• KSBB Journal
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• v.15 no.6
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• pp.548-555
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• 2000

A hydrogel, poly(N-isopropylacrylamide-co-N, N-dimethylaminopropylmethacrylamide), sensitive to both pH and temperature, was synthesized and characterized at $^13∼23{\circ}C$ and pH of 10.3∼12.3. The gel was more transparent and mechanically stronger at lower preparation temperature and pH. Large pores observed in scanning electron microscope seem to be responsible for the lower biomolecular separation efficiency. The lower critical solution temperature (LCST) decreased at a higher polymerization temperature. At $25^{\circ}C$, which is lower than the LCST, the gel was swollen regardless of the solution pH. At $40^{\circ}C$, however, the gel was swollen at neutral and acidic pHs even though the temperature was higher than the LCST. The gel collapse pH, defined as the point at which the gel made its largest volume decrease per unit pH increment, increased as the gel preparation temperature increased.

• Journal of the Mineralogical Society of Korea
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• v.16 no.1
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• pp.33-47
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• 2003

Various applied-mineralogical characterization including measurements of surface area, size distribution, swelling index, and viscosity were done for some domestic bentonites in order to decipher the rheological properties and their controlling factors. The bentonites, which are Ca-type and relatively low-grade (rnontmorillonite contents: 30 ∼ 75 wt%), occur mostly as subhedral lamellas with the size range of 2 ∼ 4 $\mu\textrm{m}$. The size distribution of mineral fractions in bentonite suspension is dominant in the range of 10 ∼ 100 $\mu\textrm{m}$, and though rather complicated, exhibits roughly bimodal patterns. The feature is more conspicuous in the case of zeolitic bentonite. The bentonites have surface areas ranging 269 ∼ 735 $\m^2$/g, which are measured by EGME adsorption method. The EGME surface areas are nearly proportional to the rnontmorillonite contents, moisture contents, or total CEC. In the surface area measurements, zeolitic bentonites have slightly higher values than those zeolite- free types. The measured swelling index and viscosity of domestic bentonites are comparatively low in values. The swelling values of bentonites were measured to be 250∼500% at maximum by progressively mixing amounts of 2 ∼ 5 wt% Na$_2$CO$_3$, which varies depending on the contents of rnontmorillonite and other impurities, especially zeolite. Much amount of sodium carbonate is required for optimum swelling property of zeolitic bentonited which has usually strong Na- exchanged capacity. The bentonites, which are comparatively feldspar-rich and low in size and crystallinity, tend to be higher in viscosity values. Tn addition, the viscosity is largely higher in case of the bentonites with higher pH in suspension. However, the rheological properties of bentonites such as swelling index and viscosity do not show any obvious relationships with rnontmorillonite contents and mean particle size in suspension. In contrast, roughly speaking, the swelling index of bentonites is reversely proportional to the values of surface area which can be regarded as a collective physico-chemical parameter encompassing all the effects caused by mineral composition, surface charge, particle size, morphological farm, and etc. in bentonites. Thus, the rheological properties in bentonite suspension appear to be rather complicated characteristics which mainly depend on the flocculation of clay particles and the mode of particle association, i.e. quasicrystals, controlled by surface charge, morphology, size, and texture of rnon-tmorillonite, and which partly affected by the finer impurities such as zeolite.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.347-347
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• 2003

폴리아크릴로니트릴을 NaOH로 가수분해시키면 carboxylate anion과 carboxanlide기가 생성되며, 물을 흡수할 경우 sodium carboxylate기의 해리로 팽윤이 크게 일어나므로 고흡수성을 지니게 된다. 일찍이 flory[1]는 가교된 고분자 전해질이 고흡수성을 나타내는 겔을 형성할 것으로 예측한 바 있다. 이 가교 결합이 아크릴 섬유의 부분 가수분해에 대한 자료는 새로운 기능을 부여하면서 섬유의 물성을 어느 정도 유지하는데 요구되는 조건을 제시하게되므로 향후 아크릴 섬유의 개질에 활용될 수 있다. (중략)

• Proceedings of the Membrane Society of Korea Conference
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• 1991.04a
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• pp.31-33
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• 1991

생체적합성이 우수하며 자연계에 널리 존재하는 chitin의 탈아세틸화물인 chitosan은 인공피부, 생분해성 고분자 재료 및 약물방출용 고분자막으로서 널리 사용되고 있다. 특히 chitosan은 cellulose와 유사한 화학구조를 가지고 있으며 보다 풍부한 반응성 작용기를 가지므로 이를 개질하려는 연구가 활발하게 진행되고 있다. 따라서 본 연구실에서는 chitosan막이 산성 조건하에서 팽윤되는 성질을 이용한 pH-sensitive막을 이용한 약물방출 조절에 관한 연구를 진행하고 있다.

• Journal of the Korean Geotechnical Society
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• v.20 no.8
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• pp.15-27
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• 2004

Sliding aspects of rock slope, where large-scaled tension cracks are induced during preliminary excavation, have been analyzed. Structure of rock mass is investigated by performing the electrical resistivity survey and the orientations and positions of discontinuities are measured from DOM-drilled core log. Geological evidence far primary failure movement has been detected and clay minerals which possess swelling properties are identified through XRD analysis. Slope stability is examined by considering the orientations of discontinuities and their trace distributions on the cut-face and neighboring natural slope surface. Both orientations and positions of failure-invoking discontinuity planes, traces of which are exposed within the anticipated sliding region, are concerned fur analyzing the preferred sliding directions. Regional sliding vectors are assessed based on the relative positions of potential sliding planes in the boreholes and the general trend of anticipated failure movement of rock slope is also investigated.

• Korean journal of food and cookery science
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• v.13 no.4
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• pp.379-383
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• 1997

To study the effect of amylose on the mechanism of gel formation, swelling power, water solubility, the pattern of alkali gelatinization and gel properties were investigated. The swelling power of waxy maize starch (Amioca) was the highest and followed by those of PFP > Amaizo > Amylomaize VII. Amioca showed higher iodine affinity of soluble amylose than other maize starches. The apparent viscosity of alkali gelatinization measured by Brookfield viscometer for Amaizo was 70${\times}$10$^3$cp which was higher than Amylomaize VII. The apparent viscosity of PFP was increased to 70${\times}$10$^3$cp and then decreased. As maize starches were autoclaved at 121$^{\circ}C$ with starch: water ratio (1 : 9) and autoclaving-cooling cycle were up to 4 times, gel properties were measured by rheometer. Amaizo showed the highest value for hardness, adhesiveness, springiness, and cohesiveness, and hardness of gel after two cycles of autoclaving-cooling was the highest. Gel properties seemed to be affected by the chain length of amylose rather than the content of amylose.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.2
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• pp.135-147
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• 2016

The buffer in geological disposal system is one of the major elements to restrain the release of radionuclide and to protect the container from the inflow of groundwater. The buffer material requires long-term stability, low hydraulic conductivity, low organic content, high retardation of radionuclide, high swelling pressure, and high thermal conductivity. These requirements could be determined by the quantitative analysis results. In case of South Korea, the bentonites produced in Gyeongju area have been regarded as candidate buffer/backfill materials at KAERI (Korea Atomic Energy Research Institute) since 1997. According to the study on several physical and chemical characteristics of domestic bentonite in the same district, this is the Ca-type bentonite with about 65% of montmorillonite content. Through this study, we present the criteria for the performance evaluation items and methods when collecting new buffer/backfill materials.

• Tunnel and Underground Space
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• v.21 no.1
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• pp.20-32
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• 2011

Failure aspects of cut-slope, which induce the sequential collapses during the excavation stage, have been analyzed. Slope rock structures are investigated by examining the orientations and positions of discontinuity planes calculated based on the BIPS image inside the boreholes. Drilled core log has been also used to identify the structural defects. Clay minerals of swelling potentials are detected through XRD analysis. Numerical analysis for slope stability has been performed by utilizing the joint shear strength acquired from the direct joint shear test. Cut-slope collapse characteristics have been studied by investigating the posture of failure-prawn joint planes and the stability of tetrahedral blocks of different sizes. Cross-section analysis has been also performed to analyze the cut-slope behavior and to estimate the amount of reinforcement required to secure the stability of cut-slope. Behavior of reinforced cut-slope is also investigated by analyzing the slope monitoring data.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.17 no.4
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• pp.413-421
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• 2004

In this paper, a structural analysis for the pressurized water reactor(PWR) spent nuclear fuel disposal canister which is deposited under the 500m deep underground is carried out to predict the creep deformation of the canister while the underground water and swelling bentonite pressure are applied on the canister. Usually the creep deformation may be caused due to the Pressure and the high heat applied to the canister even though additional external loads are not applied to the canister. These creep deformations depend on the time. In this paper, oかy the underground water and bentonite swelling Pressure are considered for the creep deformation analysis of the canister, because the heat distribution inside canister due the spent fuel is not simple and depends on time. A proper creep function is adopted for the creep analysis. The creep analysis is carried out during $10^8$ seconds. The creep analysis results show that the creep strains are very small and these strains occur usually in the lid and bottom of the canister not in the cast iron insert. A much smaller strain is found in the cast iron insert. Hence, the creep deformation doesn't affect the structural safety of the canister, and also the creep stress which shows the stress relaxation phenomenon doesn't affect the structural safety of the canister.

• Economic and Environmental Geology
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• v.53 no.1
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• pp.87-98
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• 2020

The bird track fossil site in Haman Formation is divided into seven sedimental layers by the sedimentary structures, lithofacies and sequences. The bird tracks top on the highest layer, which includes ripple marks and suncracks. The layer has lithofacies with reddish grey siltstone and dark grey mudstone, alternately. As an analysis for the same rocks of the fossil site, physical properties show on mean values for 0.62% of absorption rate, 1.64% of porosity and 2.63 of specific gravity. Rock-forming minerals composed mainly of plagioclase, quartz, calcite, chlorite and mica. Meanwhile, we executed an experiments based on the petrography and weatherings to find a proper consolidants. In the experiments, the OH 100 reagent proved stable aspect and the lowest transition rate in terms of weight and chromaticity. Also, it showed the highest increase in ultrasonic velocity, improving the physical properties of the rocks. In the case of applying the OH 100 with antihygro, an swelling inhibitors on the sedimentary rocks, the chromaticity indicated an stable transition aspect. When it comes to the physical properties, the antihygro also decreases the porosity effectively. Thus, the most proper method for the fossil site of Haman Formation is to apply antihygro and OH 100 reagents since the rocks includes clay minerals that show swelling characteristics. However, this result is deduced from an indoor application experiments, leaving the necessity of verification how these reagents would affect the bird tracks site under the field condition.