• Elastomers and Composites
• /
• v.49 no.1
• /
• pp.31-36
• /
• 2014

Polyester polyols were synthesized by using each one mole of sebacic acid, isophthalic acid, ethylene glycol, and neopentyl glycol. The synthesized polyol had 56.6 mg KOH/g of hydroxy value and 1980 g/mole of molecular weight. From FT-IR structure analysis of polyester polyol, Hydroxy group(-OH) was observed around 3600 $cm^{-1}$, -CH shoulder of sebacic acid at 2950 $cm^{-1}$, carbony group of ester around 1730 $cm^{-1}$, and benzene ring of isophthalic ring was represented at 1600 $cm^{-1}$, 740 $cm^{-1}$. In case of polyurethane, hydroxy peak was showed at 3600 $cm^{-1}$, and -NH group around 3300 $cm^{-1}$, 1530 $cm^{-1}$. From $^1H$ NMR measurement of polyester polyol, it was found that sebacic acid was represented at 1.3, 1.5, 2.1 ppm, isophthalic acid at 7.3, 8.1, 8.7 ppm, ethylene glycol at 4.2 ppm, and neopentyl glycol at 0.8, 3.2, 3.9 ppm, respectively. In the polyurethane, it is almost the same as spectrum of polyester polyol, but showed very week peak at 7 ppm by benzene ring of toluene diisocyanate.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.02a
• /
• pp.139-139
• /
• 2013

본 발표에서는 3차원 안테나 유도 방식(3DAI)의 대기압 플라즈마 발생기술을 소개하고 그 응용에 대해 논의하고자 한다. 3DAI (3 Dimensional Antenna Induced) 방식의 가장 큰 특징은 하나의 전원 장치로 아크 발생 없이 다수의 금속 전극에서 플라즈마를 발생 할 수 있다는 특징과 3차원과 같은 높이 100 mm 이상의 큰 volume에서 플라즈마를 발생할 수 있는 기술로 그 적용을 확대할 수 있을 것으로 기대되는 기술이다. 다수의 금속 전극에서 플라즈마를 발생 시키는 기술은 대면적 처리가 가능하다는 의미이며 금속 전극을 사용한다는 것은 반 영구적 전극 사용을 할 수 있다는 의미로 해석할 수 있다. 본 연구에서는 신발 접착에 필요한 플라즈마 처리면적 350 mm, 플라즈마 발생 높이 100 mm급 3DAI 대기압 플라즈마 발생 장치를 개발하였다. 개발된 3DAI 플라즈마 기술을 이용하여 신발 재료 접착에 적용하였다. 화학 약품인 프라이머를 사용하지 않고 수성접착제를 사용하여 밑창인 고무와 중창인 IP 및 PU 등에서 모두 초기 접착 강도 1.5 kg/cm 이상, 경시 접착강도 3.5 kg/cm 이상으로 모재가 대부분 파괴되는 접착 강도를 얻었으며, 접착 수율이 99.9% 이상의 높은 생산성을 보여주고 있다.

• Elastomers and Composites
• /
• v.48 no.4
• /
• pp.276-281
• /
• 2013

Polyester type polyurethane foam modified with acrylic polyol was prepared by quasi prepolymer method. Thermal and dynamic mechanical properties of polyurethane foam were analysed by thermal gravimetric analysis(TGA) and dynamic mechanical analysis(DMA). Also, glass transition temperature was measured by differential scanning calorimeter(DSC). As acrylic polyol contents were increased, thermal stability measured by TGA was slightly decreased. Storage modulus was increased and tan delta was decreased with increasing of acrylic polyol contents.

• The Korean Journal of Rheology
• /
• v.9 no.1
• /
• pp.33-39
• /
• 1997

PCL, MDI, BD 및 DMPA를 이용, 폴리우레탄(PU)을 ionomer 및 nonionomergudxo 로 제조하였으며 이때 연질성분의 함량(SSC) 및 길이가 PU의 기계적, 동적기계적 특성은 물론 형상기억특성에 미치는 영향을 연구하였다. Ionomer는 nonionomer에 비하여 경도, 탄 성율 및 강도가 모두 우수하였으며 그 효과는 실온에서 경질성분의 함량(HSC)이 높은 PU 일수록 보다 뚜렷하였는데 이는 HSC가 증가할수록 ion 중심의 농도가 증가하며 ion 중심간 의 Coulob 력이 고온보다 실온에서 보다 큰데 기인하는 것으로 해석하였다. 반복인장하중실 험에서 ionomer는 nonionomer에 비해 회복변형이 크고 잔류변형이 작았는데 이는 ionomer 의 고무탄성율이 보다 큰 데 기인한 것으로 해석하였다. 나아가 재료의 형상기억거동은 기 본적으로 탄성율의 온도의존성에 크게 의존함을 알수있었다.

• Elastomers and Composites
• /
• v.48 no.3
• /
• pp.190-194
• /
• 2013

In this study, sebacic acid made from castor oil was used as monomer with isophthalic acid and glycols for polyester polyol synthesis. Polyurethane adhesive was synthesized from the various polyester polyol. From the result of adhesion strength test, polyester polyol made from sebacic acid showed better adhesive force than that of adipic acid due to higher cohesive energy. Branched glycol containing methyl group represented better adhesion than linear glycol. In the chain extender, adhesion strength increased going from PG, EG, BD. From the measurement of TGA, BD showed the best heat stability, and followed by PG, EG. Glass transition temperature increased in the order PG, EG, BD by the result of DMA.

• Elastomers and Composites
• /
• v.40 no.3
• /
• pp.212-221
• /
• 2005

Polyurethanes containing mesogen unit (MPU-6) were prepared from 4,4'-diphenylmethane diisocyanate (MDI) and 4,4'-bis(6-hydroxy hexoxy)biphenyl (BP-6) having flexible chain composed of 6 carbons. Intrinsic viscosities of MPU-6s were in the range of $0.23{\sim}0.56 dL/g$. The mesomorphic behaviors of MPU-6 were observed in X-ray and polarizing microscopy analysis. However, MPU-6s demonstrated a 'virtual liquid crystal' behavior, which did not exhibit mesophase on slow heating and slow cooling. MPU-6 having lower molecular weight exhibited higher crystallization rate and melting crystallization temperature due to increased mobility of polymer chains. The increased mobility of polymer chains facilitate the orientation of mesogen units that may act as a nucleating agent.

• Elastomers and Composites
• /
• v.35 no.3
• /
• pp.205-214
• /
• 2000

The polyurethane resin was prepared by the reaction of tolylenediisocyanate(TDI) and polypropyleneglycol(PPG). Physical properties of the resin were investigated experimentally. Charging catalyst before TDI-dropping induced the rapid increase of viscosity. On the other hand, charging catalyst after TDI-dropping resulted in mild stability without immoderate generation of heat on reaction. The use of phosphoric acid as catalyst led to low viscosity by restraining side-reaction such as forming of branch-chain, buret reaction and allopanate reaction, but it showed low cross-link density and slow drying. The curing speed was more influenced by structures of molecules rather than NCO/OH ratio. Including PPG 400 over 30 wt % showed excellent adhesive strength due to increase of crosslink density.

• Elastomers and Composites
• /
• v.39 no.3
• /
• pp.234-243
• /
• 2004

The elastomeric and conductive polyurethane (PU) films were prepared by poly(propylene glycol) (PPG), toluene 2,4-diisocyanate, 3-methylthiophene (3-MT) at various preparation conditions, such as the reaction time, the $FeCl_3$ concentration, the weight ratio of the 3-MT to PU and the reaction temperature for the diffusion-oxidative reaction. The conductive poly (3-methylthiophene) (PMT) layers via the diffusion-oxidative reaction of 3-MT and ferric chloride were formed by immersing the film in organic solution of $FeCl_3$/ethyl acetate. The preparation conditions greatly affected the electrical conductivity of the 3-MT/PU composite. The effects of the reaction time and temperature on morphology and surface free energy were investigated by scanning electron microscopy (SEM) analysis and contact angle measurement, respectively. The conductivity of the composite was as high as 42 S/cm.

• Journal of the Korean Institute of Landscape Architecture
• /
• v.38 no.5
• /
• pp.93-101
• /
• 2010

The demand for elastic pavement, providing comfort for pedestrians is expected to increase continuously but the lack of a standard for materials mixing ratio, that is, the optimal mixing ratio between ERDM chip and polyurethane binder, is still in a trial and error stage. This study aimed at recommending an optimal mixing ratio for elastic landscape pavement through a coherence and resilience test depending on ratio. The test result is outlined as follows. In a tensile strength test, samples B and C indicated a close positive relationship between the binder mixing ratio and tensile strength, indicating that the higher the mixing ratio the higher the tensile strength. In a hardness test, none of samples A, B or C indicated a statistical interrelationship between the binder mixing ratio and hardness. That is, the hardness of the elastic pavement material remained unchanged, irrespective of the binder mixing ratio. In a resilience lest, Samples A and B indicated a close negative interrelation between mixing ratio and resilience, indicating that the higher the mixing ratio, the lower the resilience. Upon analyzing the optimal mixing ratio based on test results, an increase in tensile strength began to slow at a 20% mixing ratio, while resilience began to reduce rapidly at 22%, Thus the optimal range for a mixing ration appeared to be 20~22%. The outcome of this study could to provide guidance for improving the elasticity and stability of elastic pavement.

• Clean Technology
• /
• v.15 no.3
• /
• pp.172-179
• /
• 2009

The thermoplastic polyurethane waste (TPU-S) with good tensile properties, hardness, NBS abrasion resistance, specific gravity and low wet coefficient of kinetic friction was melt-blended with ethylene propylene diene monomer rubber (EPDM) with high wet slip resistance and low mechanical properties to form EPDM/TPU-S blend films, and their composition-property relationship was investigated to find the optimum composition for shoe outsole material. The properties except the wet slip resistance increased with increasing TPU-S contents in the blend. All the properties except elongation at break, specific gravity and the wet coefficient of kinetic friction in the range of $0{\sim}65\;wt%$ of TPU-S did not attain the values predicted by the simple additive rule. The optimum weight ratio of EPDM/TPU-S for the application to the typical shoe outsole material was found to be 30/70.