• Title/Summary/Keyword: 팽윤성

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Electron Beam Radiation Syntheses of Carboxymethylcellulose-based Composite Superabsorbent Hydrogels: Dependence of Gel Properties on Polymer Composition and Additives (전자빔 조사에 의한 카르복시메틸셀룰로스 기반 복합 초흡수제 제조시 폴리머 조성 및 첨가물질의 종류에 따른 겔 특성 변화)

  • Sung, Yoonki;Kim, Tak-Hyun;Lee, Byunghwan
    • Clean Technology
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    • v.22 no.4
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    • pp.258-268
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    • 2016
  • In this work, carboxymethylcellulose-based composite superabsorbent hydrogels were prepared by electron beam radiation. The composition of carboxymethylcellulose (CMC) varied from 4 wt%, 5 wt%, and 6 wt% to 7 wt% based on the amount of distilled water in the syntheses of hydrogels. Graphite oxide, reduced graphene oxide, activated carbon, and bentonite were used as additives for the synthesis of composite superabsorbent. The effect of CMC composition and the type of additives on the gel properties of the prepared hydrogels was investigated. In order to verify the functional groups in the prepared materials, Fourier transform infrared spectroscopy was used. In addition, mechanical strength, gel fraction, swelling kinetics, and equilibrium swelling ratios were measured for the prepared hydrogels. Swelling experiments were carried out in distilled water, urea solution, and physiological saline water. Prepared hydrogels were reused for 5 times, and gel fraction and swelling ratio were measured at every 24 hours. Among the prepared hydrogels, $C_{5%}GO$ and $C_{5%}rGO$ exhibited excellent mechanical property and relatively high swelling ratios for urea solution and physiological saline water with promising applicability as slow-release fertilizers.

Swelling Properties of Poly(ethylene terephthalate) Fiber in Mixed Solvent(II) ―Equilibrium Swelling and Shrinkage― (혼합용매중에서의 Poly(ethylene terephthalate)섬유의 팽윤성(II) ―평형팽윤 및 수축거동―)

  • Lee, Mun Cheul;Pak, Pyong Ki;Cho, Hyun Hok
    • Textile Coloration and Finishing
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    • v.6 no.4
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    • pp.17-26
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    • 1994
  • Poly(ethylene terephthalate)(PET) filaments were treated in binary mixtures of organic solvents such as benzyl alcohol/perchloroethylene(BA/PER), benzyl alcohol/trichloroethylene(BA/TRI), benzyl alcohol/ethylene chloride(BA/EC), methanol/perchloroethylene (ME/PER), and methanol/trichloroethylene(ME/TRI). From the equilibrium swelling of PET, total and partial isotherms of PET for sorption of solvent mixtures and isotherms for distribution of the components between the phases were taken. Also the shrinkage and the crystallinity of PET treated with binary mixtures were investigated. The results obtained were summerized as follows: 1. All isotherms for distribution of the components between the phase deviated from the diagonal in system of PET-binary mixtures. Especially in the binary mixtures of ME/PER or ME/TRI, selectivo sorption of chlorinated hydrocarbon PER and TRI by PET occured. 2. The shrinkage of PET treated in binary mixrures was increased to compare with single solvent-treated, but the composition of binary mixtures corresponding to maximum values of shrinkage was not always agreed with the composition of binary mixtures corresponding to maximum values of shrinkage was not always agreed with the composition of binary mixtures exhibiting of the maximum swelling of PET. 3. The crystallinity of PET treated in binary mixtures generally increased than that of single solvent-treated.

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Effect of Phenylboronic Acid on the Swelling-Shrinking Behavior of Hydrogel (Hydrogel의 팽윤-수축 거동에 미치는 Phenylboronic Acid의 영향)

  • Lee, Jong-Ho;Oh, Han-Jun;Cho, Donghwan;Han, In Suk
    • Journal of Adhesion and Interface
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    • v.12 no.2
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    • pp.56-61
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    • 2011
  • In the present study, glucose-sensitive hydrogels using phenylboronic acid (PBA) without glucose oxidase and catalase were prepared. The swelling-shrinking behavior of the hydrogel according to the variation of pH and glucose and ionic concentrations was investigated. The swelling ratio of the hydrogel containing PBA increased with increasing the glucose concentration and the volume was very sensitively varied with the pH. However, the ionic concentration did not change significantly the relative swelling ratio on the hydrogel, indicating that the hydrogel was dimensionally stable.

Physicochemical Properties of Korean Raw Noodle Flours (우리나라 생면용 밀가루의 성질)

  • Shin, Soong-Nyong;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.418-424
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    • 2005
  • The physicochemical properties of raw noodle flours (n = 11) commercially produced from Australian Standard White (ASW) (Group 1, n = 8) and blonds (Group 2, n = 3) of ASW and Australian hard, western white or hard red winter were investigated. Protein and ash contents were lower in Group 1. The tristimulus color values, mean particle size, flour swelling volume (FSV) and rheological parameters of farinograph and extensigraph were not different between two flour groups. Peak viscosity measured with Rapid Visco Analyzer was higher in Group 1. The protein content was positively correlated with mean particle size, dough stability and dough extensibility, and negatively correlated with FSV and peak viscosity. The FSV wag positively correlated with the peak viscosity. The rheological parameters of dough did not show any correlations with FSV and peak viscosity.

Properties of Pohang Mudstone with High Porosity According to Water Immersion (수침에 따른 공극률이 큰 포항 이암의 특성)

  • Kim, Byung-Soo;Lee, Yun-Jae;Kim, Tae-Hyung;Kim, Byeong-Jun
    • Journal of the Korean Geotechnical Society
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    • v.37 no.11
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    • pp.83-92
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    • 2021
  • In this study, effective porosity measurement, electron microscope (SEM) observation, X-ray diffraction analysis (XRD), slaking, swelling, and unconfined compression strength according to water immersion were analyzed to evaluate the properties of mudstone with high porosity in Pohang. As a result of the test for 16 square samples (5 cm), the effective porosity was 14.67% on average, higher than porosity of general mudstone, and electron microscope observation confirmed that the porosity was actually high. As a result of X-ray diffraction analysis, the swelling clay mineral content was 2.3~4.1%, which was lower than the results of previous studies in Pohang. The slake durability index was 37.73~87.73%, showing low to medium durability, which was lower than the results of previous studies. It was confirmed that the swelling property rapidly expanded to 1.79~1.82% of maximum swelling strain in the major axis direction for 30 minutes. As the properties of decreasing the unconfined compression strength according to water immersion, the samples rapidly weathered after 10 minutes of water immersion, and the strength decreased. It was confirmed that the results of previous studies related to mudstone in Pohang were different. This is judged to be due to the high porosity of mudstone in study.

Studies on the Substrances Contained in Glucomannan Lowering Liver and Serum Cholesterol Levels (구약고구마(Glucomannan)의 섬유질이 간 및 혈청지질에 미치는 영향)

  • 이숙경
    • Journal of Food Hygiene and Safety
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    • v.6 no.2
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    • pp.73-78
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    • 1991
  • As reported previously, it was found that glucomannan, contains a potent cholesterol-lowering material. This study was designed to characterize this material further. Both the water sluble and the alcohol soluble extracts of glucomannan were prepared, and each of these extracts were capable of reducing serum and liver cholestrol levels of rats: This finding indicates that a potent cholesterol-lowering material contained in glucomannan is an organic compound with hydrophilic groups.

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Slope Stability Analysis of Waste Landfill by Centrifuge Model Test (원심모형실험을 통한 폐기물 매립장의 사면안정성 평가)

  • Shin, Eun-Chul;Oh, Young-In;Heo, Yol
    • Journal of the Korean Geotechnical Society
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    • v.16 no.2
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    • pp.145-154
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    • 2000
  • 오늘날 폐기물 매립장의 구조적 안정성문제는 국내.외적으로 중요한 문제로 대두되고 있으며, 특히, 사면의 차수체계에서의 안정성에 대한 논란이 사회적 문제로 대두되고 있다. 또한, 우리 나라는 주민들의 NIMBY 현상과 국토의 효율적 활용을 위하여, 폐기물 매립장을 해안매립지나 산간지방에 많이 건설하고 있다. 그러나, 이러한 경우 사면구배가 급해지고 토목섬유의 활용이 불가피해져 안정성에 많은 문제점을 내포하게 된다. 이 연구는 폐기물 매립장 사면의 안정성을 해석하기 위하여, 원심모형실험을 실시하였다. 또한, 이론식 및 사면안정 해석 프로그램을 이용하여 안전을 산정하였다. 이 연구에 사용한 토목섬유 점토차수재(GCLs)의 팽윤도는 침출수와 증류수의 투과수에 대하여 22~25%의 팽윤도를 보였으며, 투수계수는 투과수가 침출수일 경우, 1.47$\times$10-10cm/sec, 증류수일 경우, 8.75$\times$10-11cm/sec의 값을 나타내었다. 원심모형실험 결과, 토목섬유 점토차수재의 포화여부와 지오멤브레인(HDPE)의 표면거칠기에 따라 사면 안전율이 각각 변화함을 알 수 있었으며, 표면이 거친 지오멤브레인과 건조한 토목섬유 점토차수재를 사용하였을 때, 파괴가 발생되지 않아 사면안정성이 높은 것으로 평가되었다. 또한, 이론에 의해 도출된 사면의 안전율과 사면안정 해석프로그램에 의한 안전율 계산 시, 전자의 경우가 후자의 경우보다 작게 평가됨을 알 수 있다.

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Vacuum Pressure Treatment of Water-Soluble Melamine Resin Impregnation for Improvement of Dimensional Stability on Softwoods (목재의 치수안정성 개선을 위한 진공가압 멜라민 수지함침처리)

  • Oh, Seung-Won;Park, Hee-Jun
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.327-333
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    • 2015
  • To measure the dimensional stability of three softwoods by vacuum pressurization of water soluble melamine-formaldehyde (MF) resin impregnation process, properties of resin treated compressed woods (compregs) were measured after impregnating the water soluble MF resin into three coniferous wood species for different impregnation times and resin concentrations. As the resin concentration was higher and impregnation time was longer, coefficients of volumetric shrinkage and anti-volumetric swelling efficiency increased, but coefficients of volumetric swelling, anti-volumetric swelling efficiency and absorption decreased. Also, weight percent gain increased remarkably as the resin concentration was high, but there was no uniform relationship with impregnation time.

Changes in the Properties of Nonwaxy Rice Flours by Lipid Extraction (탈지에 의한 멥쌀가루 성질의 변화)

  • 이현주;신말식
    • Korean journal of food and cookery science
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    • v.13 no.4
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    • pp.478-483
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    • 1997
  • The effects of defatting by ether or 85% methanol on the properties of nonwaxy rice flours (Odaebyeo and Mankeumbyeo) were investigated. Starch granules in the rice flour were all polygonal and showed all A-type crystalline patterns regardless of defatting. Amylose content of the rice flour extracted by ether (crude lipid-defatted rice flour, CLDRF) was similar to the untreated (untreated rice flour, URF), however, that of 85% methanol (total lipid-defatted rice flour, TLDRF) was increased. Defatting decreased the water binding capacities of rice flour in all samples. The swelling power of rice flour was higher in Odaebyeo than Mankeumbyeo, and that of CLDRF showed a similar pattern to the untreated. Swelling power was the highest in TLDRF up to 85$^{\circ}C$, but decreased in the following order CLDRF > URF > TLDRF at above 95$^{\circ}C$. A similar pattern was observed in the leached soluble fraction, and its apparent amyloae content was increased rapidly at above 85$^{\circ}C$.

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Assessment of Physicochemical Properties of Domestic Bentonite and Zeolite as Candidate Materials for a Engineered Barrier in a Radwaste Repository (방사성폐기물 처분장 공학방벽 재료로서의 국산 벤토나이트 및 제올라이트에 대한 물리화학적 특성 평가)

  • 정찬호
    • The Journal of Engineering Geology
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    • v.9 no.2
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    • pp.89-100
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    • 1999
  • This study was carried out to assess the physicochemical properties of domestic bentonites and zeolites from Tertiary Formation as the candidate material for a engineered barrier of a radioactive waste repository. Natural bentonite and zeolite samples were collected from nine bentonite mines and six zeolite mines in Yeonil-Gampo area. The commercial products of bentonite and zeolite were obtained from local companies. The collected samples were investigated to study the following physicochemical properties: X-ray diffraction patterns, swelling, cation exchange capacity(CEC), specific surface area, montmorillonite content, pH, organic carbon content, thermal property, microstruciure and chemical composition. Based on the physicochemical properties of bentonite and zeolite, the bentonites from U-41 and G-46 mines and the zeolites from Daedo and Y-1 mines are regarded as the most desirable candidate materials.

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