• Journal of the Korean Geotechnical Society
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• v.15 no.3
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• pp.99-111
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• 1999

The frictional capacity of auger-cast piles is often very small because of the disturbance of the soil surrounding the pile during the excavation process. Usage of expansive agents and a pressurized injection technique for auger-cast piles should improve the frictional resistance between pile and soil. This paper presents the test results of auger-cast model piles installed with expansive mortar in laboratory compacted weathered soil. The model piles were installed in a calibration chamber with a variation in the amount of expansive agent, the injection process and the chamber pressure. It was observed that the pile shaft resistance increases with the increased amount of expansive agent, and also increases when mortar is pressure injected. The shaft resistance increased up to 24% for the pile installed only with expansive mortar and increased up to 56% for the pile installed with the pressurized injection of expansive mortar, compared with that of piles with plain mortar.

• Polymer(Korea)
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• v.31 no.3
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• pp.206-214
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• 2007

The theoretical study is developed for predicting the thermal expansion changes of composites which include complex inclusion, which is used three-dimensional ellipsoid model ($a_1>a_2>a_3$), which has two aspect ratios (the primary aspect ratio, $\rho_{\alpha}=a_1/a_3$ and the secondary aspect ratio, $\rho_{\beta}=a_1/a_2$). We can predict the feature of general thermal expansion factors by theoretical approach of matrix with aligned ellipsoidal inclusion using the Eshelby's equivalent tensor. The coefficients of longitudinal linear thermal expansion ${\alpha}_{11}$ decrease to those of inclusions, ${\alpha}_f$, as both aspect ratios increase. The coefficients of transverse linear thermal expansion of composites ${\alpha}_{33}$ initially increase and show the parabolic corves with maximum values, as the concentrations of filler increase. The coefficient of thermal expansion, ${\alpha}_{22}$ in the transverse direction decreases, as $\rho_{\alpha}$ increases, however, ${\alpha}_{22}$ increases as $\rho_{\beta}$ increases. The coefficient of linear thermal expansion of composites, ${\alpha}_{33}$ in the normal direction increases, as $\rho_{\alpha}$ increases, while ${\alpha}_{33}$ decreases as $\rho_{\beta}$ increases.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.223-231
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• 1998

Existing cast in place piles made by grouting cement mortar have many problems that cracks by autogeneous and drying shrinkage bring about the deterioration of force for piles, segregations by the submersion of ground water occur and also, high cement contents lead to rise the manufacturing cost. Therefore, this study is intended to investigate the mechanical properties of high performance mortar, incorporating expansive additives and fly ash. for cast in place piles. According to the experimental results, as the contents of expansive additives increase in mortar mixture, fluidity decrease and air contents shows inverse tendency. Setting time is delayed. Although compressive strength at 7days shows a decline tendency. compressive strength at 28days and 91days increase slightly with 5% of expansive additives. As fly ash increase in mortar mixture, high fluidity is shown, air contents increase and setting time is delayed at fresh state, and additives are, the larger length change is, whereas shrinkage decrease with the increase of fly ash.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.77-85
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• 2012

Production process of the flexible ceramic foamed body through the complexation with the fiberous sepiolite and expanded pearlite was researched. The processing of fibrillation of the inorganic mineral fiber sepiolite is the most important whole processing for manufacturing of the ceramic foamed body consisting of the expanded perlite and sepiolite. The fibrous sepiolite and expanded pearlite are blended and becomes the slurry phase. And this slurry phase is converted to a massive foamed body through the low temperature heat treatment process less than $300^{\circ}C$. The heat-treatment process of the slurry phase composite has to be designed to include the evaporation step of the moisture remaining among the slurry composition, foaming step by the decomposition of the foaming agent, and resolution removal step of the organic material which was added in the composite remained after the foaming step. The heat treatment process should be considered as significant factors in design of total process. As to the condition of heat treatment process and foaming agent, there was the a correlation. An organic type foaming agent like DSS (dioctyl sodium sulfosuccinte) was effective in foaming of the slurry compound consisting of the expanded perlite and sepiolite fiber.

• Polymer(Korea)
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• v.39 no.1
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• pp.64-70
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• 2015

Thermally expandable microcapsules (TEMs) can be expanded upon heating since the activation energy of liquid hydrocarbon at the core of the TEMs increased at high temperature. Due to this property, TEMs are widely used in the industry as blowing agents or light-weight fillers. In this article, chemical blowing agent and TEM were used for making polypropylene (PP) foams, and their mechanical properties were compared. Physical properties (tensile strength, impact strength etc.) of PP foams decreased with increasing the amount of blowing agents while weight of specimen decreased. However, PP foam produced with TEMs showed higher impact strength than the one with a chemical blowing agent. In order to figure out the difference of impact strength, the morphology of PP foamed was investigated. Expanding properties of TEM can be controlled by changing core back distance.

• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.441-448
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• 2011

In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.5
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• pp.34-40
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• 2014

High-performance fiber-reinforced cement composite (HPFRCC) shows very high autogenous shrinkage, because it contains a low water-to-binder ratio (W/B) of 0.2 and high fineness admixture without coarse aggregate. Thus, it needs a method to decrease the cracking potential. Accordingly, in this study, to effectively reduce the shrinkage of HPFRCC, a total of five different ratios of SRA (1% and 2%), EA (5% and 7.5%), and a combination of SRA and EA (1% and 7.5%) were considered. According to the test results of ring-test, a combination of SRA and EA (1% and 7.5%) showed best performance regarding restrained shrinkage behavior without significant deterioration of compressive and tensile strengths. This was also verified by performing modified drying shrinkage crack test.

• The Korean Journal of Rheology
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• v.7 no.3
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• pp.181-191
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• 1995

점탄성유체의 물성치들 중 정압열팽창계수 및 밀도는 자연대류 열전달 연구에 전단 속도 0에서의 점도는 점탄성유체에 대한 모델들 사용 시 필요하다. 본 연구에서는 점탄성유 체이며 마찰 감소 첨가제, 유전자 분리용액동으로 사용하는 Separan AP-273 용액의 정압열 팽창계수, 밀도 및 전단속도 0에서의 점도에대한 농도 및 온도의 영향을 조사하였다. 작동유 체의 물성치들은 10~6$0^{\circ}C$의 온도범위와 100~20,000wppm의 농도범위에서 측정되었다. 작 동유체의 물성치들에 미치는 열주기와 노화의 영향을 조사하기 위해서 정압열팽창계수와 전 단속도 0에서의 점도를 교대로 두 번씩 측정했다. 정압열팽창계수 및 밀도를 측정하는 장치 의 측정 정밀도는 증류수에 대한 측정치와 문헌에 나타난 자료를 비교하여 얻었고 이는 $\pm$ 2%이내였다. Separan AP-273용액의 정압열팽창계수 및 밀도는 증류수의 값들로 대치될수 있다. 작동유체의 정압열팽창계수와 밀도는 열주기와 노화의 영향을 받지 않았다. 낙하식 점 도계를 사용해 측정한 겉보기점도 값들을 나타내느 flow curve에서 전단속도가 0이 되는방 향으로 겉보기점도를 외삽시켜 Separan AP-273용액에 대한 전단속도0에서의 점도를 얻었 다. 정압열팽창계수 측정 전후에 측정한 작동유체에 대한 전단속도 0에서의 점도는 열주기 와 노화로 인해 퇴화되었다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.11a
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• pp.85-88
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• 2008

As super-high-strength concrete uses a large amount of binder, there is an autogenous shrinkage strain larger than dry shrinkage and it degrades the quality of structures. Thus, we need a technology to minimize the shrinkage strain of super-high-strength concrete. Accordingly, the present study prepared super-high-strength concrete with design strength of over 100MPa and, using an embedded gauge, measured the shrinkage strain of free shrinkage specimens for super-high-strength concrete containing expansion agent. According to the results of this study, the expansion rate of concrete increased in the early stage due to the admixture of expansion agent, but the shrinkage rate went down with the lapse of time. The effect of the admixture of expansion agent on compressive strength appeared insignificant. Further research shall be made on different kinds of expansion agents and various mixture ratios for basic analysis to reduce autogenous shrinkage of super-high-strength concrete.

• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1090-1097
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• 1998

Lidocaine compounds have widely been used as local anesthetics. Regarding the molecular mechanism for anesthesia by lidocaine, it is proposed that lidocaine molecules penetrate to the hydrophobic region of cell membrane and expand the membrane volume, producing a change in protein conformation that blocks sodium permeability or lidocaine molecules directly adsorb into lidocaine receptor in the protein channel without expanding the cell membrane. But these proposals have never been proven experimentally. In this study, the expansion of cell membrane by lidocaine compounds was investigated by employing lipid monolayer at the air/water interface as the mimetic system of cell membrane. It was found that oil-soluble lidocaine contracted the area/molecule of lipid in the monolayer of phosphatidyl choline, sphingomyelin, DS-PL95E and lipoid, but expanded the monolayer of phosphatidyl ethanolamine only in a certain range of mixing ratios. On the contrary, water-soluble lidocaine-HCl salt expanded the monolayers of all lipids used in this study.