• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.51-58
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• 1996

The rearrangement of [(ethoxycarbonyl)phenylaminomethyl]phenylcarbamic acid ethyl esters(N-benzyl compounds) to methylenediphenyldiurethanes(MDU) in sulfuric acid, sulfuric acid-absolute ethanol solvent system, and sulfuric acid-nitrobenzene solvent system, and boron trifluoride at $90^{\circ}C$ was studied. The production of MDU was the highest in sulfuric acid-nitrobenzene system giving 64% MDU yield, of which 58% was 4,4'-MDU. The simultaneous condensation of EPC and formaldehyde and rearrangement to MDU were studied in the presence of different amounts of sulfuric acid, trifluoroacetic acid, and boron trifluoride at $70^{\circ}C$. Though 17mmol of sulfuric acid with 30mmol of EPC produced the highest MDU, the MDU yield was much lower than that from separate condensation and rearrangement reaction.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.5
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• pp.595-602
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• 2012

In this study, for the purpose of reduction of $CO_2$ gas emission and to increase recovery of waste heat from ships, the ORC (Organic Rankine Cycle) is investigated and offered for the conversion of temperature heat to electricity from waste heat energy from ships. Simulation was performed with waste heat from the exhaust gasse which is relatively high temperature and cooling sea water which is relatively low temperature from ships. Various fluid is used for simulation of the ORC system with variable temperature and flow condition and efficiency of system and output power is compared. Finally, 2,400kW output power is obtained by system optimization of the preheater and reheater utilizing waste heat form sea water cooling system.

• Journal of Navigation and Port Research
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• v.36 no.5
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• pp.349-355
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• 2012

In this study, for the purpose of reduction of $CO_2$ gas emission and to increase recovery of waste heat from ships, the ORC(Organic Rankine Cycle) is investigated and offered for the conversion of temperature heat to electricity from waste heat energy from ships. Simulation is performed with waste heat from the exhaust gasse which is relatively high temperature and cooling sea water which is relatively low temperature from ships. The result shows that 1,000kW power generation is available from exhaust gas and 600kW power generation is available from sea water cooling system. Different fluid is used for simulation of the ORC system with variable temperature and flow condition and efficiency of system and output power is compared.