• Title/Summary/Keyword: 토양오염특성

Search Result 952, Processing Time 0.023 seconds

Characteristics of Pesticide Runoff and Persistence on Agricultural Watersheds in Korea (영농지역에서 작물재배 형태에 따른 농약의 잔류성과 유출특성)

  • Park, Byung-Jun;Kwon, Oh-Kyung;Kim, Jin-Kyoung;Kim, Jin-Bea;Kim, Jin-Ho;Yoon, Soon-Kang;Shim, Jae-Han;Hong, Moo-Gi
    • Korean Journal of Environmental Agriculture
    • /
    • v.28 no.2
    • /
    • pp.194-201
    • /
    • 2009
  • To evaluate the exposure of non-point source pesticide pollution in agricultural watershed and to investigate pesticide distribution and runoff from agricultural land, paddy field, upland and orchard, this experiment was carry out during crop growing seasons. The pesticide were detected twenty pesticides fungicide 4, insecticide 10, herbicide 6) in water of Neungchon agricultural watershed and detection concentrations were range 0.008${\sim}$7.59 ppb. Most of the detection pesticides were using pesticides to rice paddy fields to control fungi, insects, weeds. During the crop cultivation, the pesticide were detected total thirty pesticides by pepper field soil 6, orchard soil 4, sesame field soil 3 and rice paddy field soil 5, and pesticide concentrations were range 0.001${\sim}$0.109 ppm. Especially the herbicides were detected mainly in May and June in the stream water. The pesticide were detected thirty pesticides by fungicide 2, insecticide 6, herbicide 5 in water of Jungam Koseong agricultural watershed and detection concentrations were range 0.01${\sim}$7.21 ppb. In regard to the detected pesticides, the concentration of individual pesticides measured in surface water of the study areas never exceeded guidelines for agriculture chemicals concerning water quality-effluent from paddy fields in Japan (Katayama, 2003). Runoff rate of pesticides was range 0.07${\sim}$3.06 % from Kongju agricultural land to watershed after applied pesticides.

An operation of Pangyo experimental catchment to assess the variation of stream hydrology and water quality by urbanization (도시화에 따른 하천 수문.수질 변동 영향 평가를 위한 판교 시험유역의 운영)

  • Jang, Cheol-Hee;Kim, Hyeon-Jun;Kim, Chul-Gyum;Noh, Seong-Jin
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2006.05a
    • /
    • pp.1865-1869
    • /
    • 2006
  • 도시화는 수문학적으로 산림이나 농경지와 같은 투수지역을 건물, 도로 등의 불투수지역으로 변화시키는 것이며, 이로 인하여 홍수파의 도달시간이 줄어들고 첨두유량이 증가하는 등의 수문변화를 수반하게 된다. 도로나 건물 등이 대부분을 차지하고 있는 도시지역에서는 지표면이나 식생으로부터 대기중으로 방출되는 증발산량이 농촌이나 산림지역보다 상대적으로 적으며, 강우시 토양중의 침투량과 지표면의 저류량도 도시지역에서는 매우 적게 나타난다. 본 연구에서는 도시화로 인하여 대규모의 토지이용 변화가 예상되는 신도시 개발예정지구인 판교 운중천 유역을 시험유역으로 선정하여 장기적인 수문/수질 모니터링을 수행하고 있으며, 향후 판교 시험유역에서 계측된 자료와 유역수문모형을 활용하여 개발 전후의 홍수 및 장기유출 특성을 분석하여 도시화가 하천의 수문 및 수질에 미치는 영향을 정량적으로 비교 분석하고자 한다. 이를 위해 2004년과 2005년에 시험유역내의 운중천과 금토천에 매송2교, 삼평교, 판교교, 운중저수지, 저수지 용수로, 내동교 등 총 6개의 수위관측소와, 매송2교와 내동교의 2개 우량관측소를 설치하여 실시간 계측을 수행하고 있으며, 인근의 기존에 운영되고 있던 탄천 본류의 성남과 궁내 수위관측소와 운중천의 낙생 우량관측소 자료를 활용하여 유역 수문자료를 수집하고 있다. 수집된 자료를 이용하여 장단기 유출분석을 수행한 결과, 택지개발공사가 시작되기 전인 현재로서는 택지개발 대상지구인 운중천 유역이나 비대상지구인 금토천 유역, 그리고 하류의 운중천 본류 유역 모두 강우시나 무강우시 비슷한 유출 특성을 가지고 있는 것으로 나타났다. 향후 도시화가 점차적으로 진행됨에 따라서 이러한 유출 특성의 변화 양상을 파악해 나간다면, 도시화에 따른 유출 특성의 변화는 물론 수질 변화에 대해서도 정성적, 정량적인 규명이 가능할 것으로 생각된다.TEX>의 범위이고, 2차 처리수의 유입수의 T-N, T-P 농도와 유사하였다.적인 방법론을 제시할 수 있을 것으로 사료된다.첨두홍수량을 저류하기 위해서 상대적으로 넓은 저류면적이 필요한 것으로 나타난다. 대등한 수위감소값의 홍수저감효과를 발휘하기 위해서 본 연구에서는 On-Line 저류지 면적은 Off-Line 저류지에 비 두배 이상이 필요한 것으로 보여졌다.들에 관한 정보는 종종 현장관측에서 조차 무시되는 경우가 많다. 이에 본 연구에서는 수질모형의 매개변수 중 특히 수리특성에 관련된 매개변수들이 수질에 미치는 영향을 파악하는 것을 목적으로 하고 있다. 이를 위해 적용된 수질모형은 QualKo를 사용하였으며, 대상 하천은 낙동강 본류 경남구간 시점 부근인 회천 합류 전부터 낙동강 본류 경남구간 종점 부근인 밀양강 합류 전까지의 경남 오염총량관리 기본계획 시 구축된 모형 매개변수를 바탕으로 분석을 수행하였다. 일차오차분석을 이용하여 수리매개변수와 수질매개변수의 수질항목별 상대적 기여도를 파악해 본 결과, 수리매개변수는 DO, BOD, 유기질소, 유기인 모든 항목에 일정 정도의 상대적 기여도를 가지고 있는 것을 알 수 있었다. 이로부터 수질 모형의 적용 시 수리 매개변수 또한 수질 매개변수의 추정 시와 같이 보다 세심한 주의를 기울여 추정할 필요가 있을 것으로 판단된다.변화와 기흉 발생과의 인과관계를 확인하고 좀 더 구체화하기 위한 연구가 필요할 것이다.게 이루어질 수 있을 것으로 기대된다.는 초과수익률이 상승하지만, 이후로는 감소하므로, 반전거래전략을 활용하는 경우 주식투자기간은 24개월이하의 중단기가 적합함을 발견하였다. 이상의 행태적 측면과 투자성과측면의 실증결과를 통하여 한국주식시장에 있어서 시장수익률을 평균적으로 초과할 수 있는 거래전략은 존재하므로 이러한 전략을 개발 및 활용할 수 있으며, 특히, 한국주식시장에

  • PDF

The Cesium Removal Using a Polysulfone Carrier Containing Nitric Acid-treated Bamboo Charcoal (질산으로 표면처리한 대나무 활성탄을 첨가한 폴리술폰 담체의 세슘제거 효율 규명)

  • Rahayu, Ni Wayan Sukma Taraning;Kim, Seonhee;Tak, Hyunji;Kim, Kyeongtae;Lee, Minhee
    • Economic and Environmental Geology
    • /
    • v.53 no.5
    • /
    • pp.529-542
    • /
    • 2020
  • The cesium (Cs) sorption characteristics of a bead-type polysulfone carrier contained HNO3-treated bamboo charcoal (3 - 5 mm in diameter) in water system were investigated and its Cs removal efficiency as an adsorbent from water was also identified by various laboratory experiments. From the results of batch sorption experiments, the bead-type polysulfone carrier with only 5% HNO3-treated bamboo charcoal (P-5NBC) represented the high Cs removal efficiency of 57.8% for 1 hour sorption time. The Cs removal efficiency of P-5NBC in water after 24 hours reaction maintained > 69% at a wide range of pH and temperature conditions, attesting to its applicability under various water systems. Batch sorption experiments were repeated for P-5NBC coated with two cultivated microorganisms (Pseudomonas fluorescens and Bacillus drentensis), which were typical indigenous species inhabited in soil and groundwater. The Cs removal efficiency for two microorganisms coated polysulfone carrier (BP-5NBC) additionally increased by 19% and 18%, respectively, compared to that of only P-5NBC without microorganisms coated. The average Cs desorption rate of P-5NBC for 24 h was lower than 16%, showing the Cs was stably attached on HNO3-treated bamboo charcoal in so much as its long-term use. The maximum Cs sorption capacity (qm) of P-5NBC calculated from the Langmuir isotherm model study was 60.9 mg/g, which was much higher than those of other adsorbents from previous studies for 1 h sorption time. The results of continuous column experiments showed that the P-5NBC coated with microorganisms packed in the column maintained > 80% of the Cs removal efficiency during 100 pore volumes flushing. It suggested that only 14.7 g of P-5NBC (only 0.75 g of HNO3 treated bamboo charcoal included) can successfully clean-up 7.2 L of Cs contaminated water (the initial Cs concentration: 1 mg/L; the effluent concentration: < 0.2 mg/L). The present results suggested that the Cs contaminated water can be successfully cleaned up by using a small amount of the polysulfone carrier with HNO3-treated bamboo charcoal.

Identifying sources of heavy metal contamination in stream sediments using machine learning classifiers (기계학습 분류모델을 이용한 하천퇴적물의 중금속 오염원 식별)

  • Min Jeong Ban;Sangwook Shin;Dong Hoon Lee;Jeong-Gyu Kim;Hosik Lee;Young Kim;Jeong-Hun Park;ShunHwa Lee;Seon-Young Kim;Joo-Hyon Kang
    • Journal of Wetlands Research
    • /
    • v.25 no.4
    • /
    • pp.306-314
    • /
    • 2023
  • Stream sediments are an important component of water quality management because they are receptors of various pollutants such as heavy metals and organic matters emitted from upland sources and can be secondary pollution sources, adversely affecting water environment. To effectively manage the stream sediments, identification of primary sources of sediment contamination and source-associated control strategies will be required. We evaluated the performance of machine learning models in identifying primary sources of sediment contamination based on the physico-chemical properties of stream sediments. A total of 356 stream sediment data sets of 18 quality parameters including 10 heavy metal species(Cd, Cu, Pb, Ni, As, Zn, Cr, Hg, Li, and Al), 3 soil parameters(clay, silt, and sand fractions), and 5 water quality parameters(water content, loss on ignition, total organic carbon, total nitrogen, and total phosphorous) were collected near abandoned metal mines and industrial complexes across the four major river basins in Korea. Two machine learning algorithms, linear discriminant analysis (LDA) and support vector machine (SVM) classifiers were used to classify the sediments into four cases of different combinations of the sampling period and locations (i.e., mine in dry season, mine in wet season, industrial complex in dry season, and industrial complex in wet season). Both models showed good performance in the classification, with SVM outperformed LDA; the accuracy values of LDA and SVM were 79.5% and 88.1%, respectively. An SVM ensemble model was used for multi-label classification of the multiple contamination sources inlcuding landuses in the upland areas within 1 km radius from the sampling sites. The results showed that the multi-label classifier was comparable performance with sinlgle-label SVM in classifying mines and industrial complexes, but was less accurate in classifying dominant land uses (50~60%). The poor performance of the multi-label SVM is likely due to the overfitting caused by small data sets compared to the complexity of the model. A larger data set might increase the performance of the machine learning models in identifying contamination sources.

The application of GIS and RS for extracting Sumjin Watershed hydrologic-parameter (섬진강 유역 수문인자 추출을 위한 GIS와 RS의 활용)

  • 김지은;이근상;조기성;장영률
    • Spatial Information Research
    • /
    • v.8 no.2
    • /
    • pp.257-274
    • /
    • 2000
  • Recently, natural environment is being forced by the quick increasing of population and industrialization, and especially, capacity and pollution of water resource is being come to the front. It needs to extract the accurate topological and hydrological parameters of watershed in order to manage water resource efficiently. But, these data are processed yet by manual work and simple operation in hydrological fields. In this paper, we presented algorithm that could extract topological any hydrological parameters over Sumjin watershed using GIS and RS and it gives the saving of data processing time and the confidency of data. The extraction procedure of topological characteristics and hydrological parameters is as below. First, watershed and stream are extracted by DEM and curve number is extracted throughout the overlay of landcov map and soil map. Also, we extracted surface parameters like watershed length and the slope of watershed length by Grid computation into watershed and stream. And we gave the method that could extract hydrologic parameters like Muskingum K and sub-basin lag time by executing computation into surface parameters and average SCS curve number being extracted.

  • PDF

A Study on the Relationship between Void Ratio and Permeability by Constant Strain Rate Consolidation Test (일정변형률 압밀시험을 이용한 간극비-투수계수의 관계 연구)

  • Joo, Jong-Jin;Lim, Hyung-Duk;Lee, Woo-Jin;Kim, Dae-Kyu;Kim, Nak-Kyung;Kim, Hyung-Joo
    • Journal of the Korean GEO-environmental Society
    • /
    • v.3 no.3
    • /
    • pp.15-25
    • /
    • 2002
  • The permeability coefficient is one of the fundamental engineering properties of soft clays. Consolidation process as well as migration of pollutants in soil are affected the permeability coefficient, which generally decreases with the reduction in void ratio during consolidation. After Kozeny(1927) and Carman(1956), many researchers have proposed the relationships between void ratio and permeability in such forms as; (1) log e - log k(1+e), (2) e - log k, or (3) log e - log k. Constant rate of strain (CRS) tests was performed with undisturbed samples obtained at Kunsan and Kimhae deposits, which are representative Korean marine clay. From the results of the tests, the relationships were found valid for Kunsan and Kimhae clays. The experimental correlation $C_k=0.5e_o$ was satisfied with Kimhae clay but not with Kunsan clay.

  • PDF

Enhanced TPH Degradation of Diesel-Contaminated Soil by Microwave Heating (디젤오염토양의 TPH 분해를 위한 마이크로파의 가열특성)

  • Jung, Byung-Gil;Kim, Dae-Yong;Kim, Jung-Kwon
    • Journal of Environmental Science International
    • /
    • v.17 no.5
    • /
    • pp.479-484
    • /
    • 2008
  • The application of microwave technology has been investigated in the remediation of diesel-contaminated soil. The paper deals with economic assessment by means of cost analysis and degradation characteristics at different microwave powers for total petroleum hydrocarbon (TPH) in diesel contaminated soils. The soils from S Mountain around the D University were sampled. The samples were screened with 2.0 mm mesh and dried for 6 hours before the diesel was added into the dried soils. The diesel-contaminated soil (3,300 mg THP/kg soil) was prepared with diesel (S Co.). The drying process was carried out in a microwave oven, a standard household appliance with a 2,450 MHz frequency and 700 W of power. The experiments were conducted from 0 to 20 minutes as the microwave powers increased from 350W to 500W to 700W. The concentrations of TPH were analysed using a gas chromatography/mass spectrometer (GC/MS). The initial concentration of TPH was 3,300 mg TPH/kg soil. The weight of contaminated soil was 200g. The concentration of TPH was decreased to 1,828 mg TPH/kg soil (44.7%), 1,347 mg TPH/kg soil (59.2%) and 1,014 mg TPH/kg soil (69.3%) at 350W, 500W and 700W for 15 minutes respectively. In addition, the curve was best fit with first order kinetics using the least-square method. The ranges of a first order rate constant k and r-square were $0.0298{\sim}0.0375min^{-1}$ and $0.9373{\sim}0.9541$ respectively.

Studies on nickel uptake in transgenic Arabidopsis thaliana introduced with TgMTP1 gene encoding metal tolerance protein (TgMTP1 과발현 애기장대에서 Nickel 흡수 연구)

  • Kim, Donggiun
    • Journal of Plant Biotechnology
    • /
    • v.42 no.4
    • /
    • pp.409-413
    • /
    • 2015
  • To enhance phytoremediation, which removes heavy metal from soil, transgenic plants were applied to contaminated soil. We constructed a transformation vector expressing both $TgMTP_1$ (T. goesingense metal tolerance protein):HA and TgMTP:GFP genes. Transgenic plants were generated using an Agrobacterium-mediated transformation system that expressed the two vectors. Screening and analysis confirmed the incorporation of foreign genes into the Arabidopsis thaliana genome. Callus was induced in the 116 T3 line. These transgenic plants and calli were used for further analyses on the accumulation of Ni. The 116 T3-line plants and calli from selected lines were resistant to heavy metals and accumulated Ni in their leaves. The expression level of TgMTP RNA was equal in all leaves, but protein stability increased in the leaves with Ni treatment. According to these results, we suggest that $TgMTP_1$-overexpressing plants may be useful for phytoremediation of soil.

Impact of the Geochemical Characteristics and Potential Contaminants Source of Surrounding Soil on Contamination of a Reservoir in an Island (II) - Appraisal of flow categorized by Incursion Using Rainfall-Runoff Model - (주변토양의 지구화학적 특성과 잠재적 오염원이 도서지역 저수지의 오염부하에 미치는 영향(II) - 강우 유출 모형을 이용한 유입경로별 유출량 평가 -)

  • Park, Sun-Hwan;Park, Wan-Sub;Jun, Young-Bong;Kim, Chang-Gyun;Kim, Sung-Gou;Kang, Seon-Hong;Chang, Yoon-Young;Jeong, Jeong-Ho;Jung, Jong-Ahm
    • Journal of Environmental Impact Assessment
    • /
    • v.19 no.3
    • /
    • pp.215-222
    • /
    • 2010
  • This research aims to gain the result of assessment of inflow categorized by runoff path using DIROM (Daily Irrigation Reservoir Operation Model) for Baengnyeong-myeon reservior which was built for residents of Baengnyeong island to solve the shortage of drinking water and stable supply of domestic water. The simulation results of DIROM and actual hydrograph of the reservoir show very low correlation with geological characteristics. The simulation results by DIROM after adjusting with modified Tank III model which considers all outflow from Tank II model as interflow among 3 level tanks show good correlation of its regional runoff and inflow characteristics with $R^2$=0.9058. In the study area, diffluence of 37% of rain fall of the study year has been simulated, which shows low result compared to the average river runoff of national water resource. In addition, 34.5% of total inflow to the study reservoir is mainly interflow and baseflow among expected several channels.

Groundwater Flow Modeling for a Finite Unconfined Sandy Aquifer in a Laboratory Scale (사질 자유면 대수층 모형에서의 지하수 모델링)

  • 이승섭;김정석;김동주
    • Journal of the Korean Society of Groundwater Environment
    • /
    • v.6 no.4
    • /
    • pp.188-193
    • /
    • 1999
  • Transport of pollutants in aquifer largely depends on groundwater flow which is governed by aquifer hydraulic parameters. Determination of these parameters and associated groundwater modeling become essential for adequate remediation of contaminate groundwater. The objective of this paper is to analyze groundwater flow and determine the optimum hydraulic parameters by performing groundwater modeling based on sensitivity analysis for unconfined sandy gavel aquifer constructed in a laboratory scale under various boundary condition. Results revealed that the simulated drawdown was lower than the observed drawdown irrespective of boundary conditions. and specific yield (S$_{y}$) had less effect on the grondwater flow than permeability (K) in the aquifer. Water balance analysis showed that the measured drawdown in neighboring observation wells during pumping was higher than either simulated or recovered water table. The indicated that a difference might exist in the water tables between aquifer and wells. The difference was investigated by time domain reflectometry (TDR) measurements on water contents in the region of water table and capillary fringe, and explained by a delayed response of water table during gravitational drainage as the water table was lowered as a result of pumping.g.

  • PDF