• Rubber Technology
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• v.23 no.2
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• pp.109-120
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• 2022

• Applied Chemistry for Engineering
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• v.29 no.4
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• pp.399-404
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• 2018

This study compared the tackiness and adhesion of different tire tread compounds and rubber cements before and after vulcanization. The tackiness of natural rubber (NR) cement was the highest for all tread compounds before vulcanization, and the decrease in tackiness of NR cements over time was smaller than that of synthetic rubber cements. The tackiness before vulcanization was affected by the glass transition temperature of the rubber used in the cement and the decrease in tackiness over time of NR was smaller compared to that of using the synthetic rubber. The adhesion of NR-based cements after vulcanization was high for NR tread compounds but low for synthetic rubber tread compounds. On the contrary, the adhesion of emulsion (SBR) and solution SBR cements was high on all tread compounds which was shown to be higher when the rate of vulcanization of cement rubber was lower.

• Rubber Technology
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• v.23 no.1
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• pp.1-13
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• 2022

• Rubber Technology
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• v.22 no.1
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• pp.1-14
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• 2021

• Elastomers and Composites
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• v.48 no.3
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• pp.201-208
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• 2013

In this study, effect of different amounts of sulfur and vulcanization accelerators in the acrylonitrile styrene-butadiene rubber (AN-SBR)/silica compounds on the properties of tire tread compound were studied. As a result, cure rate and degree of cross-linking of the compounds were increased due to enhanced cross-linking reactivity by the increased amounts of sulfur and vulcanization accelerators. Also, abrasion resistance and the mechanical properties such as hardness and modulus of the compounds were improved by enhanced degree of cross-linking of the compounds. For the dynamic properties, tan ${\delta}$ value at $0^{\circ}C$ was increased due to the increase of glass transition temperature ($T_g$) by enhanced degree of cross-linking of the compound, and tan ${\delta}$ value at $60^{\circ}C$ was decreased. Initial cure time ($t_1$) showed the linear relationship with tan ${\delta}$ value at $60^{\circ}C$. This result is attributed that reduced initial cure time ($t_1$) of compounds by applying increased amount of curatives can form cross-linking in early stage of vulcanization that may suppress development of filler network. This result is verified by observation on the surface of annealed compounds using AFM (atomic force microscopy). Consequently, decreased initial cure time is considered a very important parameter to reduce tan ${\delta}$ at $60^{\circ}C$ through reduced re-agglomeration of silica particles.

• Composites Research
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• v.36 no.3
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• pp.141-153
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• 2023

This review paper presents an introduction of contact mechanics and rubber friction theory for sliding friction of elastomer composites in contact with rough surfaces. Particularly, Klüppel & Heinrich theory considers the self-affine (or fractal) characteristic for rough surfaces to predict adhesion and hysteresis frictions of elastomers based on the contact mechanics of Greenwood & Williamson. Due to dynamic excitation process of elastomer composites while sliding in contact with multiscale surface roughness (or asperity), viscoelastic properties in a wide frequency range becomes major contributor to friction behaviors. A brief description and examples are provided to construct a viscoelastic master curve considering nonlinear viscoelasticity of elastomer composites. Finally, application of rubber friction theory to tire tread compounds in traction with road surfaces is discussed with several experimental and theoretical results.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.310-316
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• 2020

Terpene-modified phenolic resins were used to improve the tires wet traction related to the driving safety and also rolling resistance related to fuel efficiency. In this work, alpha-pinene, beta pinene, and delta limonene resins, which constitute different basic structures of terpene-modified phenolic resins, were individually added to the tread compounds of tires and their physical properties were compared with those of the alkyl phenol resin compounds. Alkyl phenolic resins showed no significant difference in tangent delta from terpene-modified phenolic resins at 0 ℃, which is related to wet traction, but showed higher tangent delta at 80 ℃, which is related to rolling resistance, indicating smaller fuel efficiency improvement effects. Among the terpene-modified phenolic resins, beta pinene one showed improved wet traction and fuel efficiency compared to those of other resins. Delta limonene resin showed the best wet traction improvement effect, and alkyl phenolic resins showed relatively high tensile strength and abrasion property. All terpene-modified resins exhibited better rolling resistance than those of alkyl phenolic ones so that they can be said to have better fuel efficiency improvement effects and also to improve other properties compared to those of blanks. Terpene-modified phenolic resins could be used when mixing tire compounds referring to the properties of the phenolic resins revealed in this work, which could result in preparing compounds with improved wet traction and rolling resistance.