• 에너지공학
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• 제14권1호
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• pp.18-23
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• 2005

본 연구는 저온축열물질로서 TMA(Tri-methyl-amine, (CH₃)₃N)를 20～25 wt％로 포함하고 있는 TMA-물계 포접화합물의 냉각특성에 대하여 냉열원온도 -5℃에서 실험적으로 연구를 수행하였다. 연구결과, TMA의 질량농도가 증가할수록 상변화온도와 비열이 증가하였으며, 과냉도가 감소하고 액상유지시간이 단축되었다 특히, TMA 25wt%를 포함한 TMA-물계 포접화합물은 상변화온도 평균 5.8℃, 과냉도 8.0℃, 액상유지시간 10분, 비열 4.099kJ/kg℃를 나타내었다. 본 연구의 결과로부터 TMA-물계 포접화합물은 물보다 높은 상변화온도를 나타내었으며, 과냉도가 감소하고, 액상유지시간이 단축되는 과냉각 억제효과를 확인 할 수 있었다.

• 에너지공학
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• 제14권2호
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• pp.117-122
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• 2005

본 연구에서는 TMA $25\;wt\%$-물계 포접화합물에 첨가제를 첨가하며 상변화온도, 과냉도, 비열 그리고 체적변화율의 냉각특성에 대한 실험적 연구를 수행하였다 사용된 첨가제는 에탄올 이며, 냉열원온도는 $-7^{\circ}C$이다. 실험결과들은 다음과 같다. 1) 상변화온도는 $25\;wt\%$-물계 포접화합물에 에탄올을 첨가하여 냉각과정동안 $0.32\~0.96^{\circ}C$가 상승되었다. 2) 과냉도는 TMA $25\;wt\%$-물계 포접화합물에 에탄올 $0.5\;wt\%$를 첨가한 경우에 $0.9^{\circ}C$가 억제되었다. 3) 비열은 TMA $25\;wt\%$-물계 포접화합물에 에탄올 $0.1\;wt\%$를 첨가한 경우에 $0.19\;kJ/kg^{\circ}C$가 증가하였다. 4) 체적변화율은 TMA $25\;wt\%$-물계 포접화합물에 에탄올을 첨가한 경우에 $1.15\~l.5\%$가 감소하였다.

• 대한기계학회논문집B
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• 제34권2호
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• pp.173-178
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• 2010

빙축열시스템은 저온잠열저장을 위해 물을 사용한다. 그러나 물은 액체에서 고체로 상변화를 하는 과정에서 물의 과냉각 현상에 의하여 냉동기의 냉동용량 증가와 COP감소의 원인이 되고 있다. 본 연구는 저온잠열축열물질로 적용 가능한 TMA(Tri-methyl-amine, $(CH_3)_3N$) 20~25 wt%를 포함하고 있는 TMA-물계 포접화합물(TMA-water clathrate compound)의 냉각특성에 대한 실험적 연구를 수행하였다. 실험적 연구 결과, TMA 질량농도가 높을수록 상변화온도는 증가하였고, 과냉각도와 비열은 감소하였다. 특히, TMA 25wt%를 포함하고 있는 포접화합물은 냉각과정동안 평균 상변화온도 $5.8^{\circ}C$와 과냉각도 $8.0^{\circ}C$, 액상유지시간 651sec 및 비열 3.499 kJ/kgK로서 다른 TMA 농도보다 양호한 냉각특성을 나타내었다. 이와 같이 저온잠열축열물질로서 TMA 25wt%-물계 포접화합물을 적용하는 것이 유리할 것으로 판단된다.

• 한국태양에너지학회 논문집
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• 제34권6호
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• pp.85-92
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• 2014

This study carried out experimental on the cooling characteristics of clathrate compound including TMA(Tri-Methyl-Amine ; $(CH_3)_3N$) as a low temperature latent heat storage material. And additive was used for subcooling improvement of TMA-water clathrate compound. The conclusion of above study is as following ; TMA 25wt%-water clathrate compound is shown stable phase change and low subcooling degree. The subcooling was improved in the case ethanol($CH_3CH_2OH$) 0.5wt% is added to TMA 25wt%-water clathrate compound.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2471-2475
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• 2007

Clathrate compound is the material that host in hydrogen bond forms cage and guest is included into it and combined. Crystallization of hydrate is generated at higher temperature than that of ice from pure water. And physical properties according to temperature are stable and congruent melting phenomenon is occurred without phase separation. But clathrate compound still had supercooling problem occurred in the course of phase change and supercooling should be minimized because it affects efficiency of equipment very much. Therefore, various studies on additives to restrain this or heat storage methods are needed. In this study was investigated the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of 20${\sim}$25 wt% as a low temperature latent heat storage material. And ethanol$(CH_3CH_2OH)$ was added and its cooling characteristics were studied experimentally to restrain supercooling of TMA-water clathrate compound.

• 설비공학논문집
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• 제14권8호
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• pp.634-640
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• 2002

The purpose of this study is to investigate the propriety of TMA clathrate as a cold storage medium. Particularly, this is to examine the extent of subcooling improvement when the additives is added to the TMA clathrate, because water used for cold storage ma terial has low phase change temperature and subcooling. This study has been analyzed and compared pure water with TMA 30 wt% clathrate how phase change temperature, subcooling and specific heat in the various concentrations are changed. This results prove low phase change temperature and subcooling control effect when the ethanol is added to the TMA 30 wt% clathrate than the TMA 30 wt% clathrate. In addition, it results low specific heat when there is added to the TMA 30 wt% clathrate over 0.5 wt% ethanol in the cold heat source temperature under $-7^{\circ}C$. The other side, it results high specific heat when the ethanol is added in it at the cold heat source temperature under $-5^{\circ}C$. Therefore, it is found that the additive must be controlled by available solution limit and study for new additive must be lasted to know its effect.

• 설비공학논문집
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• 제11권2호
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• pp.205-214
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• 1999

The objective of this paper is to investigate the thermal properties of TMA clathrate compound applicable to cold storage system for building air-conditioning. Especially, the test tube experiments are performed by comparing and analyzing the temperature of phase change, specific heat and subcooling characteristic according to the variation of density, temperature of heat source and charging quantity in TMA clathrate compound. The results are summarized as follows:1) $-15^{\circ}C$ is not proper as the temperature of heat source because the temperature of subcooling is above $8.3^{\circ}C$ 2) temperature of phase change is dropped as the temperature of heat source is lower, 3) the effect of subcooling suppression with about 8$^{\circ}C$ is confirmed when the temperature of heat source is $-10^{\circ}C$ in case of 26, 27, and 30wt%, while the temperature of subcooling is about $0^{\circ}C$ when the temperature of heat source is $-15^{\circ}C$ in case of 25, 26 and 30wt%. Thus, the effect of subcooling suppression is greater as the temperature of heat source is lower. Additionally, the concentrative study is needed on mass concentration causing the phase change without subcooling phenomenon when the temperature of heat source is $-15^{\circ}C$. Thus, it is concluded that TMA clathrate compound has enough thermal properties as the cold storage medium for building air-conditioning.

• 설비공학논문집
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• 제17권2호
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• pp.125-130
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• 2005

This study was peformed to investigate the phase change temperature, the supercooling, the maintenance time of liquid phase and the change rate of volume of TMA 30 $wt\% clathrate compound with additives. TMA 30 $wt\% clathrate compound with additive was cooled at heat source temperature of $-6^{circ}C$. The additives are ethylene glycol and chloroform. Their concentration are 0.1$wt\% respectively. The experimental results showed that the phase change temperature was not affected by additives and this was average $5.3^{circ}C$. Also the supercooling and the maintenance time of liquid phase were decreased by additives. Especially, the average value of supercooling showed by $8.8^{circ}C$ and the maintenance time of liquid phase was by 19 minutes in the case of chloroform 0.1$wt\%. Additionally, the average change rate of volume showed by $1.26{\~}1.31\%$ according to additives and the volume was decreased by the phase change from liquid to solid.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1746-1750
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• 2004

The objective of this study is to investigate the effect of supercooling repression on the clathrate compound by adding additives. For this purpose, phase change temperature and supercooling were measured when additives added to TMA30wt% clathrate for heat source temperature of $-6^{\circ}C$. The experimental results show that the phase change temperature with the chloroform of 0.1wt% is higher by $0.3^{\circ}C$ than TMA30wt% and the supercooling with the surfactant 0.1wt% is reduced by $9.2^{\circ}C$.

• 한국자동차공학회논문집
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• 제15권1호
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• pp.23-28
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• 2007

This study aims to find out cooling characteristics of TMA(Tri-Methyl-Amine, $(CH_3)_3N$) 25wt%-water clathrate compound with ethanol($CH_3CH_2OH$) such as supercooling, phase change temperature and specific heat. For this purpose, ethanol is added as per weight concentration and cooling experiment is performed at $-6{\sim}-8^{\circ}C$, cooling heat source temperature, and it leads the following result. (1) Phase change temperature is decreased due to freezing point depression phenomenon. Especially, it is minimized as $3.8^{\circ}C$ according to cooling source temperature in case that 0.5wt% of ethanol is added. (2) If 0.5wt% of ethanol is added, average supercooling degree is $0.9^{\circ}C$ and minimum supercooling is 0.8, $0.7^{\circ}C$ according to cooling heat source temperature. The restraint effect of supercooling is shown. (3) Specific heat shows tendency to decrease if ethanol is added. It is $3.013{\sim}3.048\;kcal/kg^{\circ}C$ according to cooling heat source temperature if 0.5wt% of ethanol is added. Phase change temperature higher than that of water and inhibitory effect against supercooling can be confirmed through experimental study on cooling characteristics of TMA 25wt%-water clathrate compound by adding additive, ethanol. This can lead to shorten refrigerator operation time of low temperature latent heat storage system and improve COP of refrigerator and efficiency of overall system. Therefore energy can be saved and efficiency can be improved much more.