• Title/Summary/Keyword: 편광도

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Mineralogical Characteristics of Tachylite occurring in Basic Dike, Basaltic Agglomerate Formation, Ulleung Island and Its Implications of Volcanic Activity (울릉도의 하부층 현무암질 집괴암 층내 염기성 암맥에서 산출되는 타킬라이트의 광물학적 특성과 화산학적 의미)

  • Bae, Su-Gyeong;Choo, Chang-Oh;Jang, Yun-Deuk
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.63-76
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    • 2012
  • Tachylite, black basaltic glass formed by the rapid cooling of molten basalt, locally occurs at the Basaltic Agglomerate Formation (BAF), the lowest formation of Ulleung Island. The purposes of this study are to characterize the occurrence and mineralogy of tachylite and to elucidate its formation condition, with emphasis on its fracture pattern, which can serve as implications for the early volcanic activity of Ulleung Island. To this end, we investigated the occurrence pattern of tachylite in the field and carried out mineralogical analyses using optical microscope, XRD, EPMA, and SEM. Tachylite occurs at the chilled margin of basic dikes which are distributed in Naesujeon, Dodong and Jeodong seasides, Turtle Rock, and Yaerimwon, whose widths vary from several cm to 10 cm. It is evident that the outer surface of tachylite is dense and smooth, whereas the inner surface, if fractured, is characterized by conchoidal fracture. The matrix of tachylite consists of amorphous, glass and some fine-grained phenocrysts present in tachylite include biotite, anorthoclase, sanidine, plagioclase, hornblende, and Fe-Ti oxides. The fracture patterns characteristic of tachylite are subrounded, oval, or less commonly polygonal, bounded by joints to form globule or lump. Taking into account texture and mineralogy, tachylite is interpreted to have undergone little subsequent alteration at low temperature via hydration or hydrolysis that could form clay minerals after it was formed. Because tachylite with peculiar fractures occurs as dikes in a close association with BAF, its presence is considered as reliable evidence that when tachylite formed, the most part of BAF was still under subaqueous conditions, or at least saturated with seawater.

Fabrication and Characteristics of CFRC(Carbon Firber Reinforced Carbon Composites) Fabricated with Carbon Fiber and Coal Tar Pitch Matrix (석탄계 핏치를 결합재로한 탄소/탄소 복합재의 제조 및 특징)

  • Ju, Hyeok-Jong;Choe, Don-Muk;O, In-Seok
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.194-205
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    • 1994
  • In this research, we attempt to fabricate an excellent CFRC(Carbon Fiber Reinforced Carbon), which has good thermal and mechanical properties, with 8H/satin woven fabric prepreg, high modulus and high strength type continuous carbon fiber and raw coal tar pitch(RCTP) matrix or THF soluble fraction(THFSP) matrix which has good graphitizability. Green bodies were fabricated with hot press molding technique and CFRC samples were made after carbonization, impregnation, recarbonization and graphitization steps. For the purpose of characterization of the physical properties, SEM, polarized light microscope, TGA were observed, and tested flexural strength, modulus and ILSS. After heat treating the THFSP matrix up to $2300^{\circ}C$, the value of $C_0$/2 was 3.380$\AA$, which is analogous to the structure of natural graphite and the value of 2$\theta$ is $26.276^{\circ}$ approached to the Bragg's angle of natural graphite. As a result of TGA to test the high temperature air oxidation, the THFSP matrix, graphitized up to $2300^{\circ}C$, exhibited the best air oxidation resistance. And mechanical properties were increased up to 65~70% as fiber volume fraction increased. Because of the good orientation graphitizability, the fracture surface of THFSP matrix CFRC is very good.

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Characterization of Microtextures formed by Chemical Weathering in Crystalline Rocks and Implications for Rock Mechanics (화학적 풍화에 의한 결정질 암석내의 미세조직 발달특징과 암반공학적 의미)

  • Choo, Chang-Oh;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.21 no.4
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    • pp.381-391
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    • 2011
  • Weathering can reduce rock strength and eventually affect the structural stability of a rock mass, which is important in the field of engineering geology. Several methods have been developed to evaluate the degree of weathering, including the chemical weathering index. In this study, we analyzed the weathering degree and characteristics of microtextures and pores in crystalline rocks (gneiss and granites) based on petrographic observations, the chemical weathering index, mineralogy by XRD, microtextural analysis by SEM/EDS, measurements of pore size and surface area by the BET method, and microporosity by X-ray CT. The formation of secondary minerals and microtexture in gneiss and granitic rocks are assumed to be affected by complex processes such as dissolution, precipitation, and fracturing. Hence, it is clear that some chemical weathering indices that are based solely on whole-rock chemistry (e.g., CIA and CWI) are unable to provide reliable assessments of the degree of weathering. Great care is needed to evaluate the degree of chemical weathering, including an understanding of the mineralogy and microtexture of the rock mass, as well as the characteristics of micropores.

THE DYNAMIC CHANGE OF ARTIFICIALLY DEMINERALIZED ENAMEL BY DEGREE OF SATURATION OF REMINERALIZATION SOLUTION AT pH 4.3 (pH 4.3에서 재광화 용액의 포화도에 따른 인공 탈회된 법랑질의 동력학적 변화)

  • Yi, Ji-Sook;Roh, Bung-Duk;Shin, Su-Jung;Lee, Yoon;Gong, Hyung-Kyu;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.34 no.1
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    • pp.20-29
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    • 2009
  • The purpose of this study is to observe and compare the dynamic change of artificially demineralized enamel by remineralization solutions of different degrees of saturation at pH 4.3. In this study, 30 enamel specimens were demineralized artificially by lactic acid buffered solution. Each of 10 specimens was immersed in pH 4.3 remineralization solution of three different degrees of saturation (0.22, 0.30, 0.35) for 10 days. After demineralization and remineralization, images were taken by a polarizing microscope (${\times}100$). The density of lesion were determined from images taken after demineralization and remineralization. During remineralization process, mineral deposition and mineral loss occurred at the same time. After remineralization, total mineral amount and width of surface lesion increased in all groups. The higher degree of saturation was, the more mineral deposition occurred in surface lesion and the amount of mineral deposition was not much in subsurface lesion. Total demineralized depth increased in all groups.

Occurrences of Sepiolites within a Seosan Group, Western Part of Chungnam (충남 서부 서산층군 내 해포석의 산출)

  • Song, Suckhwan;Lim, Koju;Lee, Wooseok
    • Economic and Environmental Geology
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    • v.46 no.2
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    • pp.141-151
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    • 2013
  • This study examines the mineralogy of sepiolites occurred within the carbonaceous rocks of Songak schist and Pyeongtaek migmatitic gneiss of Precambrian Seosan group, in the western part of Chungnam. Host rocks of the sepiolite were dolomitic rocks and have experienced hydrothermal alteration and metamorphism. Mesozoic granite is assumed as a main source of hydrothermal alteration for the dolomitic rocks. Some of the tremolite asbestos coexist with the sepiolites. Representative sepiolite and tremolite samples were collected from the layers cracks or fractures of the dolomitic rocks and/or examined with microscope with microscope, XRD, SEM and TEM. Sepiolites are mainly recognized along the cracks assumed as pathways of hydrothermal solution. Tremolites are mainly found at layers or cracks of the dolomitic rocks and occur as asbestos as well as non-asbestos forms. It was confirmed that some of the tremolite asbestos were coexisted with the sepiolites. Overall results suggest that the occurrences of sepiolites within the dolomitic rocks mainly result in the hydrothermal alteration and the fluid from the acidic rocks, possibly granites. It also suggests that coexisting tremolite asbestos were formed by similar geological environment.

The Characteristics of Mesophase Pitch Prepared by Heterogeneous Fluorination Process from Pyrolysis Fuel Oil (열분해잔사유로부터 불균일계 불소화공정에 의해 제조된 메조페이스 피치의 특성)

  • Kim, Do Young;Kim, Ji-Hyun;Lee, Hyung-Ik;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.537-542
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    • 2016
  • In this study, we have prepared mesophase pitch from pyrolysis fuel oil (PFO) by heterogeneous reforming process. This process was conducted by direct fluorination at various temperature and followed by the heat treatment at $390^{\circ}C$. The reformed pitch was then investigated by softening point analysis, elemental analysis, fourier-transform infrared spectroscopy, high resolution X-ray diffraction and polarization microscope analysis. Carbon contents of reformed pitch increased according to increasing the reaction temperature of fluorination, while oxygen, nitrogen and sulfur contents were completely eliminated. As the fluorination temperature increased, the creation, growth, coalescence and alignment process of mesophase spheres were observed. Also the interlayer spacing of carbon hexagonal planar structure decreased, while its crystalline size increased. In addition, aromatic ring compound contents increased by the condensation polymerization of aliphatic compound. These results can be attributed to the radical reactivity of the fluorine increased as the reaction temperature increased. It was considered that the fluorination reaction could help PFO to generate aromatic compounds, via promoting polymerization by radical reaction.

The Preparation of Multi-Lamellar Emulsion Which Containing Pseudoceramide(PC-9) (유사 세라마이드(PC-9)를 함유한 다중 층상 유화물의 제조)

  • Park, Byeong-Deog;Yeom, Jong-Kyung;Lee, Myung-jin;Kim, Yoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.1
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    • pp.55-68
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    • 1999
  • A muti-lamellar emulsion containing a pseudoceramide, N-Ethanol-2-myristyl/ palmityl-3-oxostearmide/arachidamide(PC-9) has been prepared and its efficacy evaluation has been investigated. In order to prepare a muti-lamellar emulsion, first, the gram ratios of PC-9, fatty acid and cholesterol on the phase diagram to be capable of forming their lamellar liquid crystal structures were determined and secondly, the multi-lamellar emulsion was preprared using glyceryl monostearate and polyoxyethylene glyceryl monosteartate as emulsifers together with above mentioned pseudo-stratum corneum lipid components. Besides natural oils such as olive oil had a tendency to build up the multi-lamellar emulsion. And according as the amount of oil increased in the emulsion, it was observed that the optical anisotropy of “Maltese Cross” which was a typical configuration of multi-lamella mesophase texture diminished. In the dried state of the multi-lamella emulsion, it was examined to transform its emulsion phase into a lamella liquid crystal one. And finally, when the emulsion was applied into a human skin, it was investigated that it had effectiveness in reducing transepidermal water loss (TEWL) of the skin.

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Evaluating the Efficacy of Whitening Products by Using Luminescence Measurement and Revealing Correlation between Luminescence and Other Parameters (투명감 측정을 통한 제형의 미백 효능 평가와 투명감에 관여하는 요소들에 대한 분석)

  • Jeong, Choon-Bok;Kim, Han-Kon;Nam, Gae-Won
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.4
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    • pp.253-258
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    • 2010
  • Until now, evaluating the efficacy of brightening mainly depends on total reflective light measurement. For example, SHV (Saturation, Hue, Value), $L^*$ $a^*$ $b^*$ (CIELAB color space system) color space system was used and lightness and saturation changes were chosen as major parameters for evaluating brightening effect. However, those parameters were calculated from total reflective light on the skin and it is hard to evaluate perceptive efficacy such as luminescence, and glossy. In this research, we applied new method for estimating change of luminescence of skin by using 'Lumiscan' which uses polarized light for detecting surface and inside reflective light independently. We also tested 15 different parameters for finding correlations between luminescence and those parameters. As a results, our 2 different brightening products showed 5 ~ 9 % increase of luminescence at 4 and 8 weeks. And we also found that skin roughness (-28 %), melanin index (-17 %), redness (-7 %), hydration (15 %), and lightness (6 %) were related to luminescence of skin.

Efficient Second Harmonic Generation of a High-power Yb-doped Fiber MOPA Incorporating MgO:PPSLT (MgO:PPSLT를 이용한 고출력 Yb 광섬유 레이저 빔의 고효율 이차조화파 변환)

  • Song, Seungbeen;Park, Eunji;Park, Jong Sun;Oh, Yejin;Jeong, Hoon;Kim, Ji Won
    • Korean Journal of Optics and Photonics
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    • v.31 no.3
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    • pp.142-147
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    • 2020
  • In this paper, we report highly efficient second harmonic generation of continuous-wave Yb fiber lasers incorporating a periodically poled LiTaO3 device (MgO:PPSLT) as a frequency converter. The seed laser output from a Yb fiber master oscillator using a Fabry-Perot feedback cavity was amplified in a Yb fiber amplifier stage, yielding 28.5 W of linearly polarized output at 1064 nm in a beam with beam quality, M2, of ~1.07. Second harmonic generation was achieved by passing the laser beam through MgO:PPSLT. Under optimized conditions, we obtained 11.1 W of green laser output at 532 nm for an incident signal power of 25.0 W at 1064 nm, corresponding to a conversion efficiency of 44.4%. The detailed investigation to find the optimized operating conditions and prospects for further improvement are discussed.

The Growth of $MgO:LiNbO_3$ Single Crystal by Czochralski Method and its Density Measurement (Czochralski법에 의한 $MgO:LiNbO_3$단결정 성장과 밀도 측정)

  • Kim, Il-Won;Park, Bong-Chan;Kim, Gap-Jin
    • Korean Journal of Crystallography
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    • v.4 no.2
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    • pp.74-85
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    • 1993
  • Single crystals of LiNbO3 have found extensive application in electro-optic and nonlinear optic devices. However, laser-induced refartive index inhomogeneities, which have been labeled opical damage impose limits on device optical damage in LiNbO3 is imporved if more than 4.5 rml% MgO is added to the melt The laser damage thrueshold increased as much as 100 times better then that of undoped crystals. The MgO doped cystal has thus been urterlsiv81y studied since then. In the study, Mgo:LiNbOs(MLA) single crystals dopsd with 0, 2.5, 5.0, 7.5, 10.0 mol% MgO have been grown by the czocrualski technique. The metls were prepared in the platinum crluible and 15∼20mm diameter crystals were grown with a length of 20∼30mm in a resitance heater. The growth rate was 2.5mm/hr, the rotation speed 15rpn. Before sawing MLN single crystals were annealed for 24 hours under atmosphere at a temperature of 1080℃. After sawing, we have found an annual ring cross section of MNA crystals only in the direction of perpendicilar to the c-axis. Nonuniform dispusion of MgO was pointed out that the cuties of the state of oxide were strongly affected by oxygen partial pressure in.

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