae, Kyong-Min
    • Elastomers and Composites
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    • v.45 no.1
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    • pp.2-6
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    • 2010
  • The sizing treatments of PAN-based carbon fiber surfaces were carried out in order to improve the interfacial adhesion in the carbon fibers/nylon6 composite system. The parameter to characterize the wetting performance and surface free energy of the sized fibers were determined by a contact angle method. The mechanical interfacial properties of the composites were investigated using critical stress intensity factor ($K_{IC}$). The cross-section morphologies of sized CFs/nylon6composites were observed by SEM. As the experimental results, it was observed that silane-based sizing treated carbon fibers showed higher surface free energies than other sizing treatments. In particular, the KIC of the sizing-treated carbon fibers reinforced composites showed higher values than those of untreated carbon fibers-reinforced composites. This result indicated that the increase in the surface free energy of the fibers leads to the improvement of the mechanical interfacial properties of carbon fibers/nylon6 composites.

Development for Penetrative Performance Improving Agent to In Prevent Deterioration of Concrete Structures (콘크리트 구조물의 내구성능 저하를 방지하는 침투형 성능개선제 개발)

  • Ryu Gum-Sung;Koh Kyoung-Taek;Kim Sung-Wook;Kim Do-Gyeum
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.489-498
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    • 2005
  • Recently, the deterioration of concrete structures have been increased by the damage from salt, carbonization, freezing & thawing and the others. Therefore, the measures for the deterioration of concretes have been taken. Among them, it has been often used that surface treatment which cut off the deterioration factors of durability by protecting the surface of concrete. The water proof and repair materials for concrete mainly use organic materials such as epoxy, these materials excel in intial bonding force and resistance to chemical agents. But they cause difference in the modulus of elasticity and the rate of shrinkage and expansion of concrete, and thus result in such problems as scaling and spatting in the progress of time. Therefore in this study it develop the performance Improving agent of concrete surface that can block a deterioration cause such as $CO_2$ gas, chloride ion and water from the outside and enhance waterproofing ability by reinforcing the concrete surface when applying it to concrete structures.

Effect of Coupling Agent and Fiber Loading on Mechanical Behavior of Chopped Jute Fiber Reinforced Polypropylene Composites (황마 단섬유 강화 폴리프로필렌 복합재료의 기계적 거동에 미치는 결합제 및 섬유 Loading의 영향)

  • Rasel, S.M.;Nam, G.B.;Byeon, J.M.;Kim, B.S.;Song, J.I.
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.204-210
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    • 2011
  • In this study, Jute fibers reinforced polypropylene (JFRP) composites were manufactured by injection molding technique. In order to improve the affinity and adhesion between fibers and thermoplastic matrices during manufacturing, Maleic anhydride (MA) as a coupling agent have been employed. Untreated and treated surfaces of jute fibers were characterized using SEM and Fourier transform infrared (FTIR). Physical properties like water absorption rate were studied. Tensile and flexural tests were carried out to evaluate the composite mechanical properties. Tensile test and bending test indicated that JFRP composites show higher strength and modulus than pure PP. In addition, strength and modulus were found to be influenced by the variation of MAPP content (1%, 2%, and 3%). Tensile fracture surfaces were examined using scanning electron microscope. It ensures better interfacial adhesion between fibers and matrix by increasing the percentage of MAPP.

유리섬유/에폭시 복합절연재료의 계면 접착력 개선에 관한 연구 2

  • 김순태;황영한;박홍태;엄무수;이규철;이종호
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.434-442
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    • 1995
  • To improve dielectric and mechanical properties of insulating composite by plasma surface treatment, new plasma surface treatment process is designed with concentric and hemi-circle electrodes system. the plasma, which is generated between anode and cathode, is induced to the upper side of the electrode system and treats the surface of the insulators. The optimal surface treatment condition is that pressure : 0.5[torr], flux density : 100[gauss], discharge current : 500[mA] and treatment time : 3 minutes. The composite filled with glass cloth surface-treated by plasma shows the improvement in electric and mechanical properties, comparing non- and coupling agent treated samples.

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Freeze drying of a Wooden Comb Excavated at Shinchang-dong Wetland Site with Cetylalcohol (세틸알콜을 이용한 광주 신창동 저습지 출토 목제 빗의 동결건조)

  • Park, Youngman
    • Conservation Science in Museum
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    • v.11
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    • pp.49-52
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    • 2010
  • A wooden Comb excavated at Shinchang-dong wetland site was treated with cetylalcohol as a reinforcing agent. The conservation process was done by freeze drying the wooden artifact after substituting it with no.3 butyl alcohol and impregnating with 40wt% cetylalcohol solution. Consequently there was no noticeable surface damage. Also it showed 54% of remaining weight and a shrinkage of length 3.3%, width 2.1% and thickness 3.1%. Therefore using cetylalcohol for conservation of waterlogged archeological wood was effective dimensional stability and remaining weight.

UV Degradation Characteristics and Applicability of Coating Agent for Conservation of FRP Artifacts (FRP 작품 보존을 위한 자외선 열화 특성 및 자외선 차단 코팅제 적용 연구)

  • Han, Ye Bin;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.33 no.3
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    • pp.203-214
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    • 2017
  • This study evaluated the degradation characteristics of FRP by ultraviolet (UV) rays and applied a UV-resistant coating to prevent the degradation of the surface of these sculptures. As a result of the degradation caused by UV rays, there were slight changes in the FRP surface and contact angle. The chromaticity sharply increased in the early phase of degradation. After applying the coating to the FRP, no significant surface changes were observed. However, it had lower changes in color as compared to the uncoated specimen, so it was verified that the control of discoloration could be possible. Some changes in the gloss and contact angle were observed depending on the extent of degradation, but the UV coating agent remained relatively stable. Analysis of the infrared light spectrum showed that there were almost no chemical changes, and it could be concluded that the coating treatment prevented degradation for a certain period. This study investigated the degradation of FRP used as materials in artwork exposed to UV rays, and it was found that there was a delay in the onset of degradation in the FRP with the UV-resistant coating when compared to the uncoated FRP.

Effects of Hydrophilic Additives on the Release Rate of Protein Drugs (단백질 약물 방출속도에 미치는 친수성 첨가제의 영향)

  • Kwon, Young-Kwan;Kim, Ji-Hyeon;Yoo, Young-Je
    • KSBB Journal
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    • v.22 no.4
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    • pp.213-217
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    • 2007
  • It has been reported that hydrophobic additives generally decrease the release rate of protein drugs from drug delivery systems (DDS) and hydrophilic additives increase the release rate. In many cases, however, the addition of hydrophilic molecule is necessary for improving the stability of protein drugs. In the present work, the effects of hydrophilic additives on the release profiles, and micelle formation of protein drug formulations were investigated to develop a novel method for protein drug delivery. For model protein drug, bovine serum albumin (BSA) was employed and several hydrophilic additives were used in the release experiments. Hydrophilic additive D-sorbitol showed the lower release rates of BSA than other hydrophobic additives due to the gel strengthening ability of the additive and the optimum concentration of D-sorbitol was 3 w/v % for the retarded release rate. In addition, it was found that the addition of D-sorbitol was very effective for obtaining homogeneous and stable DDS. The results were discussed in terms of the micelle formation and the micelle structure, i.e., the differences in gel structure and the distribution of drugs in micelles.