• Title/Summary/Keyword: 포틀랜드

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Quantitative Analysis of Mineral Composition in Porland Cement Clinker by X-ray Diffraction (포틀랜드 시멘트 클린커 광물조성의 X선구절에 의한 정량분석)

  • Chang, Se-Kyung;Rhee, Jhun;Han, Ki-Sung
    • Journal of the Korean Ceramic Society
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    • v.23 no.2
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    • pp.64-70
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    • 1986
  • In this investigation x-ray diffraction method was mainly studied for quantitative analysis of clinker mineral composition. And also optical microscopic observation and Bogue calculation method were applied to compare with the x-ray diffraction method. In the procedure of x-ray diffraction analysis graphite monochromator automatic divergence slit and spinner for sample holder were used for minimizing the error due to the operation of the equipment. Especially the separation of overlapped peaks were proceeded by micro-processor automatically. The results of x-ray diffraction method for synthesized clinker were consistent with the Bogue value and the results of optical microscopic observation. However the results of quantitative analysis of mineral composition or commercial clinker containing solid solution of minor component were different from the Bogue value. On the other hand they agreed reasonably well with results of the optical mic-roscopic observation.

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An Experimental Study on the Hydration and Mechanical Properties of High Strength Concrete with High Calcium Sulfate Cement (고황산염시멘트를 이용한 고강도콘크리트의 수화 및 역학적 특성에 관한 실험적 연구)

  • 박승범;임창덕
    • Magazine of the Korea Concrete Institute
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    • v.5 no.1
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    • pp.129-138
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    • 1993
  • 프리텐션 방식 원심력 고강도 콘크리트 말뚝[KS F 4306]제조에 관한 실험적 연구로써 고황산염시멘트를 이용한 800kg/$ extrm{cm}^2$이상의 고강도콘크리트 제조시 수화 특성검토와 콘크르트 조직내의 기공율과 압축강도간의 상관식을 도출하여 고강도 발현기구를 규명하였으며 콘크리트 압축 및 휨강도간의 상관식 유도와 내구성 측면에서의 내동해성, 건조수축, 화학저항성등을 보통 포틀랜드 시멘트와 비교 고찰한 결과, 고황상염시멘트의 내구성이 우수함을 확인하였다.

Crystallization of the Liquid Phase in Portland Cement Clinker (Effects of $K_2O$ and MgO) (포틀랜드시멘트 클링커융액의 결정화에 관한 연구($K_2O$와 MgO의 영향))

  • 한기성;문정연;김용국
    • Journal of the Korean Ceramic Society
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    • v.19 no.3
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    • pp.236-240
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    • 1982
  • The crystallization of melts with similar composition of Portland cement liquid containing 0-5% $K_2O$ was studied by differential thermal and isothermal reaction. The devitrification of melts was occured in stages, the recognizable amount of CaO was appered at the first step, then proto-C3A was crystallized. The latter showed to occur in both cubic C3A and Ca-ferrite crystallization. Batches lost remarkable amounts of $K_2O$ as a result of volatilization during melting and the solubility of $K_2O$ in the melts was unstable.

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An Experimental Study on the Quality Characteristics of Ordinary Portland Cement in Domestic Market (국내 보통 포틀랜드 시멘트의 품질특성에 관한 실험적 연구)

  • 배수호;윤상대;박광수;신의균
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.14-18
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    • 1995
  • Since cement is one of materials of concrete and have an important effect upon physical properties of concrete, the quality characteristics of ordinary portland cement in domestic market are evaluated in this study. For this purpose, eight kinds of cement are selected and tested on the specific gravity, normal consistency, setting time, fincness, and compressive strength of cement ranged from 300kg/$\textrm{m}^3$ to 600kg/$\textrm{m}^3$ are tested for each kind of cement. As a result,ordinary portland cement in domestic market are satisfied with physical performance prescribed by KS L 5201(Portland Cement) and when unit weight of cement is 300~600kg/$\textrm{m}^3$, the maximum compressive strength of concrete cylinder is showed to be about 440-540kgf/$\textrm{cm}^2$.

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Sulfate Resistance of Portland CementMatrices (포틀랜드시멘트계 경화체의 황산염저항성)

  • 문한영;이승태;김홍삼
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.714-717
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    • 2000
  • To consider sulfate resistance of cement pastes and motars for 3 types of portland cements which have different $C_3A$ contents an silicate ratio($C_3S/C_2S$), they were immersed in 5% sodium sulfate solution for 400 days. SEM analysis and ($Ca(OH)_2$ contents of cement pastes, and compressive strength and length change of cement mortars, were performed to investigate the effects of ($C_3$ and ($Ca(OH)_2$ contents. According to the results of this study, low heat portland cement pastes, and compressive strength and length change of cement mortars, were performed to investigate the effects of C3A and ($Ca(OH)_2$ contents. According to the results of this study, low heat portland cement had a good sulfate resistances because of a small quantity of gypsum and ettringite due to less ($Ca(OH)_2$ contents. However, ordinary portland cement had an adverse result. This was also confirmed by SEM analysis.

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An Experimental Study on the Early Strength Estimation of Belite Cement Concrete by Microwave Method (마이크로파 가열기법에 의한 저열 포틀랜드시멘트 콘크리트의 조기강도 추정에 관한 실험적 연구)

  • 이민경;황병준;전판근;박병근;김성식;정상진
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.1041-1046
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    • 2003
  • The most recent building trend is going large, high rise, high strength as overlarge project is developing in domestic construction business. Belite cement has properties like low heat, excellent long term strength, and durability without admixture (fly ash, silica fume). So, Belite cement is suitable for mass structure which is needed high strength, high fluidity and low heat property. This study is to examine the possibility of site adoption microwave-use early strength estimation method. Based on the existed study related the portland cement, the interrelation between Belite cement and microwave-use early strength estimation method is required.

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Effects of Soluble Alkalis on the Rheological Properties of Belite-rich Cement with Polycarbonate Superplasticizer (폴리카르복실산계 유기 혼화제를 첨가한 Belite-rich Cement의 유동특성에 미치는 가용성 알칼리의 영향)

  • 황인수;정재현;송종택
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.152-157
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    • 2001
  • 본 연구에서는 고유동, 저발열 및 고강도 특성을 발현하는 belite-rich cement(BRC)에 있어서 카르복실산계 유기혼화제를 사용했을 때 가용성 알칼리의 함량 변화에 따른 흡착거동과 유동특성에 미치는 영향성에 대해 검토하였다. BRC에서 알칼리 0.1~0.2 wt% 및 알칼리 설페이트 0.3~0.5 wt% 첨가시 슬럼프가 증가하거나 손실이 거의 없었으며, 그 이상의 함량을 첨가하였을 때 다시 유동서 저하를 가져왔다. 그러나, 보통 포틀랜드 시멘트(OPC)의 슬럼프 유지능력은 알칼리 및 알칼리 설페이트를 첨가할수록 감소되었다.

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Preparation and Properties of CSA Type Expansive Cement Using Industrial By-products (산업부산물을 이용한 CSA계 팽창시멘트의 제조 및 특성)

  • 송종택;조진상;전준영
    • Journal of the Korean Ceramic Society
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    • v.38 no.2
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    • pp.183-192
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    • 2001
  • 산업부산물을 이용하여 3CaO.3Al$_2$O$_3$.CaSO$_4$(C$_4$A$_3$S) 클링커를 합성하였다. 이때, 원료 물질은 산업부산물로 플라이 애쉬, 고로 수쇄 및 괴재슬래그를 $Al_2$O$_3$원으로 그리고 부산석고를 SO$_3$원으로 이용하였으며, CaO원으로 천연석회석을 사용하였다. 제조된 $C_4$A$_3$S 클링커를 CaSO$_4$, CaO를 배합하여 CSA계 팽창재를 제조하였으며, 일반 포틀랜드 시멘트(OPC)에 10 wt.% 첨가하여 수화 및 물성 특성을 조사하였다. 주요 수화생성상은 에트링자이트 및 수산화칼슘이었다. 수화시 에트링자이트의 생성으로 인해 팽창 및 경화체가 치밀화되어 건조수축이 감소되었고, 강도(압출, 인장, 휨)가 향상되었다.

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Microstructure and Freeze-Thaw Resistance of Portland Cement Mortars (포틀랜드 시멘트 모르타르의 미세구조와 동결융해저항성에 대하여)

  • 이종호;장복기
    • Journal of the Korean Ceramic Society
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    • v.28 no.11
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    • pp.917-925
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    • 1991
  • For the present experiment five Portland cement mortars are in order: mortars with two different water/ cement ratios (W/C=0.45 and 0.50, each having no chemical additive), and those with an additive such as superplasticizer, air-entraining agent or water-repelling agent. We fix the W/C ratio of mortars having additive so that their pastes can yield the same workability as that of the cement mortar of W/C=0.50 with no additive. It is shown that the freeze-thaw resistivity depends heavily on the characteristic of wide pores. Despite a good deal of wide pores, the air-entrained specimen shows a good freeze-thaw resistivity due to appropriate air-pores. And also the specimen with water-repelling agent, which proves to cause the microstructure to become hydrophobic, make good resistance to freeze-thaw cycles in spite of its high wide-porosity. Our suggestion is that the freeze-thaw durability of Portland cement mortar/concrete can be more effectively enhanced by using air-entraining agent or water-repelling agent, and simutaneously by taking proper measures against foaming and/or the increased tendency of wide-pore building due to additive.

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