• Resources Recycling
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• v.20 no.3
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• pp.12-27
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• 2011

DOWA group has been working on metal recycling applying the smelting and refining process of KOSAKA Smelter. DOWA has developed it's metal recycling technologies through the treatment of black ore(complex sulfide ores) that contain many kinds of non-ferrous metals. In addition to these special technologies, DOWA has strengthened its hydrometallurgical process of precious metals and ability to deal with low-grade materials such as used electrical appliances or vehicles. On the other hand, JX Nippon Mining & Metals Corporation(JX-NMMC) carries out its metal recycling and industrial waste treatment businesses employing advanced separation, extraction and refining technologies developed through its extensive experience in the smelting of non-ferrous metals. JX-NMMC collects approximately 100,000t/y of copper and precious metal scraps from waste sources such as electronic parts, mobile phones, catalytic converters, print circuit boards and gold plated parts. These items are recycled through the smelting and refining operations of Saganoseki smelter and Hitachi Metal-recycling complex(HMC). In this like, metal recycling industries combined with environmental business service in Japan have been developed through excellent technologies for mineral processing and non-ferrous smelting. Also, both group, Dowa and JX-NMMC, were contributed to establish Japan's recycling-oriented society as the typical leading company of non-ferrous smelting. Now. it is an important issue to set up the collection system for e-waste.

• Journal of the Korea Concrete Institute
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• v.20 no.5
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• pp.557-563
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• 2008

Recently, the amount of disposed construction materials like demolished concrete is growing fast and the shortage of natural concrete aggregate is becoming serious. Therefore, recycling of aggregate extracted from the demolished concrete is getting important and use of the recycled aggregate for concrete has been seriously considered. However, the use of the recycled aggregate even for low performance concrete is very limited because recycled aggregate which contains large amount of old mortar has very low quality. Therefore, removing the paste sticked to the recycled aggregate is very important in the manufacturing of high quality recycled aggregate. We have studied a series of research according to complex crushing method, which is removed the ingredient of cement paste from recycled fine aggregate using both the low speed wet abrasion crusher as mechanical process and the acid treatment as chemical processes. This paper is to analyze the quality of the recycled fine aggregate produced by those complex method and investigate optimum manufacturing condition for recycled fine aggregate by the design of experiments. The experimental parameters considered are water ratio, coase aggregate ratio, and abrasion time. As a result, data concerning the properties of recycled sand were obtained. It was found that high quality recycled fine aggregate could be to obtain at the condition of the fifteen minute of abrasion-crusher time and the over 1.0 of recycled coarse aggregate ratio.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.1
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• pp.75-83
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• 2004

Temperature-phased anaerobic digestion (TPAD), anaerobic sequencing batch reactor (ASBR), and co-digestion technologies were combined together in order to overcome low efficiencies of conventional anaerobic sewage sludge digestion processes. In the performance, TPAD-ASBR process showed high VS removal efficiency over 60% up to the organic loading rate (OLR) of 2.7 g VS/L/d. The first-stage of TPAD-ASBR and control system played a most significant role in VS destruction and methane production. Methane production rate (0.79 l $CH_4/L/d$) of the system was higher than that (0.59 l $CH_4/L/d$) of the control system. The substrate characteristics of the sewage sludge, such as low VS concentration (1.5%, w/w) and biodegradability, were properly improved by the addition of food waste as a co-substrate, leading to more efficient VS removal and methane production. With several track studies, it was revealed that the independent solid retention time (SRT) of those systems prevented untreated particles from outflowing and also, extended the retention time of the active biomass for further degradation. Consequently, it was confirmed that the sequencing batch operation of the TPAD process using co-substrate was a promising alternative for the recycling of sewage sludge with low VS content.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.1
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• pp.58-66
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• 2004

The purpose of this study is to examine the possibility of reuse fermented foodwaste as a bulking agent in livestock waste and foodwaste composting. Aerobic composting device was added to the following sample : Foodwaste + Sawdust, Livestock feces+Sawdust, Foodwaste + Ferment, Livestock feces + Ferment. Temperature, pH, OM/N ratio, moisture, heavy metals, and microbes were measured in process of aerobic composting. The results of this study are following. 1. The composting period is determined in 16~24days, according to the change of temperature and OM/N ratio. 2. The salinity contents in compost of livestock waste and foodwaste ferment is about 0.5%, which can be solved the problems of salinity contents in foodwaste composting. 3. The proper ratio of livestock waste composting is 40% of cow feces to 60% of foodwaste ferment. 4. Processing expense of aerobic composting of foodwaste and sawdust is 40 won/kg composting expense of foodwaste and ferment is 30 won/kg. Fermented product composting can cut down the expense of bulking agent than others.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.640-647
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• 2006

It is difficult to treat wastewater involved in heavy metal in electroplating industry. Recently, many industries adopt the clean technology to prevent production of pollutant in the process or reuse after the appropriate pollutant treatment. In this study, we estimate the ability of recovery of nickel and the efficiency using lab-scale ion exchange and electrodialysis process with electroplating industry wastewater. In the ion exchange experiments with 5 types of resin, the result showed that S 1467(gel-type strong acidic cation exchange resin) has the highest exchange capacity. And it showed that the 4 N HCl has the highest in regeneration efficiency and maximum concentration in the regeneration experiments with various kinds md concentration of the regenerant. During the electrodialysis experiments, we varied the current density, the concentration of electrode rinse solution, the flow rate of concentrate and electrode rinse solution in order to find the optimum operating condition. As a result, we obtained $250A/m^2$ of current density, 2 N $H_2SO_4$ of concentration of electrode rinse solution, 30 mL/min of flow rate of concentrate and electrode rinse solution as the best operating conditions. We performed the scale-up experiments on the basis of ion exchange and electrodialysis experiments. And we obtained the experimental result that exchange capacity of S 1467 was 1.88 eq/L resin, and regeneration efficiency was 93.7% in the ion exchange scale-up experiment, we also got the result that concentration and dilution efficiency increased, and current efficiency kept constant in the scale-up experiments.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.3
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• pp.132-137
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• 2008

The average concentrations of COD and copper in the livestock sludge are $930,726{\pm}380.801$ mg/kg and $679{\pm}341$ mg/kg, respectively. Due to the high concentrations, dumping to the sea of the sludge could pose potential adverse effects to the marine environment. On the contrary, it could have economic advantages on land as the energy of biogas generated by decomposition of organisms and the compost in case of the sludge of good quality with the abundant nitrogen and phosphorus. Nevertheless, the amount of livestock sludge dumped to the sea in Korea increased sharply from 51,000 $m^3$ in 1997 to 2,745,000 $m^3$ in 2005. And also it had the high proportion of 27% in total amount of waste dumped into the sea (7,451,000 $m^3$) in 2007. It might cost between 20,000 won and 33,000 won to dump to the sea of the sludge. In comparison, it might cost 20,000 won to com- post the sludge. And its purification treatment even might cost just 10,000 won. It means that the disposal of the sludge at sea is the most expensive method to deal with the sludge, but ranchers, who engage in the livestock industry, still prefer the disposal at sea to the other methods on land such as the compost and purification treatment. In this article, therefore, we would analyze various factors in the ranchers' preference for the disposal of the sludge at sea, and then we could suggest some legal improvements to prevent and reduce pollution of the sea.

• Journal of Biosystems Engineering
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• v.9 no.1
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• pp.62-70
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• 1984

가축배설물(家畜排泄物)의 콤포스트화(化) 작업(作業)의 공학적(工學的)인 국면(局面)은 축산(畜産) 경영(經營)의 축산물(畜産物) 생산성(生産性), 에너지 보전(保全), 공해방지(公害防止)와 분뇨처리(糞尿處理)의 노력(勞力) 절약(節約)에 긴밀(緊密)한 관계(關係)가 있다. 그러나 우리나라에 있어서 축산업(畜産業)의 사양(飼養) 규모(規模)와 두수(頭數)는 매년(每年) 증가(增加)하고 있는 경향(傾向)인바 전통적(傳統的)인 가축(家畜) 배설물(排泄物) 처리(處理) 및 재이용(再利用) 과정(科程)에서 발생(發生)되는 문제점(問題點)에 대(對)한 연구(硏究) 자료(資料)가 없고 특(特)히 콤포스트화(化) 작업(作業)이 원시적(原始的)이므로 개선(改善) 확립(確立)이 절실(切實)히 요구(要求)되는 실정(實定)이다. 본(本) 연구(硏究)의 목적(目的)은 가축(家畜) 분뇨(糞尿)의 콤포스트화(化) 작업(作業) 과정(科程)에서 공학적(工學的)인 제(諸) 문제점(問題點)을 조사(調査) 분석(分析)하여 현상(現狀)을 평가(評價)하고 개선(改善) 방안(方案)을 모색(摸索)하기 위한 기본자료(基本資料)를 제공(提供)하고져 수행(遂行)하였다. 이에 관한 조사(調査)와 분석(分析) 결과(結果)를 요약(要約)하면 다음과 같다. 1. 축산농가(畜産農家)의 가축(家畜) 배설물(排泄物) 처분(處分) 방법(方法)은 대부분(大部分)이 자연건조(自然乾燥), 퇴적(堆積), 혐기적(嫌氣的)인 고형(固形) 또는 액상(液狀) 퇴비화(堆肥化)에 의하여 실시(實施)되고 있었으며 가축분뇨(家畜糞尿)로 인(因)한 공해(公害)는 심각(深刻)하다는 것을 알 수 있었다. 2. 호기성(好氣性) 야적(野積) 콤포스트의 통기작업(通氣作業)은 트랙터에 부착(附着)되어진 전후(前後) 작동식(作動式) 로우더가 바람직하다. 3. 농축산(農畜産) 폐기물(廢棄物)의 콤포스트화(化) 작업(作業)은 축산농가(畜産農家)를 중심(中心)으로 한 콤포스트 센타에서 전체 농가(農家)가 지방(地方) 증진(增進)과 오염(汚染) 방지(防止)를 하기 위해 참여(參與)하여 완전(完全) 공동(共同) 이용(利用) 체계에 따라 일관성(一貫性)있게 수행(遂行)되어야 한다. 4. 호기성(好氣性) 야적(野積) 콤포스트 작업(作業)은 다른 방법(方法)에 비하여 운영비(運營費)가 적게 들어 영세적(零細的)인 축산업(畜産業)의 경우(境遇)에 가장 적당(適當)하고 공해(公害)를 방지(防止)함으로서 한국(韓國) 축산농가(畜産農家)의 콤포스트화(化) 시설(施設)로 전망(展望)이 밝다고 판단(判斷)된다.

• Clean Technology
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• v.4 no.2
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• pp.41-53
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• 1998

Most of flame furnace with uncontrolled atmosphere forms oxidation scales in the surface during heat treatment. In this case, shot blasting and pickling are commonly used for reduction of oxidation scales. These processes have many disadvantages, such as long process time, high operating cost and environmental problems due to polishing dust, etc. Hence, this study aimed to develop the advanced heat treating equipment which could make a controlled atmosphere using a heatresisting structure into the flame furnace. The analysis result with SEM, EPMA, and EDX revealed that the amount of scales formed is much less than that with the conventional flame furnace. A brightness of the sample treated with the advanced process is similar compared to the treatment with vacuum furnace. In the present work, it was recommended that the inside structure of the furnace and gas line system could made up of SBB410 and STS310, respectively. The operating cost with the advanced heat treatment system could be reduced annually by forty million won. As a result of this study, it may be possible to reduce the oxidation scales. The fundamental information obtained in this study will be useful not only for improving the heat treatment process(reduction of shot blast and cleaning process), but for promoting the manufacture of bright products.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1056-1063
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• 2012

Recent rapidly growth in nanotechnolgies is promised novel benefits through the exploitation of their unique industrial and biomedical applications. With increasing utilization of nanomaterials in consumer products, the potential release of nanomaterials into the environment and their impacts on the ecosystem and human health have been the issues of concern. Nanomaterials that was exposed unintentionally in environment might be accumulated in various environmental media, and finally it will be influenced to human and ecosystems. Therefore, it is important to understand the fate and behavior of nanoparticles for understanding effects on environmental media (air, water, and soil phase). Therefore, in this work, we investigated the several cases for environmental exposure of nanomaterials and suggested the direction of further research. In workplace, exposure to air media is dominant, but finally waste and wastewater was moved to the water and soil phase. In addition, we found the existing sewage treatment plant was not suitable to remove completely nanomaterials in wastewater flow. To deeper study, environmental monitoring tool must be developed additionally and we suggested the several analyzing method for aged and pristine physicochemical properties of nanomaterials exposed into environmental media. This review for nanomaterials' exposure to environmental media will be helpful to investigate the environmental fate of nanomaterials and define the suitable treatment method for nano-waste.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.230-236
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• 2009

Sewage sludge cake(SSC) is seriously concerned because ocean dumping, which is the cheapest treatment method now, will be banned in 2012. On the basis of this reason, recycling of SSC is emphasized to convert the treatment method. One of the method to recycling SSC could be carbonization process which also can be reduced greenhouse gas effectively. And carbonization residue of SSC produced by carbonization process can become a renewable energy source. However, carbonization process has not been evaluated by considering basic operating data such as heating value, yield and fuel ratio. In this study, the basic characteristics of SSC such as proximate analysis, elementary analysis and heating value are analyzed. In carbonization process, the effect of carbonization temperature and time on the residue of SSC are estimated. And the analysis is carried out to obtain basic properties of the residue of SSC. From the result of chemical composition of SSC residue, there is 27% of phosphate in SSC. Phosphate will take a role of reductant to convert from hazardous substance to non-hazardous material. As increased carbonization temperature and time, heating value and yield are decreased but fuel ratio(fixed carbon/volatile combustible) of the residue is increased. In the carbonization process, the optimum temperature and time in carbonization test for SSC can be decided by $250^{\circ}C$ and 15 min, respectively. However, the carbonization residue of SSC can not be deserved to use one of renewable energy sources because the heating value at the optimum condition is relatively low. Hence, it is desirable that SSC can be mixed with other organic waste to carbonize.