• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.816-822
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• 2011

Pervaporation is known to be a low energy consumption process since it needs only an electric power to maintain the permeate side in vacuum. Also, the pervaporation is an environmentally clean technology because it does not use the third material such as an entrainer for either an azeotropic distillation or an extractive distillation. In this study, Silicalite-1 particles are hydrothermally synthesized and polydimethylsiloxane(PDMS)-zeolite composite membranes are prepared with a mixture of synthesized Silicalite-1 particles and PDMS-polymer. They are used to separate n-butanol from its aqueous solution. Pervaporation characteristics such as a permeation flux and a separation factor are investigated as a function of the feed concentration and the weight % of Silicalite-1 particles in the membrane. A 1,000 $cm^3$ aqueous solution containing butanol of low mole fraction such as order of 0.001 was used as a feed to the membrane cell while the pressure of the permeation side was kept about 0.2~0.3 torr. When the butanol concentration in the feed solution was 0.015 mole fraction, the flux of n-butanol significantly increased from 14.5 g/ $m^2$/hr to 186.3 g/$m^2$/hr as the Silicalite-1 content increased from 0 wt% to 10 wt%, indicating that the Silicalite-1 molecular sieve improved the membrane permselectivity from 4.8 to 11.8 due to its unique crystalline microporous structure and its strong hydrophobicity. Consequently, the concentration of n-butanol in the permeate substantially increased from 0.07 to 0.15 mole fraction. This composite membrane could be potentially appliable for separation of n-butanol from insitu fermentation broth where n-butanol is produced at a fairly low concentration of 0.015 mole fraction.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05b
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• pp.199-202
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• 2004

DMFC 성능을 개선시키기 위한 연구의 큰 영역은 고분자전해질막에 있으며 methanol crossover에 대한 영향을 최소화시킬 수 있는 소재개발이 우선적으로 요구되는 실정이다. 이러한 문제의 해결을 위해 Pivovar와 Cussler [1] 등은 투과증발 막분리공정에서 메탄올 저항체로 잘 알려진 폴리비닐알콜(poly vinyl alcohol, PVA)를 이용한 전해질막 연구를 하였다.(중략)

• Membrane Journal
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• v.25 no.5
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• pp.385-390
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• 2015

To determine the pervaporation separation characteristics of IPA/water mixtures, PEI/PDMS hollow fiber membrane module commercialized by Airrane Co. was subjected to both lab and pilot tests. The flux of $0.52kg/m^2h$ and IPA concentration of 68.5% at $25^{\circ}C$ were obtained whereas the $1.368kg/m^2h$ and 61.2% were measured at $55^{\circ}C$. In order to realized the durability of the module, the long-term test (at $50^{\circ}C$) of 100 days has been conducted and as a result, the flux $1.03{\sim}1.15kg/m^2h$ and IPA concentration 61.8~62.5% were maintained with the initial values.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.98-105
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• 2013

The NaA zeolite particles were dispersed in a poly(vinyl alcohol) (PVA) matrix to prepare a composite membrane. The nano sized zeolite particles of NaA were synthesized in the laboratory and the mean size was approximately 60 nm. Pervaporation characteristics such as a permeation flux and a separation factor were investigated using the membrane as a function of the feed concentration from 0.01 to 0.05 mole fraction and the weight % of NaA particles between 0 wt% and 5 wt% in the membrane. Also, the micro sized particles of $5{\mu}m$ were dispersed in the membrane for a comparison purpose. When the ethanol concentration in the feed solution was 0.01 mole fraction, the flux of water significantly increased from $600g/m^2/hr$ to $2000g/m^2/hr$ as the content of the nano NaA particles in the membrane increased from 0 wt% to 5 wt%, while the NaA particles improved the separation factor from 1.5 to 7.9. When the flux of water through the membrane containing nano sized particles was roughly 15% increased compared to the micro sized particles, whereas the separation factor of water was found to be approximately 5% increased. It can be said that the role of the nano sized NaA particles is quite important since both the flux and the separation factor are strongly affected.

• Membrane Journal
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• v.16 no.1
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• pp.25-30
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• 2006

The NaA zeolite membrane was synthesized on the surface of a porous ${\alpha}$-alumina support from the reaction solution composed of 1Si : 1Na : 4Na $6H_{2}O$. The pervaporation performance of the synthesized NaA zeolite membrane was investigated for the iso-propyl alcohol (IPA) aqueous solution according to the different feed concentration and the different operating temperature. The total flux decreases by increasing the feed IPA concentration and increases by increasing the temperature. The total flux was about $4.0{\times}10^3g/m^2\;hr\;at\;60^{\circ}C$ and 0.6 mole fraction of IPA and the separation factor was $1.8{\times}10^7\;at\;60^{\circ}C$ and 0.8 mole fraction of IPA. The separation performance of water through the NaA membrane was found to be superior to that obtainable with a distillation process just by comparison of the vapor-liquid equilibrium data.

• Clean Technology
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• v.7 no.3
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• pp.195-202
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• 2001

In this study the trace of chlorinated organic compound in aqueous solution was separated by pervaporation process using crosslinked PDMS (polydimethylsiloxane) membrane. The flux of trichloroethylene(TCE) increased linearly with feed composition but the flux of water was slightly increased. The partial flux of TCE was greater than that of tetrachloroethylene(PCE). The partial flux of TCE was not changed with operating temperature, but increased rapidly with feed flow rates. High crosslinking density causes the reduction of solubility and diffusivity for target component. The reduction of flux and selectivity for TCE is due to the chain immobilization and reduction of diffusivity with crosslinking density.

• Applied Chemistry for Engineering
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• v.10 no.7
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• pp.1041-1045
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• 1999

Three polysiloxaneimide(PSI) as membrane material were prepared by polycondensation of three aromatic dianhydrides(6FDA, BTDA, PMDA) with one siloxane-containing diamine(SIDA, aver. MW. 800). The PSIs were rubbery polymers containing 30~40 wt % of flexible siloxane chains and exhibited low density, high fractional free volume and low surface energy. They were used for pervaporation experiments with 0.05 wt % of four organic aqueous solutions containing ethyl acetate, methylene chloride, trichloroethylene, and toluene, respectively. With increasing hydrophobicity of organic solvents, both pervaporation selectivity and pemeation flux increase.

• Membrane Journal
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• v.6 no.4
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• pp.242-249
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• 1996

To improve pervaporation performance of water/ethanol mixtures, chitosan/poly(vinyl alcohol) blended and phosphorylated chitosan composite membranes were prepared. Chitosan/poly(vinyl alcohol) blends were prepared with various blend ratios and then crosslinked with glutaraldehyde by two methods. With increasing crosslinking agent content and crosslinking times separation factor increased and permeate flux decreased. Separation factor of the membrane which contains glutaraldehyde as a crosslinking agent was higher than that of the membrane surface crosslinked. Phosphorylated chitosan was prepared with various reaction times and composite membrane was prepared. As reaction times increased, the separation factor increased with high affinity for water.

• Proceedings of the Membrane Society of Korea Conference
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• 2002.11a
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• pp.33-38
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• 2002

No Abstract, See Full Text

• Membrane Journal
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• v.6 no.1
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• pp.44-52
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• 1996

For the purpose of the optimal design of a frame and plate type of pervaporation module, model equations which can predict the effects of feed flow condition on the temperature distribution of the feed developed in the module were established and the temperature distribution with feed flow condition was investigated through the model si$$\mu$ation. With increasing the Reynolds number of feed flow in the module, the flow velocity gradient in the channel height-direction as well as the volume rate of feed which acts as energy source for the evaporation of perrneants on the permeate-side surface of a membrane increased to such an extent that both mass and heat flux in the channel height direction could increase and the temperature drop of feed due to the evaporation of the permeant could be reduced correspondingly. A decrease in channel height caused the temperature drop of feed because of decreasing feed flow in the module. It was observed that the si$$\mu$ation result on the effect of Re on the temperature distribution of feed in the module has an agreement with experiment.